The University of Queensland

Electrochemistry of molybdenum and tungsten enzymes

Kalimuthu, Palraj and Bernhardt, Paul V. (2017). Electrochemistry of molybdenum and tungsten enzymes. Molybdenum and tungsten enzymes: spectroscopic and theoretical investigations. (pp. 168-222) edited by Russ Hille, Carola Schulzke and Martin L. Kirk. Cambridge, United Kingdom: Royal Society of Chemistry. doi: 10.1039/9781782628842-00168

Communication with the mononuclear molybdoenzymes: Emerging opportunities and applications in redox enzyme biosensors

Bernhardt, Paul V. (2009). Communication with the mononuclear molybdoenzymes: Emerging opportunities and applications in redox enzyme biosensors. Engineering the Bioelectronic Interface: Applications to Analyte Biosensing and Protein Detection. (pp. 1-24) edited by Davis, J.. Cambridge, UK: The Royal Society of Chemistry.

Cobalt

Bernhardt, P. V. and Lawrance, G. (2004). Cobalt. Comprehensive Coordination Chemistry II: From Biology to Nanotechnology. (pp. 1-145) edited by J. A. McCleverty and T. J. Meyer. Oxford: Elsevier/Pergamon. doi: 10.1016/B0-08-043748-6/05083-0

Kinetico-Mechanistic Studies on a Reactive Organocopper(II) Complex: Cu–C Bond Homolysis versus Heterolysis

Gonzálvez, Miguel A., Williams, Craig M., Martínez, Manuel and Bernhardt, Paul V. (2023). Kinetico-Mechanistic Studies on a Reactive Organocopper(II) Complex: Cu–C Bond Homolysis versus Heterolysis. Inorganic Chemistry, 62 (11), 4662-4671. doi: 10.1021/acs.inorgchem.3c00127

Synthesis of uronic acid 1‐Azasugars as putative inhibitors of α‐Iduronidase, β‐glucuronidase and heparanase

Doherty, Gareth G., Ler, Geraldine Jia Ming, Wimmer, Norbert, Bernhardt, Paul V., Ashmus, Roger A., Vocadlo, David J., Armstrong, Zach W. B., Davies, Gideon J., Maccarana, Marco, Li, Jin-ping, Kayal, Yasmin and Ferro, Vito (2023). Synthesis of uronic acid 1‐Azasugars as putative inhibitors of α‐Iduronidase, β‐glucuronidase and heparanase. ChemBioChem, 24 (4) e202200619, 1-7. doi: 10.1002/cbic.202200619

Interplay of electronic and geometric structure on Cu phenanthroline, bipyridine and derivative complexes, synthesis, characterization, and reactivity towards oxygen

Romo, Adolfo I.B., dos Reis, Monilson P., Nascimento, Otaciro R., Bernhardt, Paul V., Rodríguez-López, Joaquín and Diógenes, Izaura C.N. (2023). Interplay of electronic and geometric structure on Cu phenanthroline, bipyridine and derivative complexes, synthesis, characterization, and reactivity towards oxygen. Coordination Chemistry Reviews, 477 214943, 214943. doi: 10.1016/j.ccr.2022.214943

Structural and functional insight into the mechanism of the Fe‐S cluster‐dependent dehydratase from Paralcaligenes ureilyticus

Bayaraa, Tenuun, Lonhienne, Thierry, Sutiono, Samuel, Melse, Okke, Brück, Thomas B., Marcellin, Esteban, Bernhardt, Paul V., Boden, Mikael, Harmer, Jeffrey R., Sieber, Volker, Guddat, Luke W. and Schenk, Gerhard (2023). Structural and functional insight into the mechanism of the Fe‐S cluster‐dependent dehydratase from Paralcaligenes ureilyticus. Chemistry: A European Journal, 29 (9) e202203140, 1-13. doi: 10.1002/chem.202203140

<i>Ab Initio</i> Investigation of the Na₃[Ln(ODA)₃]·2NaClO₄·6H₂O (Ln = Ce–Yb; ODA = Oxydiacetate) Series

Connolly, Blake J. P., Lian, James Y. J., Bernhardt, Paul V. and Riley, Mark J. (2023). Ab Initio Investigation of the Na3[Ln(ODA)3]·2NaClO4·6H2O (Ln = Ce–Yb; ODA = Oxydiacetate) Series. Inorganic Chemistry, 62 (4), 1328-1340. doi: 10.1021/acs.inorgchem.2c01764

Designing Tailored Thiosemicarbazones with Bespoke Properties: The Styrene Moiety Imparts Potent Activity, Inhibits Heme Center Oxidation, and Results in a Novel “Stealth Zinc(II) Complex”

Dharmasivam, Mahendiran, Kaya, Busra, Wijesinghe, Tharushi, Gholam Azad, Mahan, Gonzálvez, Miguel A., Hussaini, Mohammad, Chekmarev, Jason, Bernhardt, Paul V. and Richardson, Des R. (2023). Designing Tailored Thiosemicarbazones with Bespoke Properties: The Styrene Moiety Imparts Potent Activity, Inhibits Heme Center Oxidation, and Results in a Novel “Stealth Zinc(II) Complex”. Journal of Medicinal Chemistry, 66 (2), 1426-1453. doi: 10.1021/acs.jmedchem.2c01600

Electrocatalytic aldehyde oxidation by a tungsten dependent aldehyde oxidoreductase from Aromatoleum aromaticum

Kalimuthu, Palraj, Hege, Dominik, Winiarska, Agnieszka, Gemmecker, Yvonne, Szaleniec, Maciej, Heider, Johann and Bernhardt, Paul V. (2023). Electrocatalytic aldehyde oxidation by a tungsten dependent aldehyde oxidoreductase from Aromatoleum aromaticum. Chemistry – A European Journal, e202203072. doi: 10.1002/chem.202203072

1-Azahomocubane

Fahrenhorst-Jones, Tyler, Marshall, David L., Burns, Jed. M., Pierens, Gregory K., Hormann, Robert E., Fisher, Allison M., Bernhardt, Paul V., Blanksby, Stephen J., Savage, G. Paul, Eaton, Philip E. and Williams, Craig M. (2023). 1-Azahomocubane. Chemical Science, 14 (11), 2821-2825. doi: 10.1039/d3sc00001j

Molecular networking and cultivation profiling reveals diverse natural product classes from an Australian soil-derived fungus Aspergillus sp. CMB-MRF324

Wu, Taizong, Salim, Angela A., Bernhardt, Paul V. and Capon, Robert J. (2022). Molecular networking and cultivation profiling reveals diverse natural product classes from an Australian soil-derived fungus Aspergillus sp. CMB-MRF324. Molecules, 27 (24) 9066, 1-17. doi: 10.3390/molecules27249066

Unearthing the Subtleties of Rhodium(II)-Catalyzed Carbenoid Cycloadditions to Furans with an <i>N</i>-Sulfonyl-1,2,3-triazole Probe

Bettencourt, Christian J., Krainz, Tanja, Chow, Sharon, Parr, Brendan T., Tracy, William F., Bernhardt, Paul V., Davies, Huw M. L. and Williams, Craig M. (2022). Unearthing the Subtleties of Rhodium(II)-Catalyzed Carbenoid Cycloadditions to Furans with an N-Sulfonyl-1,2,3-triazole Probe. Organic Letters, 24 (50), 9290-9295. doi: 10.1021/acs.orglett.2c03869

Noonindoles A–F: Rare indole diterpene amino acid conjugates from a marine-derived fungus, Aspergillus noonimiae CMB-M0339

Kankanamge, Sarani, Khalil, Zeinab G., Bernhardt, Paul V. and Capon, Robert J. (2022). Noonindoles A–F: Rare indole diterpene amino acid conjugates from a marine-derived fungus, Aspergillus noonimiae CMB-M0339. Marine Drugs, 20 (11) 698, 1-16. doi: 10.3390/md20110698

Catalytic electrochemistry of the bacterial Molybdoenzyme YcbX

Kalimuthu, Palraj, Harmer, Jeffrey R., Baldauf, Milena, Hassan, Ahmed H., Kruse, Tobias and Bernhardt, Paul V. (2022). Catalytic electrochemistry of the bacterial Molybdoenzyme YcbX. Biochimica et Biophysica Acta - Bioenergetics, 1863 (7) 148579, 148579. doi: 10.1016/j.bbabio.2022.148579

Scanning Optical Spectroelectrochemistry: Applications in Protein Redox Potential Measurements

Bernhardt, Paul V. (2022). Scanning Optical Spectroelectrochemistry: Applications in Protein Redox Potential Measurements. Chemistry–Methods, 3 (3). doi: 10.1002/cmtd.202200047

Nitroimidazopyrazinones with Oral Activity against Tuberculosis and Chagas Disease in Mouse Models of Infection

Ang, Chee Wei, Lee, Brendon M., Jackson, Colin J., Wang, Yuehong, Franzblau, Scott G., Francisco, Amanda F., Kelly, John M., Bernhardt, Paul V., Tan, Lendl, West, Nicholas P., Sykes, Melissa L., Hinton, Alexandra O., Bolisetti, Raghu, Avery, Vicky M., Cooper, Matthew A. and Blaskovich, Mark A.T. (2022). Nitroimidazopyrazinones with Oral Activity against Tuberculosis and Chagas Disease in Mouse Models of Infection. Journal of Medicinal Chemistry, 65 (19), 13125-13142. doi: 10.1021/acs.jmedchem.2c00972

Minimizing the reorganization energy of cobalt redox mediators maximizes charge transfer rates from quantum dots

Fort, Madeleine J., Click, Sophia M., Robinson, Evan H., He, Felix M. C., Bernhardt, Paul V., Rosenthal, Sandra J. and Macdonald, Janet E. (2022). Minimizing the reorganization energy of cobalt redox mediators maximizes charge transfer rates from quantum dots. Angewandte Chemie (International Edition), 134 (27) e202202322, e202202322. doi: 10.1002/anie.202202322

Dihydroxy‐acid dehydratases from pathogenic bacteria: emerging drug targets to combat antibiotic resistance

Bayaraa, Tenuun, Gaete, Jose, Sutiono, Samuel, Kurz, Julia, Lonhienne, Thierry, Harmer, Jeffrey R., Bernhardt, Paul V., Sieber, Volker, Guddat, Luke and Schenk, Gerhard (2022). Dihydroxy‐acid dehydratases from pathogenic bacteria: emerging drug targets to combat antibiotic resistance. Chemistry: A European Journal, 28 (44) e202200927, e202200927. doi: 10.1002/chem.202200927

Enzyme electrode biosensors for N-hydroxylated prodrugs incorporating the mitochondrial amidoxime reducing component

Zapiter, Joan, Harmer, Jeffrey R., Struwe, Michel, Scheidig, Axel, Clement, Bernd and Bernhardt, Paul V. (2022). Enzyme electrode biosensors for N-hydroxylated prodrugs incorporating the mitochondrial amidoxime reducing component. Analytical Chemistry, 94 (25), 9208-9215. doi: 10.1021/acs.analchem.2c02232

Glenthmycins A–M: macrocyclic spirotetronate polyketide antibacterials from the Australian pasture plant-derived Streptomyces sp. CMB-PB041

Wu, Taizong, Salim, Angela A., Khalil, Zeinab G., Bernhardt, Paul V. and Capon, Robert J. (2022). Glenthmycins A–M: macrocyclic spirotetronate polyketide antibacterials from the Australian pasture plant-derived Streptomyces sp. CMB-PB041. Journal of Natural Products, 85 (6), 1641-1657. doi: 10.1021/acs.jnatprod.2c00444

Borylated 2,3,4,5-tetrachlorophthalimide and their 2,3,4,5-tetrachlorobenzamide analogues: synthesis, their glycosidase inhibition and anticancer properties in view to boron neutron capture therapy

Campkin, David M., Shimadate, Yuna, Bartholomew, Barbara, Bernhardt, Paul V., Nash, Robert J., Sakoff, Jennette A., Kato, Atsushi and Simone, Michela I. (2022). Borylated 2,3,4,5-tetrachlorophthalimide and their 2,3,4,5-tetrachlorobenzamide analogues: synthesis, their glycosidase inhibition and anticancer properties in view to boron neutron capture therapy. Molecules, 27 (11) 3447, 1-28. doi: 10.3390/molecules27113447

Ascorbate-and iron-driven redox activity of Dp44mT and Emodin facilitates peroxidation of micelles and bicelles

Selyutina, O.Yu., Kononova, P. A., Koshman, V. E., Shelepova, E. A., Azad, M. Gholam, Afroz, R., Dharmasivam, M., Bernhardt, Paul V., Polyakov, N. E. and Richardson, D. R. (2022). Ascorbate-and iron-driven redox activity of Dp44mT and Emodin facilitates peroxidation of micelles and bicelles. Biochimica et Biophysica Acta - General Subjects, 1866 (4) 130078, 1-16. doi: 10.1016/j.bbagen.2021.130078

Electrochemically driven catalysis of the bacterial molybdenum enzyme YiiM

Kalimuthu, Palraj, Harmer, Jeffrey R., Baldauf, Milena, Hassan, Ahmed H., Kruse, Tobias and Bernhardt, Paul V. (2022). Electrochemically driven catalysis of the bacterial molybdenum enzyme YiiM. Biochimica et Biophysica Acta - Bioenergetics, 1863 (3) 148523, 148523. doi: 10.1016/j.bbabio.2021.148523

Glenthenamines A–F: enamine pyranonaphthoquinones from the Australian pasture plant derived Streptomyces sp. CMB-PB042

Wu, Taizong, Salim, Angela A., Cui, Hui, Khalil, Zeinab G., Bernhardt, Paul V. and Capon, Robert J. (2022). Glenthenamines A–F: enamine pyranonaphthoquinones from the Australian pasture plant derived Streptomyces sp. CMB-PB042. Journal of Natural Products, 85 (2) acs.jnatprod.1c00821, 337-344. doi: 10.1021/acs.jnatprod.1c00821

The (±)-6-Aza[1.0]triblattane skeleton: contraction beyond the Wilder–Culberson ring system

Fahrenhorst-Jones, Tyler, Bernhardt, Paul V., Savage, G. Paul and Williams, Craig M. (2022). The (±)-6-Aza[1.0]triblattane skeleton: contraction beyond the Wilder–Culberson ring system. Organic Letters, 24 (3) acs.orglett.1c04240, 903-906. doi: 10.1021/acs.orglett.1c04240

An altered heme environment in an engineered cytochrome P450 enzyme enables the switch from monooxygenase to peroxygenase activity

Podgorski, Matthew N., Harbort, Joshua S., Lee, Joel H. Z., Nguyen, Giang T.H., Bruning, John B., Donald, William A., Bernhardt, Paul V., Harmer, Jeffrey R. and Bell, Stephen G. (2022). An altered heme environment in an engineered cytochrome P450 enzyme enables the switch from monooxygenase to peroxygenase activity. ACS Catalysis, 12 (3), 1614-1625. doi: 10.1021/acscatal.1c05877

Organocopper(II) complexes: new catalysts for carbon–carbon bond formation via electrochemical atom transfer radical addition (eATRA)

Gonzálvez, Miguel A., Su, Chuyi, Williams, Craig M. and Bernhardt, Paul V. (2022). Organocopper(II) complexes: new catalysts for carbon–carbon bond formation via electrochemical atom transfer radical addition (eATRA). Chemical Science, 13 (35), 10506-10511. doi: 10.1039/d2sc03418b

To be, or not to be, an inhibitor: a comparison of Azole interactions with and oxidation by a cytochrome P450 enzyme

Podgorski, Matthew N., Coleman, Tom, Giang, Peter D., Wang, C. Ruth, Bruning, John B., Bernhardt, Paul V., De Voss, James J. and Bell, Stephen G. (2022). To be, or not to be, an inhibitor: a comparison of Azole interactions with and oxidation by a cytochrome P450 enzyme. Inorganic Chemistry, 61 (1) acs.inorgchem.1c02786, 236-245. doi: 10.1021/acs.inorgchem.1c02786

Activation of PKC supports the anticancer activity of tigilanol tiglate and related epoxytiglianes

Cullen, Jason K., Boyle, Glen M., Yap, Pei-Yi, Elmlinger, Stefan, Simmons, Jacinta L., Broit, Natasa, Johns, Jenny, Ferguson, Blake, Maslovskaya, Lidia A., Savchenko, Andrei I., Mirzayans, Paul Malek, Porzelle, Achim, Bernhardt, Paul V., Gordon, Victoria A., Reddell, Paul W., Pagani, Alberto, Appendino, Giovanni, Parsons, Peter G. and Williams, Craig M. (2021). Activation of PKC supports the anticancer activity of tigilanol tiglate and related epoxytiglianes. Scientific Reports, 11 (1) 207, 207. doi: 10.1038/s41598-020-80397-9

Molecular approach to alkali-metal encapsulation by a Prussian Blue analogue FeII/CoIII cube in aqueous solution: a kineticomechanistic exchange study

Gonzálvez, Miguel A., Bernhardt, Paul V., Font-Bardia, Mercè, Gallen, Albert, Jover, Jesús, Ferrer, Montserrat and Martínez, Manuel (2021). Molecular approach to alkali-metal encapsulation by a Prussian Blue analogue FeII/CoIII cube in aqueous solution: a kineticomechanistic exchange study. Inorganic Chemistry, 60 (23) acs.inorgchem.1c03001, 18407-18422. doi: 10.1021/acs.inorgchem.1c03001

Bhimamycin J, a rare benzo[f]isoindole-dione alkaloid from the marine-derived actinomycete Streptomyces sp. MS180069

Song, Fuhang, Yang, Na, Khalil, Zeinab G., Salim, Angela A., Han, Jiahui, Bernhardt, Paul V., Lin, Rui, Xu, Xiuli and Capon, Robert J. (2021). Bhimamycin J, a rare benzo[f]isoindole-dione alkaloid from the marine-derived actinomycete Streptomyces sp. MS180069. Chemistry and Biodiversity, 18 (11) e2100674, e2100674. doi: 10.1002/cbdv.202100674

Bioinorganic systems responsive to the diatomic gases O2, NO, and CO: From biological sensors to therapy

Gonzaga de França Lopes, Luiz, Gouveia Júnior, Florêncio S., Karine Medeiros Holanda, Alda, Maria Moreira de Carvalho, Idalina, Longhinotti, Elisane, Paulo, Tércio F., Abreu, Dieric S., Bernhardt, Paul V., Gilles-Gonzalez, Marie-Alda, Cirino Nogueira Diógenes, Izaura and Henrique Silva Sousa, Eduardo (2021). Bioinorganic systems responsive to the diatomic gases O2, NO, and CO: From biological sensors to therapy. Coordination Chemistry Reviews, 445 214096, 214096. doi: 10.1016/j.ccr.2021.214096

Temperature and counterion dependent spin crossover in a hexaamineiron(II) complex

Connolly, Blake J. P., Brosius, Victor, Mertes, Nicole, Demidova, Caroline, Bilyj, Jessica K., Riley, Mark J. and Bernhardt, Paul V. (2021). Temperature and counterion dependent spin crossover in a hexaamineiron(II) complex. European Journal of Inorganic Chemistry, 2021 (38), 3938-3949. doi: 10.1002/ejic.202100560

Tandem oxidation-dehydrogenation of (hetero)arylated primary alcohols via perruthenate catalysis

Bettencourt, Christian J., Chow, Sharon, Moore, Peter W., Read, Christopher D. G., Jiao, Yanxiao, Bakker, Jan Peter, Zhao, Sheng, Bernhardt, Paul V. and Williams, Craig M. (2021). Tandem oxidation-dehydrogenation of (hetero)arylated primary alcohols via perruthenate catalysis. Australian Journal of Chemistry, 74 (9), 652-659. doi: 10.1071/ch21137

Does H3O+ really act as a ligand in the solid state?

Blackman, Allan G., Jelley, Rebecca E., Krenske, Elizabeth H., Gahan, Lawrence R. and Bernhardt, Paul V. (2021). Does H3O+ really act as a ligand in the solid state?. Inorganic Chemistry, 60 (17) acs.inorgchem.1c01485, 13071-13079. doi: 10.1021/acs.inorgchem.1c01485

A highly sensitive and stable electrochemical nitrate biosensor

Kalimuthu, Palraj, Kruse, Tobias and Bernhardt, Paul V. (2021). A highly sensitive and stable electrochemical nitrate biosensor. Electrochimica Acta, 386 138480, 138480. doi: 10.1016/j.electacta.2021.138480

Synthesis, isolation and characterisation of fluorinated‐benzimidazoisoquinoline regioisomers

Lim, Ting Xiang, Pierens, Gregory K., Bernhardt, Paul V., Ahamed, Muneer and Reutens, David C. (2021). Synthesis, isolation and characterisation of fluorinated‐benzimidazoisoquinoline regioisomers. Magnetic Resonance in Chemistry, 59 (11) mrc.5193, 1154-1159. doi: 10.1002/mrc.5193

Mapping the pathway to organocopper(II) complexes relevant to atom transfer radical polymerization

Gonzálvez, Miguel A., Harmer, Jeffrey R. and Bernhardt, Paul V. (2021). Mapping the pathway to organocopper(II) complexes relevant to atom transfer radical polymerization. Inorganic Chemistry, 60 (14) acs.inorgchem.1c01309, 10648-10655. doi: 10.1021/acs.inorgchem.1c01309

Electrochemical exploration of active Cu-based atom transfer radical polymerization catalysis through ligand modification

Melville, Jamie N. and Bernhardt, Paul V. (2021). Electrochemical exploration of active Cu-based atom transfer radical polymerization catalysis through ligand modification. Inorganic Chemistry, 60 (13) acs.inorgchem.1c01001, 1-11. doi: 10.1021/acs.inorgchem.1c01001

Experimental and theoretical approaches for the development of 4H-Chromene derivatives as inhibitors of tyrosinase

Canavieira, Luciana Morais, Brasil, Edikarlos Macedo, Silva, Thiago de Melo e, Borges, Rosivaldo dos Santos, Silva, José Rogério Araújo, Lameira, Jerônimo, Bernhardt, Paul V., Williams, Craig M. and Alves, Cláudio Nahum (2021). Experimental and theoretical approaches for the development of 4H-Chromene derivatives as inhibitors of tyrosinase. Molecular Simulation, 47 (9), 762-770. doi: 10.1080/08927022.2021.1926455

Deconstructing the electron transfer chain in a complex molybdoenzyme: assimilatory nitrate reductase from Neurospora crassa

Kalimuthu, Palraj, Kruse, Tobias and Bernhardt, Paul V. (2021). Deconstructing the electron transfer chain in a complex molybdoenzyme: assimilatory nitrate reductase from Neurospora crassa. Biochimica et Biophysica Acta. Bioenergetics, 1862 (3) 148358, 148358. doi: 10.1016/j.bbabio.2020.148358

Neobulgarones revisited: anti and syn bianthrones from an Australian mud dauber wasp nest-associated fungus, Penicillium sp. CMB-MD22

Elbanna, Ahmed H., Khalil, Zeinab G., Bernhardt, Paul V. and Capon, Robert J. (2021). Neobulgarones revisited: anti and syn bianthrones from an Australian mud dauber wasp nest-associated fungus, Penicillium sp. CMB-MD22. Journal of Natural Products, 84 (3) acs.jnatprod.0c01035, 762-770. doi: 10.1021/acs.jnatprod.0c01035

Amaurones A–K: polyketides from the fish gut-derived Fungus Amauroascus sp. CMB-F713

Wu, Taizong, Salim, Angela A., Bernhardt, Paul V. and Capon, Robert J. (2021). Amaurones A–K: polyketides from the fish gut-derived Fungus Amauroascus sp. CMB-F713. Journal of Natural Products, 84 (2) acs.jnatprod.0c01343, 474-482. doi: 10.1021/acs.jnatprod.0c01343

Understanding the mechanistic requirements for efficient and stereoselective alkene epoxidation by a cytochrome P450 enzyme

Coleman, Tom, Kirk, Alicia M., Chao, Rebecca R., Podgorski, Matthew N., Harbort, Joshua S., Churchman, Luke R., Bruning, John B., Bernhardt, Paul V., Harmer, Jeffrey R., Krenske, Elizabeth H., De Voss, James J. and Bell, Stephen G. (2021). Understanding the mechanistic requirements for efficient and stereoselective alkene epoxidation by a cytochrome P450 enzyme. ACS Catalysis, 11 (4), 1995-2010. doi: 10.1021/acscatal.0c04872

Active site architecture reveals coordination sphere flexibility and specificity determinants in a group of closely related molybdoenzymes

Struwe, Michel A., Kalimuthu, Palraj, Luo, Zhenyao, Zhong, Qifeng, Ellis, Daniel, Yang, Jing, Khadanand, K.C., Harmer, Jeffrey R., Kirk, Martin L., McEwan, Alastair G., Clement, Bernd, Bernhardt, Paul V., Kobe, Bostjan and Kappler, Ulrike (2021). Active site architecture reveals coordination sphere flexibility and specificity determinants in a group of closely related molybdoenzymes. Journal of Biological Chemistry, 296 100672, 1-16. doi: 10.1016/j.jbc.2021.100672

Nickel coordination chemistry of bis(dithiocarbazate) Schiff base ligands; metal and ligand centred redox reactions

Bilyj, Jessica K., Silajew, Nicole V. and Bernhardt, Paul V. (2021). Nickel coordination chemistry of bis(dithiocarbazate) Schiff base ligands; metal and ligand centred redox reactions. Dalton Transactions, 50 (2), 612-623. doi: 10.1039/d0dt03204b

Structural characterisation of new ionic liquids via X-ray crystallography

Ghorbani, Mahdi, Bernhardt, Paul V. and Simone, Michela I. (2020). Structural characterisation of new ionic liquids via X-ray crystallography. Journal of Molecular Liquids, 319 114091, 114091. doi: 10.1016/j.molliq.2020.114091

Crystal structure of 6-azido-6-deoxy-1,2-O-iso-propylidene-a-D-glucofuranose

Wood, Adam, Bernhardt, Paul V., van Altena, Ian and Simone, Michela I. (2020). Crystal structure of 6-azido-6-deoxy-1,2-O-iso-propylidene-a-D-glucofuranose. Acta Crystallographica Section E: Crystallographic Communications, 76 (10), 1653-1656. doi: 10.1107/S2056989020012438

Synthetic tigliane intermediates engage thiols to induce potent cell line selective anti‐cancer activity

Chow, Sharon, Krainz, Tanja, Bettencourt, Christian J., Broit, Natasa, Ferguson, Blake, Zhu, Mingzhao, Hull, Kenneth G., Pierens, Gregory K., Bernhardt, Paul V., Parsons, Peter G., Romo, Daniel, Boyle, Glen M. and Williams, Craig M. (2020). Synthetic tigliane intermediates engage thiols to induce potent cell line selective anti‐cancer activity. Chemistry: A European Journal, 26 (59) chem.202003221, 13372-13377. doi: 10.1002/chem.202003221

The fundamental importance of basic science: examples of high-impact discoveries from an international chemistry network

Lopes, Luiz G.F., Sadler, Peter J., Bernardes-Génisson, Vânia, Moura, José J.G., Chauvin, Remi, Bernhardt, Paul V. and Sousa, Eduardo H.S. (2020). The fundamental importance of basic science: examples of high-impact discoveries from an international chemistry network. Quimica Nova, 43 (8), 1-14. doi: 10.21577/0100-4042.20170584

Cytochrome c reductase is a key enzyme involved in the extracellular electron transfer pathway towards transition metal complexes in Pseudomonas putida

Lai, Bin, Bernhardt, Paul V. and Krömer, Jens O. (2020). Cytochrome c reductase is a key enzyme involved in the extracellular electron transfer pathway towards transition metal complexes in Pseudomonas putida. ChemSusChem, 13 (19) cssc.202001645, 5308-5317. doi: 10.1002/cssc.202001645

Kalparinol, a Salvialane (Isodaucane) sesquiterpenoid derived from native Australian dysphania species that suggests a putative biogenetic link to zerumbone

Tan, Yuen Ping, Savchenko, Andrei I., Agnew-Francis, Kylie A., Boyle, Glen M., Bernhardt, Paul V., Fraser, James A. and Williams, Craig M. (2020). Kalparinol, a Salvialane (Isodaucane) sesquiterpenoid derived from native Australian dysphania species that suggests a putative biogenetic link to zerumbone. Journal of Natural Products, 83 (5) acs.jnatprod.9b01039, 1473-1479. doi: 10.1021/acs.jnatprod.9b01039

Dysidealactams and dysidealactones: sesquiterpene glycinyl-lactams, imides, and lactones from a Dysidea sp. marine sponge collected in Southern Australia

Khushi, Shamsunnahar, Salim, Angela A., Elbanna, Ahmed H., Nahar, Laizuman, Bernhardt, Paul V. and Capon, Robert J. (2020). Dysidealactams and dysidealactones: sesquiterpene glycinyl-lactams, imides, and lactones from a Dysidea sp. marine sponge collected in Southern Australia. Journal of Natural Products, 83 (5) acs.jnatprod.0c00041, 1577-1584. doi: 10.1021/acs.jnatprod.0c00041

Biophysical techniques for distinguishing ligand binding modes in cytochrome P450 monooxygenases

Podgorski, Matthew N., Harbort, Joshua S., Coleman, Tom, Stok, Jeanette E., Yorke, Jake A., Wong, Luet-Lok, Bruning, John B., Bernhardt, Paul V., De Voss, James J., Harmer, Jeffrey R. and Bell, Stephen G. (2020). Biophysical techniques for distinguishing ligand binding modes in cytochrome P450 monooxygenases. Biochemistry, 59 (9) acs.biochem.0c00027, 1038-1050. doi: 10.1021/acs.biochem.0c00027

Humulene diepoxides from the Australian arid zone herb Dysphania: assignment of aged hops constituents

Tan, Yuen Ping, Agnew‐Francis, Kylie A., Hofmann, Julian, Savchenko, Andrei I., Lafontaine, Scott R., Boyle, Glen M., Bernhardt, Paul V., Fraser, James A., Shellhammer, Thomas H. and Williams, Craig M. (2020). Humulene diepoxides from the Australian arid zone herb Dysphania: assignment of aged hops constituents. Chemistry: A European Journal, 26 (7) chem.201904420, 1653-1660. doi: 10.1002/chem.201904420

Chrysosporazines F–M: P-glycoprotein inhibitory phenylpropanoid piperazines from an Australian marine fish derived fungus, Chrysosporium sp. CMB-F294

Mohamed, Osama G., Salim, Angela A., Khalil, Zeinab G., Elbanna, Ahmed H., Bernhardt, Paul V. and Capon, Robert J. (2020). Chrysosporazines F–M: P-glycoprotein inhibitory phenylpropanoid piperazines from an Australian marine fish derived fungus, Chrysosporium sp. CMB-F294. Journal of Natural Products, 83 (2) acs.jnatprod.9b01181, 497-504. doi: 10.1021/acs.jnatprod.9b01181

Copper complexes of benzoylacetone bis-thiosemicarbazones: metal and ligand based redox reactivity*

Bilyj, Jessica K., Harmer, Jeffrey R. and Bernhardt, Paul V. (2020). Copper complexes of benzoylacetone bis-thiosemicarbazones: metal and ligand based redox reactivity*. Australian Journal of Chemistry, 74 (1), 34-47. doi: 10.1071/ch20210

The oxidation-reduction and electrocatalytic properties of CO dehydrogenase from Oligotropha carboxidovorans

Kalimuthu, Palraj, Petitgenet, Mélanie, Niks, Dimitri, Dingwall, Stephanie, Harmer, Jeffrey R., Hille, Russ and Bernhardt, Paul V. (2020). The oxidation-reduction and electrocatalytic properties of CO dehydrogenase from Oligotropha carboxidovorans. Biochimica et Biophysica Acta - Bioenergetics, 1861 (1) 148118, 148118. doi: 10.1016/j.bbabio.2019.148118

A novel long‐range n to π* interaction secures the smallest known α‐helix in water

Hoang, Huy N., Wu, Chongyang, Hill, Timothy A., Dantas de Araujo, Aline, Bernhardt, Paul V., Liu, Ligong and Fairlie, David P. (2019). A novel long‐range n to π* interaction secures the smallest known α‐helix in water. Angewandte Chemie, 131 (52), 19049-19053. doi: 10.1002/ange.201911277

A spectroelectrochemical investigation of the heme-based sensor DevS from Mycobacterium tuberculosis: a redox versus oxygen sensor

Barreto, Giamwemberg A., Carepo, Marta S. P., Gondim, Ana C. S., Guimaraes, Wellinson G., Lopes, Luiz G. F., Bernhardt, Paul, Paulo, Tercio F., Sousa, Eduardo H. S. and Diogenes, Izaura C. N. (2019). A spectroelectrochemical investigation of the heme-based sensor DevS from Mycobacterium tuberculosis: a redox versus oxygen sensor. Febs Journal, 286 (21) febs.14974, 4278-4293. doi: 10.1111/febs.14974

En route to D-ring inverted phorbol esters

Chow, Sharon, Krainz, Tanja, Bernhardt, Paul V. and Williams, Craig M. (2019). En route to D-ring inverted phorbol esters. Organic Letters, 21 (21) acs.orglett.9b03379, 8761-8764. doi: 10.1021/acs.orglett.9b03379

A novel long-range n to π* interaction secures the smallest known α-helix in water

Hoang, Huy N., Wu, Chongyang, Hill, Timothy A., Dantas de Araujo, Aline, Bernhardt, Paul V., Liu, Ligong and Fairlie, David P. (2019). A novel long-range n to π* interaction secures the smallest known α-helix in water. Angewandte Chemie International Edition, 58 (52) ange.201911277, 18873-18877. doi: 10.1002/anie.201911277

Proton-assisted air oxidation mechanisms of iron(ii) bis-thiosemicarbazone complexes at physiological pH: a kinetico-mechanistic study

Gonzálvez, Miguel A., Algarra, Andrés G., Basallote, Manuel G., Bernhardt, Paul V., Fernández-Trujillo, María J. and Martínez, Manuel (2019). Proton-assisted air oxidation mechanisms of iron(ii) bis-thiosemicarbazone complexes at physiological pH: a kinetico-mechanistic study. Dalton Transactions, 48 (44), 16578-16587. doi: 10.1039/c9dt03557e

Antibacterial 5α-spirostane saponins from the fruit of Cordyline manners-suttoniae

Tran, Trong D., Olsson, Malin A., Choudhury, Md Abu, McMillan, David J., Cullen, Jason K., Parsons, Peter G., Bernhardt, Paul V., Reddell, Paul W. and Ogbourne, Steven M. (2019). Antibacterial 5α-spirostane saponins from the fruit of Cordyline manners-suttoniae. Journal of Natural Products, 82 (10) acs.jnatprod.9b00502, 2809-2817. doi: 10.1021/acs.jnatprod.9b00502

Ascorbyl and hydroxyl radical generation mediated by a copper complex adsorbed on gold

Romo, Adolfo I. B., Dibo, Vitória S., Abreu, Dieric S., Carepo, Marta S. P., Neira, Andrea C., Castillo, Ivan, Lemus, Luis, Nascimento, Otaciro R., Bernhardt, Paul V., Sousa, Eduardo H. S. and Diógenes, Izaura C. N. (2019). Ascorbyl and hydroxyl radical generation mediated by a copper complex adsorbed on gold. Dalton Transactions, 48 (37), 14128-14137. doi: 10.1039/c9dt01726g

Basimarols A, B, and C, Highly Oxygenated Pimarane Diterpenoids from Basilicum polystachyon

Tan, Yuen P., Xue, Yongbo, Savchenko, Andrei I., Houston, Sevan D., Modhiran, Naphak, McMillan, Christopher L. D., Boyle, Glen M., Bernhardt, Paul V., Young, Paul R., Watterson, Daniel and Williams, Craig M. (2019). Basimarols A, B, and C, Highly Oxygenated Pimarane Diterpenoids from Basilicum polystachyon. Journal of Natural Products, 82 (10) acs.jnatprod.9b00522, 2828-2834. doi: 10.1021/acs.jnatprod.9b00522

Chrysosporazines A–E: P-glycoprotein inhibitory piperazines from an Australian marine fish gastrointestinal tract-derived fungus, Chrysosporium sp. CMB-F214

Elbanna, Ahmed H., Khalil, Zeinab G., Bernhardt, Paul V. and Capon, Robert J. (2019). Chrysosporazines A–E: P-glycoprotein inhibitory piperazines from an Australian marine fish gastrointestinal tract-derived fungus, Chrysosporium sp. CMB-F214. Organic Letters, 21 (19) acs.orglett.9b03094, 8097-8100. doi: 10.1021/acs.orglett.9b03094

Computer modelling and synthesis of deoxy and monohydroxy analogues of a ribitylaminouracil bacterial metabolite that potently activates human T cells

Ler, Geraldine J. M., Xu, Weijun, Mak, Jeffrey Y. W., Liu, Ligong, Bernhardt, Paul V. and Fairlie, David P (2019). Computer modelling and synthesis of deoxy and monohydroxy analogues of a ribitylaminouracil bacterial metabolite that potently activates human T cells. Chemistry – A European Journal, 25 (68) chem.201903732, 15594-15608. doi: 10.1002/chem.201903732

Phenethylammonium bismuth halides: from single crystals to bulky-organic cation promoted thin-film deposition for potential optoelectronic applications

Ghasemi, Mehri, Lyu, Miaoqiang, Roknuzzaman, Md, Yun, Jung-Ho, Hao, Mengmeng, He, Dongxu, Bai, Yang, Chen, Peng, Bernhardt, Paul V., Ostrikov, Kostya (Ken) and Wang, Lianzhou (2019). Phenethylammonium bismuth halides: from single crystals to bulky-organic cation promoted thin-film deposition for potential optoelectronic applications. Journal of Materials Chemistry A, 7 (36), 20733-20741. doi: 10.1039/c9ta07454f

Scopularides revisited: molecular networking guided exploration of lipodepsipeptides in Australian marine fish gastrointestinal tract-derived fungi

Elbanna, Ahmed H., Khalil, Zeinab G., Bernhardt, Paul V. and Capon, Robert J. (2019). Scopularides revisited: molecular networking guided exploration of lipodepsipeptides in Australian marine fish gastrointestinal tract-derived fungi. Marine Drugs, 17 (8) 475, 475. doi: 10.3390/md17080475

Contemplating 1,2,4-thiadiazole-inspired cyclic peptide mimics: a computational investigation

Xie, Sida, Bernhardt, Paul V., Gahan, Lawrence R. and Williams, Craig M. (2019). Contemplating 1,2,4-thiadiazole-inspired cyclic peptide mimics: a computational investigation. Australian Journal of Chemistry, 72 (11), 894-899. doi: 10.1071/CH19248

Electrocatalysis of a europium‐dependent bacterial methanol dehydrogenase with its hysiological electron‐acceptor cytochrome cGJ

Kalimuthu, Palraj, Daumann, Lena J., Pol, Arjan, Op den Camp, Huub J. M. and Bernhardt, Paul V. (2019). Electrocatalysis of a europium‐dependent bacterial methanol dehydrogenase with its hysiological electron‐acceptor cytochrome cGJ. Chemistry – A European Journal, 25 (37) chem.201900525, 8760-8768. doi: 10.1002/chem.201900525

Trivalent copper stabilised by acetylacetone dithiocarbazate Schiff base ligands: structural, spectroscopic and electrochemical properties

Bilyj, Jessica K., Silajew, Nicole V., Hanson, Graeme R., Harmer, Jeffrey R. and Bernhardt, Paul V. (2019). Trivalent copper stabilised by acetylacetone dithiocarbazate Schiff base ligands: structural, spectroscopic and electrochemical properties. Dalton Transactions, 48 (41), 15501-15514. doi: 10.1039/c9dt02071c

The cubane paradigm in bioactive molecule discovery: further scope, limitations and the cyclooctatetraene complement

Houston, Sevan D., Fahrenhorst-Jones, Tyler, Xing, Hui, Chalmers, Benjamin A., Sykes, Melissa L., Stok, Jeanette E., Farfan Soto, Clementina, Burns, Jed M., Bernhardt, Paul V., De Voss, James J., Boyle, Glen M., Smith, Maree T., Tsanaktsidis, John, Savage, G. Paul, Avery, Vicky M. and Williams, Craig M. (2019). The cubane paradigm in bioactive molecule discovery: further scope, limitations and the cyclooctatetraene complement. Organic and Biomolecular Chemistry, 17 (28), 6790-6798. doi: 10.1039/c9ob01238a

Synthesis of 18F-radiolabeled diphenyl gallium dithiosemicarbazone using a novel halogen exchange method and in vivo biodistribution

Venkatachalam, T.K., Stimson, D.H.R., Bhalla, R., Mardon, K., Bernhardt, Paul.V. and Reutens, D.C. (2019). Synthesis of 18F-radiolabeled diphenyl gallium dithiosemicarbazone using a novel halogen exchange method and in vivo biodistribution. Journal of Labelled Compounds and Radiopharmaceuticals, 62 (7), 321-331. doi: 10.1002/jlcr.3746

Synthesis and characterisation of indium(iii) bis-thiosemicarbazone complexes: 18 F incorporation for PET imaging

Venkatachalam, Taracad K., Bernhardt, Paul V., Pierens, Gregory K., Stimson, Damion H. R., Bhalla, Rajiv and Reutens, David C. (2019). Synthesis and characterisation of indium(iii) bis-thiosemicarbazone complexes: 18 F incorporation for PET imaging. Australian Journal of Chemistry, 72 (5), 383-391. doi: 10.1071/CH18559

Cyclooctatetraene: a&nbsp;bioactive cubane paradigm complement

Xing, Hui, Houston, Sevan D., Chen, Xuejie, Ghassabian, Sussan, Fahrenhorst-Jones, Tyler, Kuo, Andy, Murray, Cody-Ellen P., Conn, Kyna-Anne, Jaeschke, Kara N., Jin, Da-Yun, Pasay, Cielo, Bernhardt, Paul V., Burns, Jed M., Tsanaktsidis, John, Savage, G. Paul, Boyle, Glen M., De Voss, James J., McCarthy, James, Walter, Gimme H., Burne, Thomas H. J., Smith, Maree T., Tie, Jian-Ke and Williams, Craig M. (2019). Cyclooctatetraene: a bioactive cubane paradigm complement. Chemistry: A European Journal, 25 (11), 2729-2734. doi: 10.1002/chem.201806277

Element 27-Cobalt

Bernhardt, Paul V. (2019). Element 27-Cobalt. Australian Journal of Chemistry, 72 (4), 241-243. doi: 10.1071/CH19060

Cyclooctatetraenes through valence isomerization of cubanes: scope and limitations

Houston, Sevan D., Xing, Hui, Bernhardt, Paul V., Vanden Berg, Timothy J., Tsanaktsidis, John, Savage, G. Paul and Williams, Craig M. (2019). Cyclooctatetraenes through valence isomerization of cubanes: scope and limitations. Chemistry: A European Journal, 25 (11), 2735-2739. doi: 10.1002/chem.201805124

The fate of copper catalysts in atom transfer radical chemistry

Zerk, Timothy J., Gahan, Lawrence R., Krenske, Elizabeth H. and Bernhardt, Paul V. (2019). The fate of copper catalysts in atom transfer radical chemistry. Polymer Chemistry, 10 (12), 1460-1470. doi: 10.1039/c8py01688g

Cover Feature: Hydrogen-Bonding Interactions in the Ley-Griffith Oxidation: Practical Considerations for the Synthetic Chemist (Eur. J. Org. Chem. 2-3/2019)

Moore, Peter W., Zerk, Timothy J., Burns, Jed M., Bernhardt, Paul V. and Williams, Craig M. (2018). Cover Feature: Hydrogen-Bonding Interactions in the Ley-Griffith Oxidation: Practical Considerations for the Synthetic Chemist (Eur. J. Org. Chem. 2-3/2019). European Journal of Organic Chemistry, 2019 (2-3), 230-230. doi: 10.1002/ejoc.201801822

Formation and reactivity of copper acetylacetone bis(thiosemicarbazone) complexes

Bilyj, Jessica K., Harmer, Jeffery R. and Bernhardt, Paul V. (2018). Formation and reactivity of copper acetylacetone bis(thiosemicarbazone) complexes. European Journal of Inorganic Chemistry, 2018 (43), 4731-4741. doi: 10.1002/ejic.201801002

Crystal structure of ethyl 2,4-dimethyl-1-phenyl-6-thioxo-1,6-dihydropyrimidine-5-carboxylate: the product from the reaction of ethyl 3-aminocrotonate, phenylisothiocyanate and acetic anhydride

Cossar, Peter J., Russell, Cecilia C., McCluskey, Siobhann N., Pope, Dylan, Bernhardt, Paul V. and McCluskey, Adam (2018). Crystal structure of ethyl 2,4-dimethyl-1-phenyl-6-thioxo-1,6-dihydropyrimidine-5-carboxylate: the product from the reaction of ethyl 3-aminocrotonate, phenylisothiocyanate and acetic anhydride. Journal of Chemical Crystallography, 48 (3), 91-95. doi: 10.1007/s10870-018-0714-6

Hydrogen-bonding interactions in the Ley-Griffith oxidation: practical considerations for the synthetic chemist

Moore, Peter W., Zerk, Timothy J., Burns, Jed M., Bernhardt, Paul V. and Williams, Craig M. (2018). Hydrogen-bonding interactions in the Ley-Griffith oxidation: practical considerations for the synthetic chemist. European Journal of Organic Chemistry, 2019 (2-3), 303-308. doi: 10.1002/ejoc.201800860

Kineticomechanistic study of the redox pH cycling processes occurring on a robust water-soluble cyanido-bridged mixed-valence {CoIII/FeII}2 square

Alcázar, Laura, Bernhardt, Paul V., Ferrer, Montserrat, Font-Bardia, Mercè, Gallen, Albert, Jover, Jesús, Martínez, Manuel, Peters, Jack and Zerk, Timothy J. (2018). Kineticomechanistic study of the redox pH cycling processes occurring on a robust water-soluble cyanido-bridged mixed-valence {CoIII/FeII}2 square. Inorganic Chemistry, 57 (14), 8465-8475. doi: 10.1021/acs.inorgchem.8b01147

Novel chelators based on adamantane-derived semicarbazones and hydrazones that target multiple hallmarks of Alzheimer's disease

Palanimuthu, Duraippandi, Wu, Zhixuan, Jansson, Patric J., Braidy, Nady, Bernhardt, Paul V., Richardson, Des R. and Kalinowski, Danuta S. (2018). Novel chelators based on adamantane-derived semicarbazones and hydrazones that target multiple hallmarks of Alzheimer's disease. Dalton Transactions, 47 (21), 7190-7205. doi: 10.1039/c8dt01099d

Electrocatalytic hydroxylation of sterols by steroid C25 dehydrogenase from Sterolibacterium denitrificans

Kalimuthu, Palraj, Wojtkiewicz, Agnieszka, Szaleniec, Maciej and Bernhardt, Paul V. (2018). Electrocatalytic hydroxylation of sterols by steroid C25 dehydrogenase from Sterolibacterium denitrificans. Chemistry: A European Journal, 24 (30), 7710-7717. doi: 10.1002/chem.201800616

Heteroatom-Interchanged Isomers of Lissoclinamide 5: Copper(II) Complexation, Halide Binding, and Biological Activity

Xie, Sida, Savchenko, Andrei I., Kerscher, Marion, Grange, Rebecca L., Krenske, Elizabeth H., Harmer, Jeffrey R., Bauer, Michelle J., Broit, Natasa, Watters, Dianne J., Boyle, Glen M., Bernhardt, Paul V., Parsons, Peter G., Comba, Peter, Gahan, Lawrence R. and Williams, Craig M. (2018). Heteroatom-Interchanged Isomers of Lissoclinamide 5: Copper(II) Complexation, Halide Binding, and Biological Activity. European Journal of Organic Chemistry, 2018 (12), 1465-1476. doi: 10.1002/ejoc.201701659

ATP3 and MTP3: easily prepared stable perruthenate salts for oxidation applications in synthesis

Moore, Peter W., Read, Christopher D. G., Bernhardt, Paul V. and Williams, Craig M. (2018). ATP3 and MTP3: easily prepared stable perruthenate salts for oxidation applications in synthesis. Chemistry: A European Journal, 24 (18), 4556-4561. doi: 10.1002/chem.201800531

Spin Crossover in a Hexaamineiron(II) Complex: Experimental Confirmation of a Computational Prediction

Bernhardt, Paul V., Bilyj, Jessica K., Brosius, Victor, Chernyshov, Dmitry, Deeth, Robert J., Foscato, Marco, Jensen, Vidar R., Mertes, Nicole, Riley, Mark J. and Törnroos, Karl W. (2018). Spin Crossover in a Hexaamineiron(II) Complex: Experimental Confirmation of a Computational Prediction. Chemistry (Weinheim an der Bergstrasse, Germany), 24 (20), 5082-5085. doi: 10.1002/chem.201705439

Isomerism and reactivity of nickel(ii) acetylacetonate bis(thiosemicarbazone) complexes

Bilyj, Jessica K., Riley, Mark J. and Bernhardt, Paul V. (2018). Isomerism and reactivity of nickel(ii) acetylacetonate bis(thiosemicarbazone) complexes. Dalton Transactions (Cambridge, England : 2003), 47 (6), 2018-2030. doi: 10.1039/c7dt04337f

NMR, X-Ray Crystal Structure Studies and Mechanism for Formation of a Novel Di-gallium Complex and 5-Methoxy-4,5,6-triphenyl-4,5-dihydro-1,2,4-triazene-3(2H)-thione

Venkatachalam, T. K., Bernhardt, Paul V., Pierens, G. K. and Reutens, D. C. (2018). NMR, X-Ray Crystal Structure Studies and Mechanism for Formation of a Novel Di-gallium Complex and 5-Methoxy-4,5,6-triphenyl-4,5-dihydro-1,2,4-triazene-3(2H)-thione. Journal of Chemical Crystallography, 49 (3), 131-138. doi: 10.1007/s10870-018-0745-z

The central active site arginine in sulfite oxidizing enzymes alters kinetic properties by controlling electron transfer and redox interactions

Hsiao, Ju-Chun, McGrath, Aaron P., Kielmann, Linda, Kalimuthu, Palraj, Darain, Farzana, Bernhardt, Paul V., Harmer, Jeffrey, Lee, Mihwa, Meyers, Kimberley, Maher, Megan J. and Kappler, Ulrike (2018). The central active site arginine in sulfite oxidizing enzymes alters kinetic properties by controlling electron transfer and redox interactions. Biochimica et Biophysica Acta - Bioenergetics, 1859 (1), 19-27. doi: 10.1016/j.bbabio.2017.10.001

Redox-coupled structural changes in copper chemistry: Implications for atom transfer catalysis

Zerk, Timothy J. and Bernhardt, Paul V. (2017). Redox-coupled structural changes in copper chemistry: Implications for atom transfer catalysis. Coordination Chemistry Reviews, 375, 173-190. doi: 10.1016/j.ccr.2017.11.016

Chemical Diversity from a Chinese Marine Red Alga, Symphyocladia latiuscula

Xu, Xiuli, Yang, Haijin, Khalil, Zeinab G, Yin, Liyuan, Xiao, Xue, Neupane, Pratik, Bernhardt, Paul V, Salim, Angela A, Song, Fuhang and Capon, Robert J (2017). Chemical Diversity from a Chinese Marine Red Alga, Symphyocladia latiuscula. Marine drugs, 15 (12) 374, 1-10. doi: 10.3390/md15120374

Elucidating the mechanism of the Ley-Griffith (TPAP) alcohol oxidation

Zerk, Timothy J., Moore, Peter W., Harbort, Joshua S., Chow, Sharon, Byrne, Lindsay, Koutsantonis, George A., Harmer, Jeffrey R., Martinez, Manuel, Williams, Craig M. and Bernhardt, Paul V. (2017). Elucidating the mechanism of the Ley-Griffith (TPAP) alcohol oxidation. Chemical Science, 8 (12), 8435-8442. doi: 10.1039/c7sc04260d

A nanoporous cytochrome c film with highly ordered porous structure for sensing of toxic vapors

Lawrence, Geoffrey, Kalimuthu, Palraj, Benzigar, Mercy, Shelat, Kinnari J., Lakhi, Kripal S., Park, Dae-Hwan, Ji, Qingmin, Ariga, Katsuhiko, Bernhardt, Paul V. and Vinu, Ajayan (2017). A nanoporous cytochrome c film with highly ordered porous structure for sensing of toxic vapors. Advanced Materials, 29 (42) 1702295, 1702295. doi: 10.1002/adma.201702295

Kinetico-mechanistic Study on the Oxidation of Biologically Active Iron(II) Bis(thiosemicarbazone) Complexes by Air. Importance of NH···O2 Interactions As Established by Activation Volumes

Bernhardt, Paul V, Gonzálvez, Miguel A and Martínez, Manuel (2017). Kinetico-mechanistic Study on the Oxidation of Biologically Active Iron(II) Bis(thiosemicarbazone) Complexes by Air. Importance of NH···O2 Interactions As Established by Activation Volumes. Inorganic chemistry, 56 (22), 14284-14290. doi: 10.1021/acs.inorgchem.7b02381

A Novel Strategy to Introduce 18F, a Positron Emitting Radionuclide, into a Gallium Nitrate Complex: Synthesis, NMR, X-Ray Crystal Structure, and Preliminary Studies on Radiolabelling with 18F

Venkatachalam, Taracad K., Bernhardt, Paul V., Stimson, Damion H. R., Pierens, Gregory K., Bhalla, Rajiv and Reutens, David C. (2017). A Novel Strategy to Introduce 18F, a Positron Emitting Radionuclide, into a Gallium Nitrate Complex: Synthesis, NMR, X-Ray Crystal Structure, and Preliminary Studies on Radiolabelling with 18F. Australian Journal of Chemistry, 71 (3), 81-86. doi: 10.1071/CH17334

Human mitochondrial amidoxime reducing component (mARC): An electrochemical method for identifying new substrates and inhibitors

Kalimuthu, Palraj, Havemeyer, Antje, Clement, Bernd, Kubitza, Christian, Scheidig, Axel J. and Bernhardt, Paul V. (2017). Human mitochondrial amidoxime reducing component (mARC): An electrochemical method for identifying new substrates and inhibitors. Electrochemistry Communications, 84, 90-93. doi: 10.1016/j.elecom.2017.10.003

Bioelectrocatalysis of sulfite dehydrogenase from Sinorhizobium meliloti with its physiological cytochrome electron partner

Kalimuthu, Palraj, Hsiao, Ju-Chun, Nair, Remya Purushothaman, Kappler, Ulrike and Bernhardt, Paul V. (2017). Bioelectrocatalysis of sulfite dehydrogenase from Sinorhizobium meliloti with its physiological cytochrome electron partner. ChemElectroChem, 4 (12), 3163-3170. doi: 10.1002/celc.201700838

Chitosan-promoted direct electrochemistry of human sulfite oxidase

Kalimuthu, Palraj, Belaidi, Abdel A., Schwarz, Guenter and Bernhardt, Paul V. (2017). Chitosan-promoted direct electrochemistry of human sulfite oxidase. Journal of Physical Chemistry B, 121 (39), 9149-9159. doi: 10.1021/acs.jpcb.7b06712

A novel class of thiosemicarbazones show multi-functional activity for the treatment of Alzheimer's disease

Palanimuthu, Duraippandi, Poon, Rachal, Sahni, Sumit, Anjum, Rukhsana, Hibbs, David, Lin, Hsuan-Yu, Bernhardt, Paul V., Kalinowski, Danuta S. and Richardson, Des R. (2017). A novel class of thiosemicarbazones show multi-functional activity for the treatment of Alzheimer's disease. European Journal of Medicinal Chemistry, 139, 612-632. doi: 10.1016/j.ejmech.2017.08.021

Predicting and experimental evaluating bio-electrochemical synthesis — A case study with Clostridium kluyveri

Koch, Christin, Kuchenbuch, Anne, Kracke, Frauke, Bernhardt, Paul V., Krömer, Jens and Harnisch, Falk (2017). Predicting and experimental evaluating bio-electrochemical synthesis — A case study with Clostridium kluyveri. Bioelectrochemistry, 118, 114-122. doi: 10.1016/j.bioelechem.2017.07.009

Erratum to: Anoxic metabolism and biochemical production in Pseudomonas putida F1 driven by a bioelectrochemical system

Lai, Bin, Yu, Shiqin, Bernhardt, Paul V., Rabaey, Korneel, Virdis, Bernardino and Kroemer, Jens O. (2017). Erratum to: Anoxic metabolism and biochemical production in Pseudomonas putida F1 driven by a bioelectrochemical system. Biotechnology for Biofuels, 10 (1) 155, 155. doi: 10.1186/s13068-017-0843-8

Asymmetric sequential Cu-catalyzed 1,6/1,4-conjugate additions of hard nucleophiles to cyclic dienones: determination of absolute configurations and origins of enantioselectivity

Blons, Charlie, Morin, Marie S. T., Schmid, Thibault E., Vives, Thomas, Colombel-Rouen, Sophie, Basle, Olivier, Reynaldo, Thibault, Covington, Cody L., Halbert, Stephanie, Cuskelly, Sean N., Bernhardt, Paul V., Williams, Craig M., Crassous, Jeanne, Polavarapu, Prasad L., Crevisy, Christophe, Gerard, Helene and Mauduit, Marc (2017). Asymmetric sequential Cu-catalyzed 1,6/1,4-conjugate additions of hard nucleophiles to cyclic dienones: determination of absolute configurations and origins of enantioselectivity. Chemistry-A European Journal, 23 (31), 7515-7525. doi: 10.1002/chem.201606034

Cover Picture: Towards the Total Synthesis of Gedunin: Construction of the Fully Elaborated ABC Ring System (Asian J. Org. Chem. 5/2017)

Pinkerton, David M., Bernhardt, Paul V., Savage, G. Paul and Williams, Craig M. (2017). Cover Picture: Towards the Total Synthesis of Gedunin: Construction of the Fully Elaborated ABC Ring System (Asian J. Org. Chem. 5/2017). Asian Journal of Organic Chemistry, 6 (5), 475-475. doi: 10.1002/ajoc.201700182

Organo-copper(II) complexes as products of radical atom transfer

Zerk, Timothy J. and Bernhardt, Paul V. (2017). Organo-copper(II) complexes as products of radical atom transfer. Inorganic Chemistry, 56 (10), 5784-5792. doi: 10.1021/acs.inorgchem.7b00402

Inhibition of Tyrosinase by 4H-Chromene Analogues: Synthesis, Kinetic Studies and Computational Analysis

Brasil, Edikarlos M., Canavieira, Luciana M., Cardoso, Érica T. C., Silva, Edilene O., Lameira, Jeronimo, Nascimento, Jose L. M., Eifler-Lima, Vera L., de Matos Macchi, Barbarella, Sriram, Dharmarajan, Bernhardt, Paul V., Silva, Jose Rogerio Araujo, Williams, Craig M. and Alves, Claudio N. (2017). Inhibition of Tyrosinase by 4H-Chromene Analogues: Synthesis, Kinetic Studies and Computational Analysis. Chemical Biology and Drug Design, 90 (5), 804-810. doi: 10.1111/cbdd.13001

Mediated catalytic voltammetry of holo and heme-free human sulfite oxidases

Kalimuthu, Palraj, Belaidi, Abdel A., Schwarz, Guenter and Bernhardt, Paul V. (2017). Mediated catalytic voltammetry of holo and heme-free human sulfite oxidases. ChemElectroChem, 4 (4), 947-956. doi: 10.1002/celc.201600685

Synthesis and X-ray Crystal Structure of 2 and 4-Trifluoromethyl Substituted Phenyl Semicarbazone and Thiosemicarbazone

Venkatachalam, T. K., Bernhardt, P. V., Pierens, G. K. and Reutens, D. C. (2017). Synthesis and X-ray Crystal Structure of 2 and 4-Trifluoromethyl Substituted Phenyl Semicarbazone and Thiosemicarbazone. Journal of Chemical Crystallography, 47 (1), 30-39. doi: 10.1007/s10870-017-0677-z

Towards the total synthesis of gedunin: construction of the fully elaborated ABC ring system

Pinkerton, David M., Bernhardt, Paul V., Savage, G. Paul and Williams, Craig M. (2017). Towards the total synthesis of gedunin: construction of the fully elaborated ABC ring system. Asian Journal of Organic Chemistry, 6 (5), 583-597. doi: 10.1002/ajoc.201700013

Gaining synthetic appreciation for the gedunin ABC ring system

Pinkerton, David M., Vanden Berg, Timothy J., Bernhardt, Paul V. and Williams, Craig M. (2017). Gaining synthetic appreciation for the gedunin ABC ring system. Chemistry - A European Journal, 23 (10), 2282-2285. doi: 10.1002/chem.201605751

Hydroxyl radicals via collision-induced dissociation of trimethylammonium benzyl alcohols

Moore, Peter W., Hooker, Jordan P., Zavra, Athanasios, Khairallah, George N., Krenske, Elizabeth H., Bernhardt, Paul V., Quach, Gina, Moore, Evan G., O’Hair, Richard A. J. and William, Craig M. (2017). Hydroxyl radicals via collision-induced dissociation of trimethylammonium benzyl alcohols. Australian Journal of Chemistry, 70 (4), 397-406. doi: 10.1071/CH16602

Cobalt cage complexes as mediators of protein electron transfer

He, Felix M. C. and Bernhardt, Paul V. (2016). Cobalt cage complexes as mediators of protein electron transfer. Journal of Biological Inorganic Chemistry, 22 (5), 775-788. doi: 10.1007/s00775-016-1427-y

Redox dependent metabolic shift in Clostridium autoethanogenum by extracellular electron supply

Kracke, Frauke, Virdis, Bernardino, Bernhardt, Paul V., Rabaey, Korneel and Kromer, Jens O. (2016). Redox dependent metabolic shift in Clostridium autoethanogenum by extracellular electron supply. Biotechnology for Biofuels, 9 (1) 249, 249. doi: 10.1186/s13068-016-0663-2

A novel, molybdenum-containing methionine sulfoxide reductase supports survival of Haemophilus influenzae in an in vivo model of infection

Dhouib, Rabeb, Othman, Dk. Seti Maimonah Pg, Lin, Victor, Lai, Xuanjie J., Wijesinghe, Hewa G. S., Essilfie, Ama-Tawiah, Davis, Amanda, Nasreen, Marufa, Bernhardt, Paul V., Hansbro, Philip M., McEwan, Alastair G. and Kappler, Ulrike (2016). A novel, molybdenum-containing methionine sulfoxide reductase supports survival of Haemophilus influenzae in an in vivo model of infection. Frontiers in Microbiology, 7 (NOV) 1743, 1743. doi: 10.3389/fmicb.2016.01743

Synthesis, structures and spectroscopic properties of some tin(IV) complexes of the 2-acetylpyrazine Schiff bases of S-methyl- and S-benzyldithiocarbazates

Hamid, Malai Haniti S. A., Said, Ampuan Norhidayati A. H., Mirza, Aminul Huq, Karim, Mohammad Rezaul, Arifuzzaman, Md., Akbar Ali, Mohammad and Bernhardt, Paul V. (2016). Synthesis, structures and spectroscopic properties of some tin(IV) complexes of the 2-acetylpyrazine Schiff bases of S-methyl- and S-benzyldithiocarbazates. Inorganica Chimica Acta, 453, 742-750. doi: 10.1016/j.ica.2016.09.038

A kinetico-mechanistic study on CuII deactivators employed in atom transfer radical polymerization

Zerk, Timothy J., Martinez, Manuel and Bernhardt, Paul V. (2016). A kinetico-mechanistic study on CuII deactivators employed in atom transfer radical polymerization. Inorganic Chemistry, 55 (19), 9848-9857. doi: 10.1021/acs.inorgchem.6b01700

Identification, synthesis, and biological evaluation of the major human metabolite of NLRP3 inflammasome inhibitor MCC950

Salla, Manohar, Butler, Mark S., Pelingon, Ruby, Kaeslin, Geraldine, Croker, Daniel E., Reid, Janet C., Baek, Jong-Min, Bernhardt, Paul V., Gillam, Elizabeth M. J., Cooper, Matthew A. and Robertson, Avril A. B. (2016). Identification, synthesis, and biological evaluation of the major human metabolite of NLRP3 inflammasome inhibitor MCC950. ACS Medicinal Chemistry Letters, 7 (12), 1034-1038. doi: 10.1021/acsmedchemlett.6b00198

Structure-activity relationships of di-2-pyridylketone, 2-benzoylpyridine, and 2-acetylpyridine thiosemicarbazones for overcoming Pgp-mediated drug resistance

Stacy, Alexandra E., Palanimuthu, Duraippandi, Bernhardt, Paul V., Kalinowski, Danuta S., Jansson, Patric J. and Richardson, Des R. (2016). Structure-activity relationships of di-2-pyridylketone, 2-benzoylpyridine, and 2-acetylpyridine thiosemicarbazones for overcoming Pgp-mediated drug resistance. Journal of Medicinal Chemistry, 59 (18), 8601-8620. doi: 10.1021/acs.jmedchem.6b01050

Heteronuclear NMR spectroscopic investigations of gallium complexes of substituted thiosemicarbazones including x-ray crystal structure, a new halogen exchange strategy, and 18F radiolabelling

Venkatachalam, T. K., Pierens, G. K., Bernhardt, Paul. V., Stimson, D. H. R., Bhalla, R., Lambert, L. and Reutens, D. C. (2016). Heteronuclear NMR spectroscopic investigations of gallium complexes of substituted thiosemicarbazones including x-ray crystal structure, a new halogen exchange strategy, and 18F radiolabelling. Australian Journal of Chemistry, 69 (9), 1033-1048. doi: 10.1071/CH16044

The heme-based oxygen sensor Rhizobium etli FixL: influence of auxiliary ligands on heme redox potential and implications on the enzyme activity

Honorio-Felício, Nathalie, Carepo, Marta S. P., de F. Paulo, Tércio, de França Lopes, Luiz Gonzaga, Sousa, Eduardo H. S., Diógenes, Izaura C. N. and Bernhardt, Paul V. (2016). The heme-based oxygen sensor Rhizobium etli FixL: influence of auxiliary ligands on heme redox potential and implications on the enzyme activity. Journal of Inorganic Biochemistry, 164, 34-41. doi: 10.1016/j.jinorgbio.2016.08.009

Fungal biotransformation of tetracycline antibiotics

Shang, Zhuo, Salim, Angela A., Khalil, Zeinab, Bernhardt, Paul V. and Capon, Robert J. (2016). Fungal biotransformation of tetracycline antibiotics. Journal of Organic Chemistry, 81 (15), 6186-6194. doi: 10.1021/acs.joc.6b01272

Zinc(II)–thiosemicarbazone complexes are localized to the lysosomal compartment where they transmetallate with copper ions to induce cytotoxicity

Stacy, Alexandra E., Palanimuthu, Duraippandi, Bernhardt, Paul V., Kalinowski, Danuta S., Jansson, Patric J. and Richardson, Des R. (2016). Zinc(II)–thiosemicarbazone complexes are localized to the lysosomal compartment where they transmetallate with copper ions to induce cytotoxicity. Journal of Medicinal Chemistry, 59 (10), 4965-4984. doi: 10.1021/acs.jmedchem.6b00238

Effects of mutations in active site heme ligands on the spectroscopic and catalytic properties of SoxAX cytochromes

Kilmartin, James R., Bernhardt, Paul V., Dhouib, Rabeb, Hanson, Graeme R., Riley, Mark J. and Kappler, Ulrike (2016). Effects of mutations in active site heme ligands on the spectroscopic and catalytic properties of SoxAX cytochromes. Journal of Inorganic Biochemistry, 162, 309-318. doi: 10.1016/j.jinorgbio.2016.04.015

Synthesis, characterization and biological activities of semicarbazones and their copper complexes

Venkatachalam, Taracad K., Bernhardt, Paul V., Noble, Chris J., Fletcher, Nicholas, Pierens, Gregory K., Thurecht, Kris J. and Reutens, David C. (2016). Synthesis, characterization and biological activities of semicarbazones and their copper complexes. Journal of Inorganic Biochemistry, 162, 295-308. doi: 10.1016/j.jinorgbio.2016.04.006

Direct electrochemistry of nitrate reductase from the fungus Neurospora crassa

Kalimuthu, Palraj, Ringel, Phillip, Kruse, Tobias and Bernhardt, Paul V. (2016). Direct electrochemistry of nitrate reductase from the fungus Neurospora crassa. Biochimica et Biophysica Acta. Bioenergetics, 1857 (9), 1506-1513. doi: 10.1016/j.bbabio.2016.04.001

Organic–inorganic bismuth (III)-based material: A lead-free, air-stable and solution-processable light-absorber beyond organolead perovskites

Lyu, Miaoqiang, Yun, Jung-Ho, Cai, Molang, Jiao, Yalong, Bernhardt, Paul V., Zhang, Meng, Wang, Qiong, Du, Aijun, Wang, Hongxia, Liu, Gang and Wang, Lianzhou (2016). Organic–inorganic bismuth (III)-based material: A lead-free, air-stable and solution-processable light-absorber beyond organolead perovskites. Nano Research, 9 (3), 692-702. doi: 10.1007/s12274-015-0948-y

Frontispiece: Validating Eaton's Hypothesis: Cubane as a Benzene Bioisostere

Chalmers, Benjamin A., Xing, Hui, Houston, Sevan, Clark, Charlotte, Ghassabian, Sussan, Kuo, Andy, Cao, Benjamin, Reitsma, Andrea, Murray, Cody-Ellen P., Stok, Jeanette E., Boyle, Glen M., Pierce, Carly J., Littler, Stuart W., Winkler, David A., Bernhardt, Paul V., Pasay, Cielo, De Voss, James J., McCarthy, James, Parsons, Peter G., Walter, Gimme H., Smith, Maree T., Cooper, Helen M., Nilsson, Susan K., Tsanaktsidis, John, Savage, G. Paul and Williams, Craig M. (2016). Frontispiece: Validating Eaton's Hypothesis: Cubane as a Benzene Bioisostere. Angewandte Chemie International Edition, 55 (11), 8359-8359. doi: 10.1002/anie.201681161

Anoxic metabolism and biochemical production in Pseudomonas putida F1 driven by a bioelectrochemical system

Lai, Bin, Yu, Shiqin, Bernhardt, Paul V., Rabaey, Korneel, Virdis, Bernadino and Krömer, Jens O. (2016). Anoxic metabolism and biochemical production in Pseudomonas putida F1 driven by a bioelectrochemical system. Biotechnology for Biofuels, 9 (1) 39, 39.1-39.13. doi: 10.1186/s13068-016-0452-y

Validating Eaton's hypothesis: cubane as a benzene bioisostere

Chalmers, Benjamin A., Xing, Hui, Houston, Sevan, Clark, Charlotte, Ghassabian, Sussan, Kuo, Andy, Cao, Benjamin, Reitsma, Andrea, Murray, Cody-Ellen P., Stok, Jeanette E., Boyle, Glen M., Pierce, Carly J., Littler, Stuart W., Winkler, David A., Bernhardt, Paul V., Pasay, Cielo, De Voss, James J., McCarthy, James, Parsons, Peter G., Walter, Gimme H., Smith, Maree T., Cooper, Helen M., Nilsson, Susan K., Tsanaktsidis, John, Savage, G. Paul and Williams, Craig M. (2016). Validating Eaton's hypothesis: cubane as a benzene bioisostere. Angewandte Chemie (International Edition), 55 (11), 3580-3585. doi: 10.1002/anie.201510675

SET-LRP of NIPAM in water via in situ reduction of Cu(II) to Cu(0) with NaBH4

Gavrilov, Mikhail, Zerk, Timothy J., Bernhardt, Paul V., Percec, Virgil and Monteiro, Michael J. (2016). SET-LRP of NIPAM in water via in situ reduction of Cu(II) to Cu(0) with NaBH4. Polymer Chemistry, 7 (4), 933-939. doi: 10.1039/c5py01855b

Low potential catalytic voltammetry of human sulfite oxidase

Kalimuthu, Palraj, Belaidi, Abdel A., Schwarz, Guenter and Bernhardt, Paul V. (2016). Low potential catalytic voltammetry of human sulfite oxidase. Electrochimica Acta, 199, 280-289. doi: 10.1016/j.electacta.2016.01.181

Novel mechanism of cytotoxicity for the selective selenosemicarbazone, 2-acetylpyridine 4,4-dimethyl-3-selenosemicarbazone (Ap44mSe): lysosomal membrane permeabilization

Al-Eisawi, Zaynab, Stefani, Christian, Jansson, Patric J., Arvind, Akanksha, Sharpe, Philip C., Basha, Maram T., Iskander, George M., Kumar, Naresh, Kovacevic, Zaklina, Lane, Darius J. R., Sahni, Sumit, Bernhardt, Paul V., Richardson, Des R. and Kalinowski, Danuta S. (2016). Novel mechanism of cytotoxicity for the selective selenosemicarbazone, 2-acetylpyridine 4,4-dimethyl-3-selenosemicarbazone (Ap44mSe): lysosomal membrane permeabilization. Journal of Medicinal Chemistry, 59 (1), 294-312. doi: 10.1021/acs.jmedchem.5b01399

Kinetico-mechanistic studies on methemoglobin generation by biologically active thiosemicarbazone iron(III) complexes

Basha, Maram T., Bordini, Jeane, Richardson, Des R., Martinez, Manuel and Bernhardt, Paul V. (2016). Kinetico-mechanistic studies on methemoglobin generation by biologically active thiosemicarbazone iron(III) complexes. Journal of Inorganic Biochemistry, 162, 326-333. doi: 10.1016/j.jinorgbio.2015.12.004

N-Oxides rescue Ru(v) in catalytic Griffith-Ley (TPAP) alcohol oxidations

Zerk, Timothy J., Moore, Peter W., Williams, Craig M. and Bernhardt, Paul V. (2016). N-Oxides rescue Ru(v) in catalytic Griffith-Ley (TPAP) alcohol oxidations. Chemical Communications, 52 (67), 10301-10304. doi: 10.1039/C6CC05440D

Structural basis of interprotein electron transfer in bacterial sulfite oxidation

McGrath, Aaron P., Laming, Elise L., Casas Garcia, G. Patricia, Kvansakul, Marc, Guss, J. Mitchell, Trewhella, Jill, Calmes, Benoit, Bernhardt, Paul V.,, Hanson, Graeme R.,, Kappler, Ulrike and Maher, Megan J. (2015). Structural basis of interprotein electron transfer in bacterial sulfite oxidation. eLife, 4 (e09066) e09066, 1-26. doi: 10.7554/eLife.09066

Viridicatumtoxins: Expanding on a Rare Tetracycline Antibiotic Scaffold

Shang, Zhuo, Salim, Angela A., Khalil, Zeinab, Quezada, Michelle, Bernhardt, Paul V. and Capon, Robert J. (2015). Viridicatumtoxins: Expanding on a Rare Tetracycline Antibiotic Scaffold. Journal of Organic Chemistry, 80 (24), 12501-12508. doi: 10.1021/acs.joc.5b02367

Rhodium-Catalyzed [4+3] Cycloaddition to Furans: Direct Access to Functionalized Bicyclo[5.3.0]decane Derivatives

Krainz, Tanja, Chow, Sharon, Korica, Natasa, Bernhardt, Paul V., Boyle, Glen M., Parsons, Peter G., Davies, Huw M. L. and Williams, Craig M. (2015). Rhodium-Catalyzed [4+3] Cycloaddition to Furans: Direct Access to Functionalized Bicyclo[5.3.0]decane Derivatives. European Journal of Organic Chemistry, 2016 (1), 41-44. doi: 10.1002/ejoc.201501271

Engineering PQQ-glucose dehydrogenase into an allosteric electrochemical Ca2+ sensor

Guo, Zhong, Johnston, Wayne A., Stein, Viktor, Kalimuthu, Palraj, Perez-Alcala, Siro, Bernhardt, Paul V. and Alexandrov, Kirill (2015). Engineering PQQ-glucose dehydrogenase into an allosteric electrochemical Ca2+ sensor. Chemical Communications, 52 (3), 1-4. doi: 10.1039/C5CC07824E

An approach to more accurate model systems for purple acid phosphatases (PAPs)

Bernhardt, Paul V., Bosch, Simone, Comba, Peter, Gahan, Lawrence R., Hanson, Graeme R., Mereacre, Valeriu, Noble, Christopher J., Powell, Annie K., Schenk, Gerhard and Wadepohl, Hubert (2015). An approach to more accurate model systems for purple acid phosphatases (PAPs). Inorganic Chemistry, 54 (15), 7249-7263. doi: 10.1021/acs.inorgchem.5b00628

New PKS-NRPS tetramic acids and pyridinone from an Australian marine-derived fungus, Chaunopycnis sp.

Shang, Zhuo, Li, Li, Esposito, Breno P., Salim, Angela A., Khalil, Zeinab G., Quezada, Michelle, Bernhardt, Paul V. and Capon, Robert J. (2015). New PKS-NRPS tetramic acids and pyridinone from an Australian marine-derived fungus, Chaunopycnis sp.. Organic and Biomolecular Chemistry, 13 (28), 7795-7802. doi: 10.1039/c5ob01058f

Biosynthetic insights provided by unusual sesterterpenes from the medicinal herb Aletris farinosa

Challinor, Victoria L., Johnston, Ryne C., Bernhardt, Paul V., Lehmann, Reginald P., Krenske, Elizabeth H. and De Voss, James J. (2015). Biosynthetic insights provided by unusual sesterterpenes from the medicinal herb Aletris farinosa. Chemical Science, 6 (10), 5740-5745. doi: 10.1039/c5sc02056e

Antimalarial isocyano and isothiocyanato sesquiterpenes with tri- and bicyclic skeletons from the nudibranch Phyllidia ocellata

White, Andrew M., Pierens, Gregory K., Skinner-Adams, Tina, Andrews, Katherine T., Bernhardt, Paul V., Krenske, Elizabeth H., Mollo, Ernesto and Garson, Mary J. (2015). Antimalarial isocyano and isothiocyanato sesquiterpenes with tri- and bicyclic skeletons from the nudibranch Phyllidia ocellata. Journal of Natural Products, 78 (6), 1422-1427. doi: 10.1021/acs.jnatprod.5b00354

Synthesis and characterization of three amino-functionalized metal-organic frameworks based on 2-aminoterphthalic ligand

Yang, Ying, Lin, Rijia, Ge, Lei, Hou, Lei, Bernhardt, Paul V., Rufford, Thomas, Wang, Shaobin, Rudolph, Victor, Wang, Yaoyu and Zhu, Zhonghua (2015). Synthesis and characterization of three amino-functionalized metal-organic frameworks based on 2-aminoterphthalic ligand. Dalton Transactions, 44 (17), 8190-8197. doi: 10.1039/c4dt03927k

Heteronuclear NMR spectroscopic investigations of hydrogen bonding in 2-(benzo[d]thiazole-2'-yl)-N-alkylanilines

Venkatachalam, T. K., Pierens, G. K., Bernhardt, P. V. and Reutens, D. C. (2015). Heteronuclear NMR spectroscopic investigations of hydrogen bonding in 2-(benzo[d]thiazole-2'-yl)-N-alkylanilines. Magnetic Resonance in Chemistry, 53 (6), 448-453. doi: 10.1002/mrc.4228

Molybdenum and tungsten enzymes: from biology to chemistry and back

Moura, Jose J.G, Bernhardt, Paul V, Maia, Luisa B and Gonzalez, Pablo J (2015). Molybdenum and tungsten enzymes: from biology to chemistry and back. Journal of Biological Inorganic Chemistry, 20 (2), 181-182. doi: 10.1007/s00775-015-1243-9

Electrocatalytic hydrocarbon hydroxylation by ethylbenzene dehydrogenase from Aromatoleum aromaticum

Kalimuthu, Palraj, Heider, Johann, Knack, Daniel and Bernhardt, Paul V (2015). Electrocatalytic hydrocarbon hydroxylation by ethylbenzene dehydrogenase from Aromatoleum aromaticum. Journal of Physical Chemistry B, 119 (8), 3456-3463. doi: 10.1021/jp512562k

The interaction between remote chiral centres: a pseudoracemic example

Bernhardt, Paul V., Carman, Raymond M. and Le, Tri T. (2015). The interaction between remote chiral centres: a pseudoracemic example. Australian Journal of Chemistry, 68 (4), 648-651. doi: 10.1071/CH14597

Electrochemically mediated enantioselective reduction of chiral sulfoxides

Chen, Kuan I., Challinor, Victoria L., Kielmann, Linda, Sharpe, Philip C., De Voss, James J., Kappler, Ulrike, McEwan, Alastair G. and Bernhardt, Paul V. (2014). Electrochemically mediated enantioselective reduction of chiral sulfoxides. Journal of Biological Inorganic Chemistry, 20 (2), 395-402. doi: 10.1007/s00775-014-1215-5

2-Pyridyl thiazoles as novel anti-Trypanosoma cruzi agents: structural design, synthesis and pharmacological evaluation

Veríssimo de Oliveira Cardoso, Marcos, Pessoa de Siqueira, Lucianna Rabelo, Barbosa da Silva, Elany, Bandeira Costa, Lívia, Zaldini Hernandes, Marcelo, Montenegro Rabello, Marcelo, Salgado Ferreira, Rafaela, Faria da Cruz, Luana, Rodrigo Magalhaes Moreira, Diogo, Rego Alves Pereira, Valeria, Accioly Brelaz de Castro, Maria Carolina, Bernhardt, Paul V. and Lima Leite, Ana Cristina (2014). 2-Pyridyl thiazoles as novel anti-Trypanosoma cruzi agents: structural design, synthesis and pharmacological evaluation. European Journal of Medicinal Chemistry, 86, 48-59. doi: 10.1016/j.ejmech.2014.08.012

Dimeric nickel(II) and copper(II) complexes of the pentadentate N3S2 chelating agents derived from S-alkyl/aryl esters of dithiocarbazic acid

Mirza, Aminul H., Akbar Ali, Mohammad, Bernhardt, Paul V. and Asri, Izuddin (2014). Dimeric nickel(II) and copper(II) complexes of the pentadentate N3S2 chelating agents derived from S-alkyl/aryl esters of dithiocarbazic acid. Polyhedron, 81, 723-727. doi: 10.1016/j.poly.2014.07.033

New method for exploring deactivation kinetics in copper-catalyzed atom-transfer-radical reactions

Zerk, Timothy J. and Bernhardt, Paul V. (2014). New method for exploring deactivation kinetics in copper-catalyzed atom-transfer-radical reactions. Inorganic Chemistry, 53 (21), 11351-11353. doi: 10.1021/ic5022005

Cyclic penta- and hexaleucine peptides without N-methylation are orally absorbed

Hill, Timothy A., Lohman, Rink-Jan, Hoang, Huy N., Nielsen, Daniel S., Scully, Conor C. G., Kok, W. Mei, Liu, Ligong, Lucke, Andrew J., Stoermer, Martin J., Schroeder, Christina I., Chaousis, Stephanie, Colless, Barbara, Bernhardt, Paul V., Edmonds, David J., Griffith, David A., Rotter, Charles J., Ruggeri, Roger B., Price, David A., Liras, Spiros, Craik, David J. and Fairlie, David P. (2014). Cyclic penta- and hexaleucine peptides without N-methylation are orally absorbed. ACS Medicinal Chemistry Letters, 5 (10), 1148-1151. doi: 10.1021/ml5002823

A sensitive and stable amperometric nitrate biosensor employing Arabidopsis thaliana nitrate reductase

Kalimuthu, Palraj, Fischer-Schrader, Katrin, Schwarz, Gunter and Bernhardt, Paul V. (2014). A sensitive and stable amperometric nitrate biosensor employing Arabidopsis thaliana nitrate reductase. Journal of Biological Inorganic Chemistry, 20 (2), 385-393. doi: 10.1007/s00775-014-1171-0

Catalytic voltammetry of the molybdoenzyme sulfite dehydrogenase from sinorhizobium meliloti

Kalimuthu, Palraj, Kappler, Ulrike and Bernhardt, Paul V. (2014). Catalytic voltammetry of the molybdoenzyme sulfite dehydrogenase from sinorhizobium meliloti. Journal of Physical Chemistry B, 118 (25), 7091-7099. doi: 10.1021/jp503963z

Synthesis, spectroscopy and X-ray crystal structures of some zinc(II) and cadmium(II) complexes of the 2-pyridinecarboxaldehyde Schiff bases of S-methyl- and S-benzyldithiocarbazates

Mirza, Aminul Huq, Hamid, Malai Haniti S. A., Aripin, Sazwani, Karim, Mohammad Rezaul, Arifuzzaman, Md., Ali, Mohammad Akbar and Bernhardt, Paul V. (2014). Synthesis, spectroscopy and X-ray crystal structures of some zinc(II) and cadmium(II) complexes of the 2-pyridinecarboxaldehyde Schiff bases of S-methyl- and S-benzyldithiocarbazates. Polyhedron, 74, 16-23. doi: 10.1016/j.poly.2014.02.016

Attempted synthesis of the imidazylate of an α-hydroxylactone results in unexpected chlorination: Synthesis and X-ray crystal structure of 5-Chloro-5-deoxy-1,2- O -isopropylidene-β- l -idurono-6,3-lactone

Mohamed, Shifaza, Bernhardt, Paul V. and Ferro, Vito (2014). Attempted synthesis of the imidazylate of an α-hydroxylactone results in unexpected chlorination: Synthesis and X-ray crystal structure of 5-Chloro-5-deoxy-1,2- O -isopropylidene-β- l -idurono-6,3-lactone. Journal of Carbohydrate Chemistry, 33 (4), 197-205. doi: 10.1080/07328303.2014.907908

The tachykinin peptide neurokinin B binds copper(I) and silver(I) and undergoes quasi-reversible electrochemistry: towards a new function for the peptide in the brain.

Grosas, Aidan B., Kalimuthu, Palraj, Smith, Alison C., Williams, Peter A., Millar, Thomas J., Bernhardt, Paul V. and Jones, Christopher E. (2014). The tachykinin peptide neurokinin B binds copper(I) and silver(I) and undergoes quasi-reversible electrochemistry: towards a new function for the peptide in the brain.. Neurochemistry International, 70 (1), 1-9. doi: 10.1016/j.neuint.2014.03.002

Computational insights on the geometrical arrangements of Cu(II) with a mixed-donor N3S3 macrobicyclic ligand

Algarra, Andres G., Aullon, Gabriel, Bernhardt, Paul V. and Martinez, Manuel (2014). Computational insights on the geometrical arrangements of Cu(II) with a mixed-donor N3S3 macrobicyclic ligand. Inorganic Chemistry, 53 (1), 512-521. doi: 10.1021/ic402533j

Acanthocyclamine A from the Indonesian marine sponge Acanthostrongylophora ingens

Dewi, Ariyanti S., Hadi, Tri A., Fajarningsih, Nurrahmi D., Blanchfield, Joanne T., Bernhardt, Paul V. and Garson, Mary J. (2014). Acanthocyclamine A from the Indonesian marine sponge Acanthostrongylophora ingens. Australian Journal of Chemistry, 67 (8-9), 1205-1210. doi: 10.1071/CH14107

Electrochemically driven catalysis of Rhizobium sp. NT-26 arsenite oxidase with its native electron acceptor cytochrome C552

Kalimuthu, Palraj, Heath, Matthew D., Santini, Joanne M., Kappler, Ulrike and Bernhardt, Paul V. (2014). Electrochemically driven catalysis of Rhizobium sp. NT-26 arsenite oxidase with its native electron acceptor cytochrome C552. Biochimica et Biophysica Acta, 1837 (1), 112-120. doi: 10.1016/j.bbabio.2013.07.010

Kinetic studies on the oxidation of oxyhemoglobin by biologically active iron thiosemicarbazone complexes: relevance to iron-chelator-induced methemoglobinemia

Basha, Maram T., Rodríguez, Carlos, Richardson, Des R., Martínez, Manuel and Bernhardt, Paul V. (2013). Kinetic studies on the oxidation of oxyhemoglobin by biologically active iron thiosemicarbazone complexes: relevance to iron-chelator-induced methemoglobinemia. Journal of Biological Inorganic Chemistry, 19 (3), 349-357. doi: 10.1007/s00775-013-1070-9

Solvent dependent anion dissociation limits copper(i) catalysed atom transfer reactions.

Zerk, Timothy J. and Bernhardt, Paul V. (2013). Solvent dependent anion dissociation limits copper(i) catalysed atom transfer reactions.. Dalton Transactions, 42 (32), 11683-11694. doi: 10.1039/c3dt51100f

Secondary metabolites of the sponge-derived fungus Acremonium persicinum

Suciati, Fraser, James A., Lambert, Lynette K., Pierens, Gregory K., Bernhardt, Paul V. and Garson, Mary J. (2013). Secondary metabolites of the sponge-derived fungus Acremonium persicinum. Journal of Natural Products, 76 (8), 1432-1440. doi: 10.1021/np4002114

Electrochemistry, surface plasmon resonance, and quartz crystal microbalance: an associative study on cytochrome c adsorption on pyridine tail-group monolayers on gold

Paulo, Tércio de F., de Sousa, Ticyano P., de Abreu, Dieric S., Felício, Nathalie H., Bernhardt, Paul V., Lopes, Luiz G. de F., Sousa, Eduardo H. S. and Diógenes, Izaura C. N. (2013). Electrochemistry, surface plasmon resonance, and quartz crystal microbalance: an associative study on cytochrome c adsorption on pyridine tail-group monolayers on gold. Journal of Physical Chemistry B: Condensed Matter, Materials, Surfaces, Interfaces & Biophysical, 117 (29), 8673-8680. doi: 10.1021/jp400694k

Mediated electrochemistry of nitrate reductase from Arabidopsis thaliana

Kalimuthu, Palraj, Fischer-Schrader, Katrin, Schwarz, Guenter and Bernhardt, Paul V. (2013). Mediated electrochemistry of nitrate reductase from Arabidopsis thaliana. Journal of Physical Chemistry B, 117 (25), 7569-7577. doi: 10.1021/jp404076w

Structure and absolute configuration of methyl (3R)-malonyl-(13S)-hydroxycheilanth-17-en-19-oate, a sesterterpene derivative from the roots of Aletris farinosa

Challinor, Victoria L., Chap, Sonet, Lehmann, Reginald P., Bernhardt, Paul V. and De Voss, James J. (2013). Structure and absolute configuration of methyl (3R)-malonyl-(13S)-hydroxycheilanth-17-en-19-oate, a sesterterpene derivative from the roots of Aletris farinosa. Journal of Natural Products, 76 (4), 485-488. doi: 10.1021/np400035n

Synthesis of oxygenated cineole derivatives from cineole: utility of cytochrome P450(cin) as an enantioselective catalyst

Farlow, Anthony J., Bernhardt, Paul V. and De Voss, James J. (2013). Synthesis of oxygenated cineole derivatives from cineole: utility of cytochrome P450(cin) as an enantioselective catalyst. Tetrahedron: Asymmetry, 24 (5-6), 324-333. doi: 10.1016/j.tetasy.2013.02.004

The trivalent copper complex of a conjugated bis-dithiocarbazate schiff base: stabilization of Cu in three different oxidation states

Ali, Mohammad Akbar, Bernhardt, Paul V., Brax, Mathilde A. H., England, Jason, Farlow, Anthony J., Hanson, Graeme R., Yeng, Lee Len, Mirza, Aminul Huq and Wieghardt, Karl (2013). The trivalent copper complex of a conjugated bis-dithiocarbazate schiff base: stabilization of Cu in three different oxidation states. Inorganic Chemistry, 52 (3), 1650-1657. doi: 10.1021/ic302596h

New insights in the formation of five- versus seven-membered platinacycles: a kinetico-mechanistic study

Bernhardt, Paul V., Calvet, Teresa, Crespo, Margarita, Font-Bardía, Mercè, Jansat, Susanna and Martínez, Manuel (2013). New insights in the formation of five- versus seven-membered platinacycles: a kinetico-mechanistic study. Inorganic Chemistry, 52 (1), 474-484. doi: 10.1021/ic3023584

Alkyl substituted 2′-benzoylpyridine thiosemicarbazone chelators with potent and selective anti-neoplastic activity: novel ligands that limit methemoglobin formation

Stefani, Christian, Jansson, Patric J., Gutierrez, Elaine, Bernhardt, Paul V., Richardson, Des R. and Kalinowski, Danuta S. (2013). Alkyl substituted 2′-benzoylpyridine thiosemicarbazone chelators with potent and selective anti-neoplastic activity: novel ligands that limit methemoglobin formation. Journal of Medicinal Chemistry, 56 (1), 357-370. doi: 10.1021/jm301691s

Template synthesis and X-ray structural characterization of nickel(II) and zinc(II) complexes of tetradentate SNNS ligands formed by condensation of phthalaldehyde with S-methyldithiocarbazate and N-4-methyl-3-thiosemicarbazide

Ali, Mohammad Akbar, Mirza, Aminul Huq, Mei, Chan Chin, Bernhardt, Paul V. and Karim, Mohammad Rezaul (2013). Template synthesis and X-ray structural characterization of nickel(II) and zinc(II) complexes of tetradentate SNNS ligands formed by condensation of phthalaldehyde with S-methyldithiocarbazate and N-4-methyl-3-thiosemicarbazide. Polyhedron, 49 (1), 277-283. doi: 10.1016/j.poly.2012.10.008

Low-potential amperometric enzyme biosensor for xanthine and hypoxanthine

Kalimuthu, Palraj, Leimkuhler, Silke and Bernhardt, Paul V. (2012). Low-potential amperometric enzyme biosensor for xanthine and hypoxanthine. Analytical Chemistry, 84 (23), 10359-10365. doi: 10.1021/ac3025027

Mixed-ligand nickel(II) and copper(II) complexes of tridentate ONS and NNS ligands derived from S-alkyldithiocarbazates with the saccharinate ion as a co-ligand

Ali, Mohammad Akbar, Mirza, Aminul Huq, Ting, Wong Yok, Hamid, Malai Haniti S. A., Bernhardt, Paul V. and Butcher, Ray J. (2012). Mixed-ligand nickel(II) and copper(II) complexes of tridentate ONS and NNS ligands derived from S-alkyldithiocarbazates with the saccharinate ion as a co-ligand. Polyhedron, 48 (1), 167-173. doi: 10.1016/j.poly.2012.08.069

Reversible rearrangements of Cu(II) cage complexes: solvent and anion influences

Bernhardt, Paul V., Font, Helena, Gallego, Carlos, Martinez, Manuel and Rodriguez, Carlos (2012). Reversible rearrangements of Cu(II) cage complexes: solvent and anion influences. Inorganic Chemistry, 51 (22), 12372-12379. doi: 10.1021/ic301696v

Synthesis, characterization and X-ray crystal structures of thiolate sulfur-bridged dimeric copper(II) complexes of the 2-aminoacetophenone Schiff base of S-methyldithiocarbazate

Akbar Ali, Mohammad, Mirza, Aminul Huq, Hamid, Malai Haniti S. A., Aminath, Nuzuhath and Bernhardt, Paul V. (2012). Synthesis, characterization and X-ray crystal structures of thiolate sulfur-bridged dimeric copper(II) complexes of the 2-aminoacetophenone Schiff base of S-methyldithiocarbazate. Polyhedron, 47 (1), 79-86. doi: 10.1016/j.poly.2012.08.024

Catalytic electrochemistry of xanthine dehydrogenase

Kalimuthu, Palraj, Leimkuehler, Silke and Bernhardt, Paul V. (2012). Catalytic electrochemistry of xanthine dehydrogenase. Journal of Physical Chemistry B, 116 (38), 11600-11607. doi: 10.1021/jp307374z

Novel second-generation Di-2-Pyridylketone Thiosemicarbazones show synergism with standard chemotherapeutics and demonstrate potent activity against lung cancer xenografts after oral and intravenous administration in vivo

Lovejoy, David B., Sharp, Danae M., Seebacher, Nicole, Obeidy, Peyman, Prichard, Thomas, Stefani, Christian, Basha, Maram T., Sharpe, Philip C., Jansson, Patric J., Kalinowski, Danuta S., Bernhardt, Paul V. and Richardson, Des R. (2012). Novel second-generation Di-2-Pyridylketone Thiosemicarbazones show synergism with standard chemotherapeutics and demonstrate potent activity against lung cancer xenografts after oral and intravenous administration in vivo. Journal of Medicinal Chemistry, 55 (16), 7230-7244. doi: 10.1021/jm300768u

Methemoglobin formation by triapine, di-2-pyridylketone-4,4-dimethyl-3- thiosemicarbazone (Dp44mT), and other anticancer thiosemicarbazones: identification of novel thiosemicarbazones and therapeutics that prevent this effect

Quach, Patricia, Gutierrez, Elaine, Basha, Maram Talal, Kalinowski, Danuta S., Sharpe, Philip C., Lovejoy, David B., Bernhardt, Paul V., Jansson, Patric J. and Richardson, Des R. (2012). Methemoglobin formation by triapine, di-2-pyridylketone-4,4-dimethyl-3- thiosemicarbazone (Dp44mT), and other anticancer thiosemicarbazones: identification of novel thiosemicarbazones and therapeutics that prevent this effect. Molecular Pharmacology, 82 (1), 105-114. doi: 10.1124/mol.112.078964

Heterocyclic dithiocarbazate iron chelators: Fe coordination chemistry and biological activity

Basha, Maram T., Chartres, Jy D., Pantarat, Namfon, Ali, Mohammad Akbar, Mirza, Aminul Huq, Kalinowski, Danuta S., Richardson, Des R. and Bernhardt, Paul V. (2012). Heterocyclic dithiocarbazate iron chelators: Fe coordination chemistry and biological activity. Dalton Transactions, 41 (21), 6536-6548. doi: 10.1039/c2dt12387h

Copper redistribution in murine macrophages in response to Salmonella infection

Achard, Maud E. S., Stafford, Sian L., Bokil, Nilesh J., Chartres, Jy, Bernhardt, Paul V., Schembri, Mark A., Sweet, Matthew J. and McEwan, Alastair G. (2012). Copper redistribution in murine macrophages in response to Salmonella infection. Biochemical Journal, 444 (1), 51-57. doi: 10.1042/BJ20112180

Stereocontrolled Synthesis of the cis-Hydroxydecalin System: Towards Biologically Active 19-nor-Clerodanes

Mirzayans, Paul Malek, Pouwer, Rebecca H., Williams, Craig M. and Bernhardt, Paul V. (2012). Stereocontrolled Synthesis of the cis-Hydroxydecalin System: Towards Biologically Active 19-nor-Clerodanes. European Journal of Organic Chemistry, 8 (8), 1633-1638. doi: 10.1002/ejoc.201101807

Heronamycin A: A new benzothiazine ansamycin from an Australian marine-derived Streptomyces sp.

Raju, Ritesh, Piggott, Andrew M., Khalil, Zeinab, Bernhardt, Paul V. and Capon, Robert J. (2012). Heronamycin A: A new benzothiazine ansamycin from an Australian marine-derived Streptomyces sp.. Tetrahedron Letters, 53 (9), 1063-1065. doi: 10.1016/j.tetlet.2011.12.064

Crystal Structures of (3R,3aR,4S,7R,7aS)-3-(Allyloxy)hexahydro-4,7-epoxyisobenzofuran-1(3H)-one and (3S,3aR,4S,7R,7aS)-3-((E)-But-2-en-1-yloxy)hexahydro-4,7-epoxyisobenzofuran-1(3H)-one: Confirmation of NMR Predicted Stereocentre Geometry

Tarleton, Mark, Bernhardt, Paul V. and McCluskey, Adam (2012). Crystal Structures of (3R,3aR,4S,7R,7aS)-3-(Allyloxy)hexahydro-4,7-epoxyisobenzofuran-1(3H)-one and (3S,3aR,4S,7R,7aS)-3-((E)-But-2-en-1-yloxy)hexahydro-4,7-epoxyisobenzofuran-1(3H)-one: Confirmation of NMR Predicted Stereocentre Geometry. Journal of Chemical Crystallography, 42 (6), 639-644. doi: 10.1007/s10870-012-0275-z

A solid state study of keto-enol tautomerismin in three naphthaledene Schiff bases

Pierens, Gregory K., Venkatachalam, T. K., Bernhardt, Paul V., Riley, Mark J. and Reutens, David C. (2012). A solid state study of keto-enol tautomerismin in three naphthaledene Schiff bases. Australian Journal of Chemistry, 65 (5), 552-556. doi: 10.1071/CH12122

Biologically active thiosemicarbazone Fe chelators and their reactions with ferrioxamine B and ferric EDTA; a kinetic study

Bernhardt, Paul V., Martínez, Manuel, Rodríguez, Carlos and Vazquez, Marta (2012). Biologically active thiosemicarbazone Fe chelators and their reactions with ferrioxamine B and ferric EDTA; a kinetic study. Dalton Transactions, 41 (7), 2122-2130. doi: 10.1039/C1DT11685A

Polymorphism in 3-Pyridylsydnone: Preparative and Structural Aspects

Bernhardt, Paul V., Kvaskoff, David, Veedu, Rakesh Naduvile and Wentrup, Curt (2012). Polymorphism in 3-Pyridylsydnone: Preparative and Structural Aspects. Australian Journal of Chemistry, 65 (4), 376-380. doi: 10.1071/CH12041

Reactivity of di-iodine toward thiol: Desulfuration reaction of 5-nitro-2-mercapto-benzimidazole upon reaction with di-iodine

Corban, G. J., Antoniadis, C. D., Hadjikakou, S. K., Kourkoumelis, N., Tyurin, V. Yu., Dolgano, A., Milaeva, E. R., Kubicki, M., Bernhardt, P. V., Tiekink, E. R. T., Skoulika, S. and Hadjiliadis, N. (2012). Reactivity of di-iodine toward thiol: Desulfuration reaction of 5-nitro-2-mercapto-benzimidazole upon reaction with di-iodine. Heteroatom Chemistry, 23 (5), 498-511. doi: 10.1002/hc.21042

Structures of 4-iminopyrido[1,2-a]pyrimidines, pyrido[1,2-a]pyrimidin-4-ones, pyridopyrimidinium olates, and thiazolo[3,2-a]pyrimidine analogues

Bernhardt, Paul V. and Wentrup, Curt (2012). Structures of 4-iminopyrido[1,2-a]pyrimidines, pyrido[1,2-a]pyrimidin-4-ones, pyridopyrimidinium olates, and thiazolo[3,2-a]pyrimidine analogues. Australian Journal of Chemistry, 65 (4), 371-375. doi: 10.1071/CH12040

The role of Zn-OR and Zn-OH nucleophiles and the influence of para-substituents in the reactions of binuclear phosphatase mimetics

Daumann, Lena J., Dalle, Kristian E., Schenk, Gerhard, McGeary, Ross P., Bernhardt, Paul V., Ollis, David L. and Gahan, Lawrence R. (2012). The role of Zn-OR and Zn-OH nucleophiles and the influence of para-substituents in the reactions of binuclear phosphatase mimetics. Dalton Transactions, 41 (6), 1695-1708. doi: 10.1039/c1dt11187f

Halogenated 2′-benzoylpyridine thiosemicarbazone (XBpT) chelators with potent and selective anti-neoplastic activity: Relationship to intracellular redox activity

Stefani, Christian, Punnia-Moorthy, Gaya, Lovejoy, David B., Jansson, Patric J., Kalinowski, Danuta S., Sharpe, Philip C., Bernhardt, Paul V. and Richardson, Des R. (2011). Halogenated 2′-benzoylpyridine thiosemicarbazone (XBpT) chelators with potent and selective anti-neoplastic activity: Relationship to intracellular redox activity. Journal of Medicinal Chemistry, 54 (19), 6936-6948. doi: 10.1021/jm200924c

A turn-on fluorescent iron complex and its cellular uptake

Chartres, Jy D., Busby, Michael, Riley, Mark J., Davis, Jason J. and Bernhardt, Paul V. (2011). A turn-on fluorescent iron complex and its cellular uptake. Inorganic Chemistry, 50 (18), 9178-9183. doi: 10.1021/ic201495r

An unusually flexible expanded hexaamine cage and its Cu(II) complexes: Variable coordination modes and incomplete encapsulation

Qin, Chang-Jin, James, Lloyd, Chartres, Jy D., Alcock, Leighton J., Davis, Kimberley J., Willis, Anthony C., Sargeson, Alan M., Bernhardt, Paul V. and Ralph, Stephen F. (2011). An unusually flexible expanded hexaamine cage and its Cu(II) complexes: Variable coordination modes and incomplete encapsulation. Inorganic Chemistry, 50 (18), 9131-9140. doi: 10.1021/ic201326d

Revision of the absolute configurations of bethosides B and C and their aglycone

Challinor, Victoria L., Hayes, Patricia Y., Bernhardt, Paul V., Kitching, William, Lehmann, Reginald P. and De Voss, James J. (2011). Revision of the absolute configurations of bethosides B and C and their aglycone. Journal of Organic Chemistry, 76 (17), 7275-7280. doi: 10.1021/jo2012797

A rapid electrochemical method for determining rate coefficients for copper-catalyzed polymerizations

Bell, Craig A., Bernhardt, Paul V. and Monteiro, Michael J. (2011). A rapid electrochemical method for determining rate coefficients for copper-catalyzed polymerizations. Journal of the American Chemical Society, 133 (31), 11944-11947. doi: 10.1021/ja205193f

Vapour phase assembly of a halogen bonded complex of an isoindoline nitroxide and 1,2-diiodotetrafluorobenzene

Davy, Karl J. P., McMurtrie, John, Rintoul, Llew, Bernhardt, Paul V. and Micallef, Aaron S. (2011). Vapour phase assembly of a halogen bonded complex of an isoindoline nitroxide and 1,2-diiodotetrafluorobenzene. CrystEngComm, 13 (16), 5062-5070. doi: 10.1039/c1ce05344b

Structure and absolute configuration of helosides A and B, new saponins from Chamaelirium luteum

Challinor, Victoria L., Stuthe, Julia M. U., Bernhardt, Paul V., Lehmann, Reginald P., Kitching, William and De Voss, James J. (2011). Structure and absolute configuration of helosides A and B, new saponins from Chamaelirium luteum. Journal of Natural Products, 74 (7), 1557-1560. doi: 10.1021/np200100a

Insights into structure and function of the active site of SoxAX cytochromes

Kilmartin, James R., Maher, Megan J., Krusong, Kuakarun, Noble, Christopher J., Hanson, Graeme R., Bernhardt, Paul V., Riley, Mark J. and Kappler, Ulrike (2011). Insights into structure and function of the active site of SoxAX cytochromes. Journal of Biological Chemistry, 286 (28), 24872-24881. doi: 10.1074/jbc.M110.212183

Synthesis and structural characterization of (Z)-3-[(4-chlorophenylamino) methylene] naphthalene-2(3H)-one: An enol, keto or zwitterionic tautomer?

Venkatachalam, T. K., Pierens, Gregory K., Bernhardt, Paul V., Hammond, Luke and Reutens, David C. (2011). Synthesis and structural characterization of (Z)-3-[(4-chlorophenylamino) methylene] naphthalene-2(3H)-one: An enol, keto or zwitterionic tautomer?. Journal of Chemical Crystallography, 41 (7), 944-951. doi: 10.1007/s10870-011-0022-x

The truth about false unicorn (Chamaelirium luteum): Total synthesis of 23R,24S-Chiograsterol B defines the structure and stereochemistry of the major saponins from this medicinal herb

Matovic, Nicholas J., Stuthe, Julia M. U., Challinor, Victoria L., Bernhardt, Paul V., Lehmann, Reginald P., Kitching, William and De Voss, James J. (2011). The truth about false unicorn (Chamaelirium luteum): Total synthesis of 23R,24S-Chiograsterol B defines the structure and stereochemistry of the major saponins from this medicinal herb. Chemistry-A European Journal, 17 (27), 7578-7591. doi: 10.1002/chem.201100503

A new N,N-dimethyl purine from an Australian dictyoceratid sponge

Suciati, Garson, Mary J., Bernhardt, Paul V. and Pierens, Gregory K. (2011). A new N,N-dimethyl purine from an Australian dictyoceratid sponge. Journal of Chemical Crystallography, 41 (11), 1669-1672. doi: 10.1007/s10870-011-0155-y

Self-assembling dicopper(II) complexes of di-2-pyridyl ketone Schiff base ligands derived from S-alkyldithiocarbazates

Ali, Mohammad Akbar, Mirza, Aminul H., Butcher, Ray J., Bernhardt, Paul V. and Karim, Mohammad Rezaul (2011). Self-assembling dicopper(II) complexes of di-2-pyridyl ketone Schiff base ligands derived from S-alkyldithiocarbazates. Polyhedron, 30 (9), 1478-1486. doi: 10.1016/j.poly.2011.02.048

Synthesis and x-ray crystal structure of 1- and 2-cinnamoyaloxy acetonaphthones

Venkatachalam, T. K., Pierens, G. K., Bernhardt, P. V. and Reutens, D. C. (2011). Synthesis and x-ray crystal structure of 1- and 2-cinnamoyaloxy acetonaphthones. Journal of Chemical Crystallography, 41 (4), 563-569. doi: 10.1007/s10870-010-9923-3

How are "atypical" sulfite deydrogenases linked to cell metabolism? Interactions between the SorT sulfite dehydrogenase and small redox proteins

Low, Louie, Kilmartin, James Ryan, Bernhardt, Paul V. and Kappler, Ulrike (2011). How are "atypical" sulfite deydrogenases linked to cell metabolism? Interactions between the SorT sulfite dehydrogenase and small redox proteins. Frontiers in Microbiology, 2 (MAR), 58-1-58-10. doi: 10.3389/fmicb.2011.00058

Xanthine dehydrogenase electrocatalysis : Autocatalysis and novel activity

Kalimuthu, Palraj, Leimkuhler, Silke and Bernhardt, Paul V. (2011). Xanthine dehydrogenase electrocatalysis : Autocatalysis and novel activity. Journal of Physical Chemistry B, 115 (11), 2655-2662. doi: 10.1021/jp111809f

Foreword to the 39th international conference on coordination chemistry bioinorganic research front

Bernhardt, Paul V. (2011). Foreword to the 39th international conference on coordination chemistry bioinorganic research front. Australian Journal of Chemistry, 64 (3), 229-230. doi: 10.1071/CH11076

Preparation and structural characterization of nickel(II), cobalt(II), zinc(II) and tin(IV) complexes of the isatin Schiff bases of S-methyl and S-benzyldithiocarbazates

Ali, M. Akbar, Mirza, A. H., Abu Bakar, Hjh Junaidah Hj and Bernhardt, Paul V. (2011). Preparation and structural characterization of nickel(II), cobalt(II), zinc(II) and tin(IV) complexes of the isatin Schiff bases of S-methyl and S-benzyldithiocarbazates. Polyhedron, 30 (4), 556-564. doi: 10.1016/j.poly.2010.11.016

Metal Chelation

Bernhardt, Paul V. and Richardson, Des R. (2011). Metal Chelation. Current Topics in Medicinal Chemistry, 11 (5), 482-482. doi: 10.2174/156802611794785235

Synthetic and natural products as iron chelators

Sharpe, Philip C., Richardson, Des R., Kalinowski, Danuta S. and Bernhardt, Paul V. (2011). Synthetic and natural products as iron chelators. Current Topics in Medicinal Chemistry, 11 (5), 591-607. doi: 10.2174/156802611794785163

The medicinal chemistry of novel iron chelators for the treatment of cancer

Kovacevic, Zaklina, Kalinowski, Danuta S., Lovejoy, David B., Yu, Yu, Rahmanto, Yohan Suryo, Sharpe, Phillip C., Bernhardt, Paul V. and Richardson, Des R. (2011). The medicinal chemistry of novel iron chelators for the treatment of cancer. Current Topics in Medicinal Chemistry, 11 (5), 483-499. doi: 10.2174/156802611794785190

Cobalt hexaamine mediated electrocatalytic voltammetry of dimethyl sulfoxide reductase: Driving force effects on catalysis

Chen, Kuan-I., McEwan, Alastair G. and Bernhardt, Paul V. (2011). Cobalt hexaamine mediated electrocatalytic voltammetry of dimethyl sulfoxide reductase: Driving force effects on catalysis. Journal of Biological Inorganic Chemistry, 16 (2), 227-234. doi: 10.1007/s00775-010-0719-x

Discrete Rh-III/Fe-II and Rh-III/Fe-II/Co-III cyanide-bridged mixed valence compounds

Bernhardt, Paul V., Martinez, Manuel, Rodriguez, Carlos and Vazquez, Marta (2011). Discrete Rh-III/Fe-II and Rh-III/Fe-II/Co-III cyanide-bridged mixed valence compounds. Inorganic Chemistry, 50 (4), 1429-1440. doi: 10.1021/ic102061s

Mixed-ligand ternary complexes of potentially pentadentate but functionally tridentate Schiff base chelates

Ali, Mohammed Akbar, Mirza, Aminul Huq, Yee, Chiam Yin, Rahgeni, Hayatti and Bernhardt, Paul V. (2011). Mixed-ligand ternary complexes of potentially pentadentate but functionally tridentate Schiff base chelates. Polyhedron, 30 (3), 542-548. doi: 10.1016/j.poly.2010.11.019

Synthesis, characterization and X-ray crystal structures of seven-coordinate pentagonal-bipyramidal zinc(II), cadmium(II) and tin(IV) complexes of a pentadentate N3S2 thiosemicarbazone

Ali, Mohammad A., Mirza, Aminul H., Chartres, Jy D. and Bernhardt, Paul V. (2011). Synthesis, characterization and X-ray crystal structures of seven-coordinate pentagonal-bipyramidal zinc(II), cadmium(II) and tin(IV) complexes of a pentadentate N3S2 thiosemicarbazone. Polyhedron, 30 (2), 299-306. doi: 10.1016/j.poly.2010.10.027

Exploiting the versatility and selectivity of Mo enzymes with electrochemistry

Bernhardt, Paul V. (2011). Exploiting the versatility and selectivity of Mo enzymes with electrochemistry. Chemical Communications, 47 (6), 1663-1673. doi: 10.1039/c0cc03681a

Short circuiting a sulfite oxidising enzyme with direct electrochemistry: Active site substitutions and their effect on catalysis and electron transfer

Rapson, TD, Kappler, U, Hanson, GR and Bernhardt, PV (2011). Short circuiting a sulfite oxidising enzyme with direct electrochemistry: Active site substitutions and their effect on catalysis and electron transfer. Biochimica Et Biophysica Acta-bioenergetics, 1807 (1), 108-118. doi: 10.1016/j.bbabio.2010.09.005

Mediated electrochemistry of dimethyl sulfoxide reductase promoted by carbon nanotubes

Geng, W. C., Zhang, L. and Bernhardt, P. V. (2010). Mediated electrochemistry of dimethyl sulfoxide reductase promoted by carbon nanotubes. Science China Chemistry, 53 (12), 2560-2563. doi: 10.1007/s11426-010-4162-1

Synthesis of the sponge-derived plakortone series of bioactive compounds

Hayes, PY, Chow, S, Rahm, F, Bernhardt, PV, De Voss, JJ and Kitching, W (2010). Synthesis of the sponge-derived plakortone series of bioactive compounds. Journal of Organic Chemistry, 75 (19), 6489-6501. doi: 10.1021/jo101224w

A phosphorescent poly(dendrimer) containing iridium(III) complexes: Synthesis and light-emitting properties

Lai, Wen-Yong, Levell, Jack W., Jackson, Andrew C., Lo, Shih-Chun, Bernhardt, Paul V., Samuel, Ifor D. W. and Burn, Paul L. (2010). A phosphorescent poly(dendrimer) containing iridium(III) complexes: Synthesis and light-emitting properties. Macromolecules, 43 (17), 6986-6994. doi: 10.1021/ma101363h

Highly Sensitive and Stable Electrochemical Sulfite Biosensor Incorporating a Bacterial Sulfite Dehydrogenase

Kalimuthu, Palraj, Tkac, Jan, Kappler, Ulrike, Davis, Jason J. and Bernhardt, Paul V, (2010). Highly Sensitive and Stable Electrochemical Sulfite Biosensor Incorporating a Bacterial Sulfite Dehydrogenase. Analytical Chemistry, 82 (17), 7374-7379. doi: 10.1021/ac101493y

Novel thiosemicarbazones of the ApT and DpT Series and their copper complexes: Identification of pronounced redox activity and characterization of their antitumor activity

Jansson, Patric J., Sharpe, Philip C., Bernhardt, Paul V. and Richardson, Des R. (2010). Novel thiosemicarbazones of the ApT and DpT Series and their copper complexes: Identification of pronounced redox activity and characterization of their antitumor activity. Journal of Medicinal Chemistry, 53 (15), 5759-5769. doi: 10.1021/jm100561b

[4+2] Cycloaddition reactions between 1,8-disubstituted cyclooctatetraenes and diazo dienophiles: Stereoelectronic effects, anticancer properties and application to the synthesis of 7,8-substituted bicyclo [4.2.0] octa-2,4-dienes

Grange, RL, Gallen, MJ, Schill, H, Johns, JP, Dong, L, Parsons, PG, Reddell, PW, Gordon, VA, Bernhardt, PV and Williams, CM (2010). [4+2] Cycloaddition reactions between 1,8-disubstituted cyclooctatetraenes and diazo dienophiles: Stereoelectronic effects, anticancer properties and application to the synthesis of 7,8-substituted bicyclo [4.2.0] octa-2,4-dienes. Chemistry - A European Journal, 16 (29), 8894-8903. doi: 10.1002/chem.200903454

The Fe-catalyzed oxidation of aroyl hydrazones to aroyl hydrazines: mechanistic insight to a remarkable reaction

Bernhardt, Paul V. and Martinez, Manuel (2010). The Fe-catalyzed oxidation of aroyl hydrazones to aroyl hydrazines: mechanistic insight to a remarkable reaction. Journal of Coordination Chemistry, 63 (14-16), 2619-2628. doi: 10.1080/00958972.2010.491912

Cloning, expression and purification of cindoxin, an unusual FMN-containing cytochrome P450 redox partner

Hawkes, David B., Slessor, Kate E., Bernhardt, Paul V. and De Voss, James J. (2010). Cloning, expression and purification of cindoxin, an unusual FMN-containing cytochrome P450 redox partner. ChemBioChem, 11 (8), 1107-1114. doi: 10.1002/cbic.201000119

Pulsed EPR investigations of the Mo(V) centers of the R55Q and R55M variants of sulfite dehydrogenase from Starkeya novella

Rapson, Trevor D., Astashkin, Andrei V., Johnson-Winters, Kayunta, Bernhardt, Paul V., Kappler, Ulrike, Raitsimring, Arnold M. and Enemark, John H. (2010). Pulsed EPR investigations of the Mo(V) centers of the R55Q and R55M variants of sulfite dehydrogenase from Starkeya novella. Journal of Biological Inorganic Chemistry, 15 (4), 505-514. doi: 10.1007/s00775-009-0619-0

The absolute structure of (+)-aplysulfurin

Graham, SK, Garson, MJ and Bernhardt, PV (2010). The absolute structure of (+)-aplysulfurin. Journal of Chemical Crystallography, 40 (5), 468-471. doi: 10.1007/s10870-009-9679-9

The single-domain globin from the pathogenic bacterium Campylobacter jejuni: Novel D-helix conformation, proximal hydrogen bonding that influences ligand binding, and peroxidase-like redox properties

Shepherd, M, Barynin, V, Lu, CY, Bernhardt, PV, Wu, GH, Yeh, SR, Egawa, T, Sedelnikova, SE, Rice, DW, Wilson, JL and Poole, RK (2010). The single-domain globin from the pathogenic bacterium Campylobacter jejuni: Novel D-helix conformation, proximal hydrogen bonding that influences ligand binding, and peroxidase-like redox properties. Journal of Biological Chemistry, 285 (17), 12747-12754. doi: 10.1074/jbc.M109.084509

9-azidoacridine and 9-acridinylnitrene

Taherpour, Avat Arman, Kvaskoff, David, Bernhardt, Paul V. and Wentrup, Curt (2010). 9-azidoacridine and 9-acridinylnitrene. Journal of Physical Organic Chemistry, 23 (4), 382-389. doi: 10.1002/poc.1657

Methyl acrylate polymerizations in the presence of a copper/N3S3 macrobicyclic cage in DMSO at 25 °C

Bell, Craig A., Sun, Qiao, Zhang, Hong, Smith, Sean C., Bernhardt, Paul V. and Monteiro, Michael J. (2010). Methyl acrylate polymerizations in the presence of a copper/N3S3 macrobicyclic cage in DMSO at 25 °C. Polymer Chemistry, 1 (2), 207-212. doi: 10.1039/b9py00315k

Structure and absolute configuration of 3-alkylpiperidine alkaloids from an Indonesian sponge of the genus Halichondria

Mudianta, IW, Katavic, PL, Lambert, LK, Hayes, PY, Banwell, MG, Munro, MHG, Bernhardt, PV and Garson, MJ (2010). Structure and absolute configuration of 3-alkylpiperidine alkaloids from an Indonesian sponge of the genus Halichondria. Tetrahedron, 66 (14), 2752-2760. doi: 10.1016/j.tet.2010.01.068

Synthesis and characterization of pentagonal bipyramidal organotin(IV) complexes of 2,6-diacetylpyridine Schiff bases of S-alkyl- and aryldithiocarbazates

Ali, Mohammad Akbar, Mirza, Aminul Huq, Wei, Lim Kok, Bernhardt, Paul V., Atchade, Olaniran, Song, Xueqing, Eng, George and May, Leopold (2010). Synthesis and characterization of pentagonal bipyramidal organotin(IV) complexes of 2,6-diacetylpyridine Schiff bases of S-alkyl- and aryldithiocarbazates. Journal of Coordination Chemistry, 63 (7), 1194-1206. doi: 10.1080/00958971003739798

The 293 K structure of tetradehydrohaliclonacyclamine A

Mudianta, I. W., Garson, M. J. and Bernhardt, P. V. (2010). The 293 K structure of tetradehydrohaliclonacyclamine A. Acta Crystallographica Section C: Crystal Structure Communications, 66 (4), O176-O178. doi: 10.1107/S0108270110004634

Copper(II) complexes of a hexadentate mixed-donor N3S3 macrobicyclic cage: Facile rearrangements and interconversions

Bell, CA, Bernhardt, PV, Gahan, LR, Martinez, M, Monteiro, MJ, Rodriguez, C and Sharrad, CA (2010). Copper(II) complexes of a hexadentate mixed-donor N3S3 macrobicyclic cage: Facile rearrangements and interconversions. Chemistry: A European Journal, 16 (10), 3166-3175. doi: 10.1002/chem.200902611

On the solid-state isomerization of terpinolene tetrabromide

Bernhardt, Paul V., Carman, Raymond M. and Le, Tri T. (2010). On the solid-state isomerization of terpinolene tetrabromide. Australian Journal of Chemistry, 63 (3), 458-462. doi: 10.1071/CH09606

Outer-sphere redox reactions leading to the formation of discrete Co III/FeII pyrazine-bridged mixed-valence compounds

Bernhardt, Paul V., Martínez, Manuel and Rodríguez, Carlos (2010). Outer-sphere redox reactions leading to the formation of discrete Co III/FeII pyrazine-bridged mixed-valence compounds. European Journal of Inorganic Chemistry, 2010 (4), 562-569. doi: 10.1002/ejic.200900832

Helical metallomacrocyclic nickel(II) complexes of a tetradentate N 2S2 ligand derived from N-methyldithiocarbazic acid

Akbar Ali, Mohammad, Mirza, Aminul Huq, Hamid, Malai Haniti S. A., Siew, Ik Chin, Sia, Lo Pei and Bernhardt, Paul V. (2010). Helical metallomacrocyclic nickel(II) complexes of a tetradentate N 2S2 ligand derived from N-methyldithiocarbazic acid. Inorganic Chemistry Communications, 13 (12), 1445-1447. doi: 10.1016/j.inoche.2010.08.012

Microwave-induced molecular rearrangements. Flash thermolysis in the gas-phase and in solution: Synthesis of quinolones and naphthyridones

Lecoq, Delphine, Chalmers, Benjamin A., Veedu, Rakesh N., Kvaskoff, David, Bernhardt, Paul V. and Wentrup, Curt (2009). Microwave-induced molecular rearrangements. Flash thermolysis in the gas-phase and in solution: Synthesis of quinolones and naphthyridones. Australian Journal of Chemistry, 62 (12), 1631-1638. doi: 10.1071/CH09447

Foreword to Professor Alan M. Sargeson special issue

Bernhardt, Paul V. (2009). Foreword to Professor Alan M. Sargeson special issue. Australian Journal of Chemistry, 62 (10), 1195-1195. doi: 10.1071/CH09508

Macrocyclic thiophene-appended cyanido-bridged Co-III/Fe-II complexes: Precursors to mixed-valent poly-thiophene hybrid materials

Hasan. Sharizal, Kilah, Nathan L., Martinez, Manuel and Bernhardt, Paul V. (2009). Macrocyclic thiophene-appended cyanido-bridged Co-III/Fe-II complexes: Precursors to mixed-valent poly-thiophene hybrid materials. Australian Journal of Chemistry, 62 (10), 1214-1220. doi: 10.1071/CH09245

Mechanistic aspects of the chemistry of mononuclear Cr-III complexes with pendant-arm macrocyclic ligands and formation of discrete Cr-III/Fe-II and Cr-III/Fe-II/Co-III cyano-bridged mixed valence compounds

Basallote, Manuel G., Bernhardt, Paul V., Calvet, Teresa, Castillo, Carmen E., Font-Bardia, Merce, Martinez, Manuel and Rodriguez, Carlos (2009). Mechanistic aspects of the chemistry of mononuclear Cr-III complexes with pendant-arm macrocyclic ligands and formation of discrete Cr-III/Fe-II and Cr-III/Fe-II/Co-III cyano-bridged mixed valence compounds. Dalton Transactions, 2009 (43), 9567-9577. doi: 10.1039/b909151c

Highly twisted C=C double bonds in 4-methyleneisoxazolones

Kvaskoff, David, Bernhardt, Paul V., Koch, Rainer and Wentrup, Curt (2009). Highly twisted C=C double bonds in 4-methyleneisoxazolones. Australian Journal of Chemistry, 62 (9), 1068-1078. doi: 10.1071/CH09359

Towards the total synthesis of 3-hydroxyvibsanin E

Schwartz, Brett D., Denton, Justin R., Bernhardt, Paul V., Davies, Huw M. L. and Williams, Craig M. (2009). Towards the total synthesis of 3-hydroxyvibsanin E. Synthesis, 2009 (17), 2840-2846. doi: 10.1055/s-0029-1216912

Thiosemicarbazones from the old to new: Iron chelators that are more than just ribonucleotide reductase inhibitors

Yu, Yu, Kalinowski, Danuta S., Kovacevic, Zaklina, Siafakas, Aritee R., Jansson, Patric J., Stefani, Christian, Lovejoy, David B., Sharpe, Philip C., Bernhardt, Paul V. and Richardson, Des R. (2009). Thiosemicarbazones from the old to new: Iron chelators that are more than just ribonucleotide reductase inhibitors. Journal of Medicinal Chemistry, 52 (17), 5271-5294. doi: 10.1021/jm900552r

Synthesis and variable coordination modes of a bis-thiophene-appended macrocycle in complex with cobalt(III)

Hasan, Sharizal and Bernhardt, Paul V. (2009). Synthesis and variable coordination modes of a bis-thiophene-appended macrocycle in complex with cobalt(III). Journal of Inclusion Phenomena and Macrocyclic Chemistry, 65 (1), 39-47. doi: 10.1007/s10847-009-9612-z

Synthesis of cis-vinyltrimethylstannanes and cis-vinylpinacolboronates in a two-step highly regio and stereoselective process

Mirzayans, Paul Malek, Pouwer, Rebecca H., Williams, Craig M. and Bernhardt, Paul V. (2009). Synthesis of cis-vinyltrimethylstannanes and cis-vinylpinacolboronates in a two-step highly regio and stereoselective process. Tetrahedron, 65 (39), 8297-8305. doi: 10.1016/j.tet.2009.06.092

Molecular Co(III)/Fe(II) cyano-bridged mixed-valence compounds with high nuclearities and diversity of Co(III) coordination environments: Preparative and mechanistic aspects

Bernhardt, Paul V., Martínez, Manuel and Rodríguez, Carlos (2009). Molecular Co(III)/Fe(II) cyano-bridged mixed-valence compounds with high nuclearities and diversity of Co(III) coordination environments: Preparative and mechanistic aspects. Inorganic Chemistry, 48 (11), 4787-4797. doi: 10.1021/ic802198s

Magnetic, spectroscopic and X-ray crystallographic structural studies on copper(II) complexes of tridentate NNS Schiff base ligands formed from 2-acetylpyrazine and S-methyl- and S-benzyldithiocarbazates

Hamid, Malai Haniti S. A., Ali, Mhammad Akbar, Mirza, Aminul Huq, Bernhardt, Paul V., Moubaraki, Boujemaa and Murray, Keith S. (2009). Magnetic, spectroscopic and X-ray crystallographic structural studies on copper(II) complexes of tridentate NNS Schiff base ligands formed from 2-acetylpyrazine and S-methyl- and S-benzyldithiocarbazates. Inorganica Chimica Acta, 362 (10), 3648-3656. doi: 10.1016/j.ica.2009.04.019

Absolute structures and conformations of the spongian diterpenes spongia-13(16), 14-dien-3-one, epispongiadiol and spongiadiol

Yong, Ken W., L., Garson, Mary J. and Bernhardt, Paul V. (2009). Absolute structures and conformations of the spongian diterpenes spongia-13(16), 14-dien-3-one, epispongiadiol and spongiadiol. Acta Crystallographica Section C - Crystal Structure Communications, 65 (4), o167-o170. doi: 10.1107/S0108270109008816

Mediated electrochemistry of dimethyl sulfoxide reductase from Rhodobacter capsulatus

Kuan-I Chen, McEwan, Alastair G. and Bernhardt, Paul V. (2009). Mediated electrochemistry of dimethyl sulfoxide reductase from Rhodobacter capsulatus. Journal of Biological Inorganic Chemistry, 14 (3), 409-419. doi: 10.1007/s00775-008-0458-4

2-acetylpyridine thiosemicarbazones are potent iron chelators and antiproliferative agents: Redox activity, iron complexation and characterization of their antitumor activity

Richardson, Des R., Kalinowski, Danuta S., Richardson, Vera, Sharpe, Philip C., Lovejoy, David B., Islam, Mohammad and Bernhardt, Paul V. (2009). 2-acetylpyridine thiosemicarbazones are potent iron chelators and antiproliferative agents: Redox activity, iron complexation and characterization of their antitumor activity. Journal of Medicinal Chemistry, 52 (5), 1459-1470. doi: 10.1021/jm801585u

Intramolecular electron transfer in sulfite-oxidizing enzymes: Elucidating the role of a conserved active site arginine

Emesh, Safia, Rapson, Trevor D., Rajapakshe, Asha, Kappler, Ulrike, Bernhardt, Paul V., Tollin, Gordon and Enemark, John H. (2009). Intramolecular electron transfer in sulfite-oxidizing enzymes: Elucidating the role of a conserved active site arginine. Biochemistry, 48 (10), 2156-2163. doi: 10.1021/bi801553q

Iron chelators of the dipyridylketone thiosemicarbazone class: Precomplexation and transmetalation effects on anticancer activity

Bernhardt, Paul V., Sharpe, Philip C., Islam, Mohammed, Lovejoy, David B., Kalinowski, Danuta S. and Richardson, Des R. (2009). Iron chelators of the dipyridylketone thiosemicarbazone class: Precomplexation and transmetalation effects on anticancer activity. Journal of Medicinal Chemistry, 52 (2), 407-415. doi: 10.1021/jm801012z

Ring opening and ring expansion of 8-cyano-tetrazolo[1,5-alpha]pyridine with secondary amines. Reactions of azides, tetrazoles and nitrenes with nucleophiles, part 2

Addicott, Chris, Bernhardt, Paul V. and Wentrup, Curt (2009). Ring opening and ring expansion of 8-cyano-tetrazolo[1,5-alpha]pyridine with secondary amines. Reactions of azides, tetrazoles and nitrenes with nucleophiles, part 2. ARKIVOC, 2009 (vi), 30-37. doi: 10.3998/ark.5550190.0010.604

Communication with the Mononuclear Molybdoenzymes: Emerging Opportunities and Applications in Redox Enzyme Biosensors

Bernhardt, Paul V. (2009). Communication with the Mononuclear Molybdoenzymes: Emerging Opportunities and Applications in Redox Enzyme Biosensors. Engineering the Bioelectronic Interface: Applications to Analyte Biosensing and Protein Detection, 1-24. doi: 10.1039/9781847559777-00001

The absolute configurations of haliclonacyclamines A and B determined by X-ray crystallographic analysis

Mudianta, I. Wayan, Garson, Mary J. and Bernhardt, Paul V. (2009). The absolute configurations of haliclonacyclamines A and B determined by X-ray crystallographic analysis. Australian Journal of Chemistry, 62 (7), 667-670. doi: 10.1071/CH09128

A mechanistic and electrochemical study of the interaction between dimethyl sulfide dehydrogenase and its electron transfer partner cytochrome c(2)

Creevey, Nicole L., McEwan, Alastair G. and Bernhardt, Paul V. (2008). A mechanistic and electrochemical study of the interaction between dimethyl sulfide dehydrogenase and its electron transfer partner cytochrome c(2). Journal of Biological Inorganic Chemistry, 13 (8), 1231-1238. doi: 10.1007/s00775-008-0406-3

End game strategies towards the total synthesis of vibsanin E, 3-hydroxyvibsanin E, furanovibsanin A, and 3-O-methylfuranovibsanin A

Schwartz, Brett D., Williams, Craig M. and Bernhardt, Paul V. (2008). End game strategies towards the total synthesis of vibsanin E, 3-hydroxyvibsanin E, furanovibsanin A, and 3-O-methylfuranovibsanin A. Beilstein Journal of Organic Chemistry, 4 (1) 34, 1-9. doi: 10.3762/bjoc.4.34

The effects of pendant vs. fused thiophene attachment upon the luminescence lifetimes and electrochemistry of tris(2,2′-bipyridine)ruthenium(II) complexes

Nurkkala, Lasse J., Steen, Robert O., Friberg, Henrik K. J., Häggström, Johanna A., Bernhardt, Paul V., Riley, Mark J. and Dunne, Simon J. (2008). The effects of pendant vs. fused thiophene attachment upon the luminescence lifetimes and electrochemistry of tris(2,2′-bipyridine)ruthenium(II) complexes. European Journal of Inorganic Chemistry, 2008 (26), 4101-4110. doi: 10.1002/ejic.200800456

Exploiting the Anders-Gassner variant on the Wittig reaction: new methodology for the synthesis of 3,3-dimethylacroyl enol esters

Schwartz, Brett D., Williams, Craig M., Anders, Ernst and Bernhardt, Paul V. (2008). Exploiting the Anders-Gassner variant on the Wittig reaction: new methodology for the synthesis of 3,3-dimethylacroyl enol esters. Tetrahedron, 64 (27), 6482-6487. doi: 10.1016/j.tet.2008.04.068

SoxAX cytochromes, a new type of heme copper protein involved in bacterial energy generation from sulfur compounds

Kappler, U., Bernhardt, P.V., Kilmartin, J., Riley, M.J., Teschner, J., McKenzie, K.J. and Hanson, G.R. (2008). SoxAX cytochromes, a new type of heme copper protein involved in bacterial energy generation from sulfur compounds. Journal of Biological Chemistry, 283 (32), 22206-22214. doi: 10.1074/jbc.M800315200

Direct catalytic electrochemistry of sulfite dehydrogenase: Mechanistic insights and contrasts with related Mo enzymes

Rapson, Trevor D., Kappler, Ulrike and Bernhardt, Paul V. (2008). Direct catalytic electrochemistry of sulfite dehydrogenase: Mechanistic insights and contrasts with related Mo enzymes. Biochimica Et Biophysica Acta-bioenergetics, 1777 (10), 1319-1325. doi: 10.1016/j.bbabio.2008.06.005

The role of isomeric effects on the luminescence lifetimes and electrochemistry of oligothienyl-bridged dinuclear tris(2,2′-bipyridine) ruthenium(II) complexes

Steen, Robert O., Nurkkala, Lasse J., Angus-Dunne, Sarah J., Schmitt, Chantal X., Constable, Edwin C., Riley, Mark J., Bernhardt, Paul V. and Dunne, Simon J. (2008). The role of isomeric effects on the luminescence lifetimes and electrochemistry of oligothienyl-bridged dinuclear tris(2,2′-bipyridine) ruthenium(II) complexes. European Journal of Inorganic Chemistry, 2008 (11), 1784-1794. doi: 10.1002/ejic.200701118

Thermodynamic characterization of the redox centers within dimethylsulfide dehydrogenase

Creevey, N.L., McEwan, A.G., Hanson, G.R. and Bernhardt, P.V. (2008). Thermodynamic characterization of the redox centers within dimethylsulfide dehydrogenase. Biochemistry, 47 (12), 3770-3776. doi: 10.1021/bi702444r

Solvochromic effects in model eumelanin compounds

Nighswander-Rempel, Stephen P., Mahadevan, Indumathy B., Bernhardt, Paul V., Butcher, Jessica and Meredith, Paul (2008). Solvochromic effects in model eumelanin compounds. Photochemistry and Photobiology, 84 (3), 620-626. doi: 10.1111/j.1751-1097.2007.00290.x

Preparation, spectroscopic characterization and X-ray crystal and molecular structures of nickel(II), copper(II) and zinc(II) complexes of the Schiff base formed from isatin and S-methyldithiocarbazate (Hisa-sme)

Akbar Ali, M., Abu Bakar, Junaidah Hj, Mirza, A. H., Smith, S. J., Gahan, L. R. and Bernhardt, Paul V. (2008). Preparation, spectroscopic characterization and X-ray crystal and molecular structures of nickel(II), copper(II) and zinc(II) complexes of the Schiff base formed from isatin and S-methyldithiocarbazate (Hisa-sme). Polyhedron, 27 (1), 71-79. doi: 10.1016/j.poly.2007.08.022

Synthesis, spectroscopic and structural characterization of diphenyltin(IV)complexes of acetone Schiff bases of S-alkyldithiocarbazates

Ali, M.A., Mirza, A.H., Hamid, M.H.A.A., Bernhardt, P.V., Atchade, O., Song, X., Eng, G. and May, L. (2008). Synthesis, spectroscopic and structural characterization of diphenyltin(IV)complexes of acetone Schiff bases of S-alkyldithiocarbazates. Polyhedron, 27 (27), 977-984. doi: 10.1016/j.poly.2007.11.030

Structure-activity relationships of novel iron chelators for the treatment of iron overload disease: The methyl pyrazinylketone isonicotinoyl hydrazone series

Kalinowski, Danuta S., Sharpe, Philip C., Bernhardt, Paul V. and Richardson, Des R. (2008). Structure-activity relationships of novel iron chelators for the treatment of iron overload disease: The methyl pyrazinylketone isonicotinoyl hydrazone series. Journal of Medicinal Chemistry, 51 (2), 331-344. doi: 10.1021/jm7012562

Tailoring mixed-valence Co-III/Fe-II complexes for their potential use as sensitizers in dye sensitized solar cells

Bernhardt, Paul V., Boschloo, Gerrit K., Bozoglian, Fernando, Hagfeldt, Anders, Martinez, Manuel and Sienrad, Beatriz (2008). Tailoring mixed-valence Co-III/Fe-II complexes for their potential use as sensitizers in dye sensitized solar cells. New Journal of Chemistry, 32 (4), 705-711. doi: 10.1039/b716855a

Tuning the antiproliferative activity of biologically active iron chelators: characterization of the coordination chemistry and biological efficacy of 2-acetylpyridine and 2-benzoylpyridine hydrazone ligands

Bernhardt, P.V., Wilson, G.J., Sharpe, P.C., Kalinowski, D.S. and Richardson, D.R. (2008). Tuning the antiproliferative activity of biologically active iron chelators: characterization of the coordination chemistry and biological efficacy of 2-acetylpyridine and 2-benzoylpyridine hydrazone ligands. Journal of Biological Inorganic Chemistry, 13 (1), 107-119. doi: 10.1007/s00775-007-0300-4

Twisted push-pull ethylenes

Naduvile Veedu, Rakesh, Bernhardt, Paul V., Koch, Rainer and Wentrup, Curt (2008). Twisted push-pull ethylenes. Australian Journal of Chemistry, 61 (10), 805-812. doi: 10.1071/CH08277

The influence of ligand substitution at the electron donor center in molecular cyano-bridged mixed-valent CoIII/FeII and CoIII/RuII complexes

Bernhardt, Paul V., Bozoglian, Fernando, Font-Bardía, Mercè, Martínez, Manuel, Meacham, Andrew P., Sienra, Beatriz and Solans, Xavier (2007). The influence of ligand substitution at the electron donor center in molecular cyano-bridged mixed-valent CoIII/FeII and CoIII/RuII complexes. European Journal of Inorganic Chemistry, 2007 (33), 5270-5276. doi: 10.1002/ejic.200700731

Design, synthesis, and characterization of new iron chelators with anti-proliferative activity: Structure-activity relationships of novel thiohydrazone analogues

Kalinowski, DS, Sharpe, PC, Bernhardt, PV and Richardson, DR (2007). Design, synthesis, and characterization of new iron chelators with anti-proliferative activity: Structure-activity relationships of novel thiohydrazone analogues. Journal of Medicinal Chemistry, 50 (24), 6212-6225. doi: 10.1021/jm070839q

PrrC, a Sco homologue from Rhodobacter sphaeroides, possesses thiol-disulfide oxidoreductase activity

Badrick, Alison C., Hamilton, Amanda J., Bernhardt, Paul V., Jones, Christopher E., Kappler, Ulrike, Jennings, Michael P. and McEwan, Alastair G. (2007). PrrC, a Sco homologue from Rhodobacter sphaeroides, possesses thiol-disulfide oxidoreductase activity. FEBS Letters, 581 (24), 4663-4667. doi: 10.1016/j.febslet.2007.08.058

Investigating direct access to 2-oxospiro[4.5]decanones via 6 pi-electrocyclisation

Pouwer, Rebecca H., Schill, Heiko, Williams, Craig M. and Bernhardt, Paul V. (2007). Investigating direct access to 2-oxospiro[4.5]decanones via 6 pi-electrocyclisation. European Journal of Organic Chemistry, 2007 (28), 4699-4705. doi: 10.1002/ejoc.200700367

Bis{methyl [1-(6-acetyl-2-pyridyl)ethylidene]hydrazinecarbodithioato}nickel(II)

Ali, Mohammad Akbar, Mirza, Aminul Huq and Bernhardt, Paul V. (2007). Bis{methyl [1-(6-acetyl-2-pyridyl)ethylidene]hydrazinecarbodithioato}nickel(II). Acta Crystallographica Section E: Structure Reports Online, 63 (9), m2255-m2255. doi: 10.1107/S1600536807037129

Design, synthesis, and characterization of novel iron chelators: Structure-activity relationships of the 2-benzoylpyridine thiosemicarbazone series and their 3-nitrobenzoyl analogues as potent antitumor agents

Kalinowski, D. S., Yu, Y., Sharpe, P. C., Islam, M., Liao, Y. T., Lovejoy, D. B., Kumar, N., Bernhardt, P. V. and Richardson, D. R. (2007). Design, synthesis, and characterization of novel iron chelators: Structure-activity relationships of the 2-benzoylpyridine thiosemicarbazone series and their 3-nitrobenzoyl analogues as potent antitumor agents. Journal of Medicinal Chemistry, 50 (15), 3716-3729. doi: 10.1021/jm070445z

Hydrazone chelators for the treatment of iron overload disorders: iron coordination chemistry and biological activity

Bernhardt, Paul V., Chin, Piao, Sharpe, Philip C. and Richardson, Des R. (2007). Hydrazone chelators for the treatment of iron overload disorders: iron coordination chemistry and biological activity. Dalton Transactions, 2007 (30), 3232-3244. doi: 10.1039/b704102k

A functionalised macrobicycle complex available for surface immobilisation and protein grafting

Bernhardt, Paul V., Harrowfield, Jack M., Kim, Yang, Lee, Young Hoon, Park, Yu Cheol and Sujandi (2007). A functionalised macrobicycle complex available for surface immobilisation and protein grafting. Bulletin of The Korean Chemical Society, 28 (4), 589-595. doi: 10.5012/bkcs.2007.28.4.589

The stereo structures of some mycophenolic acid derivatives

Bernhardt, PV, Carman, RM and Le, TT (2007). The stereo structures of some mycophenolic acid derivatives. Australian Journal of Chemistry, 60 (5), 354-357. doi: 10.1071/CH06481

An expanded cavity hexaamine cage for copper(II)

Bernhardt, Paul V., Bramley, Richard, Geue, Rodney J., Ralph, Stephen F. and Sargeson, Alan M. (2007). An expanded cavity hexaamine cage for copper(II). Dalton Transactions, 2007 (12), 1244-1249. doi: 10.1039/b617153b

Isolation and structural characterization of di- and tetra-protonated forms of the macrocyclic hexaamine trans-6,13-dimethyl-1,4,8-11-tetraazacyclodecane-6,13-diamine

Bernhardt, Paul V., Lawrance, Geoffrey A., Skelton, Brian W. and White, Allan H. (2007). Isolation and structural characterization of di- and tetra-protonated forms of the macrocyclic hexaamine trans-6,13-dimethyl-1,4,8-11-tetraazacyclodecane-6,13-diamine. Zeitschrift Fur Anorganische Und Allgemeine Chemie, 633 (7), 1036-1039. doi: 10.1002/zaac.200700055

The NT-26 cytochrome c552 and its role in arsenite oxidation

Santini, J. M., Kappler, U., Ward, S. A., Honeychurch, M. J., vanden Hoven, R. N. and Bernhardt, P. V. (2007). The NT-26 cytochrome c552 and its role in arsenite oxidation. Biochimica et Biophysica Acta, 1767 (2), 189-196. doi: 10.1016/j.bbabio.2007.01.009

Coordination chemistry and biology of chelators for the treatment of iron overload disorders

Bernhardt, Paul V. (2007). Coordination chemistry and biology of chelators for the treatment of iron overload disorders. Dalton Transactions (30), 3214-3220. doi: 10.1039/b708133b

Investigating direct alkynylation at the bridgehead of bicyclic cages using silver(I) acetylides

Pouwer, R. H., Harper, J. B., Vyakaranam, K., Michl, J., Williams, C. M., Jessen, C. H. and Bernhardt, P. V. (2007). Investigating direct alkynylation at the bridgehead of bicyclic cages using silver(I) acetylides. European Journal of Organic Chemistry, 2007 (2), 241-248. doi: 10.1002/ejoc.200600701

Macrocyclic cobalt(III) complexes as precursors for metal-polythiophene hybrid materials

Bernhardt, P. and Kilah, N. (2007). Macrocyclic cobalt(III) complexes as precursors for metal-polythiophene hybrid materials. Polyhedron, 26 (2), 392-399. doi: 10.1016/j.poly.2006.07.001

Direct electrochemistry of human and rat NADPH cytochrome P450 reductase

Shukla, Alka, Gillam, Elizabeth M. J. and Bernhardt, Paul V. (2006). Direct electrochemistry of human and rat NADPH cytochrome P450 reductase. Electrochemistry Communications, 8 (12), 1845-1849. doi: 10.1016/j.elecom.2006.08.020

Preparation and characterization of pentagonal-bipyramidal zinc(II) and cadmium(II) complexes of a neutral N3S2 thiosemicarbazone derived from N-2-methylthiosemicarbazide and the X-ray crystal and molecular structures of the free ligand and its cadmium(II

Ali, M. A., Mirza, A. H., Ejau, W. B. and Bernhardt, P. V. (2006). Preparation and characterization of pentagonal-bipyramidal zinc(II) and cadmium(II) complexes of a neutral N3S2 thiosemicarbazone derived from N-2-methylthiosemicarbazide and the X-ray crystal and molecular structures of the free ligand and its cadmium(II. Polyhedron, 25 (17), 3337-3342. doi: 10.1016/j.poly.2006.06.003

Synthesis, characterization and X-ray crystallographic structural study of copper(II) and nickel(II) complexes of the 2-quinoline carboxaldehyde Schiff base of S-methyldithiocarbazate (Hqaldsme)

Ali, M. Akbar, Mirza, A. H., Bujang, Fatriah Hj., Hamid, Malai Haniti S.A. and Bernhardt, Paul V. (2006). Synthesis, characterization and X-ray crystallographic structural study of copper(II) and nickel(II) complexes of the 2-quinoline carboxaldehyde Schiff base of S-methyldithiocarbazate (Hqaldsme). Polyhedron, 25 (17), 3245-3252. doi: 10.1016/j.poly.2006.05.027

1,3-Dimethylisoguanine

Panthong, K., Garson, M. J. and Bernhardt, P. V. (2006). 1,3-Dimethylisoguanine. Acta Crystallographica Section C-crystal Structure Communications, 62 (4), O193-O195. doi: 10.1107/S0108270106005336

2-Methoxy-6-methyl-3-nitro-4-(2-nitroprop-1-enyl)phenyl acetate

Moore, E. G., Meredith, P. and Bernhardt, P. V. (2006). 2-Methoxy-6-methyl-3-nitro-4-(2-nitroprop-1-enyl)phenyl acetate. Acta Crystallographica Section E, 61 (6), o1709-o1711. doi: 10.1107/S1600536805014212

Azedaralide: total synthesis, relative and absolute stereochemical assignment

Baker, L. A., Williams, C. M., Bernhardt, P. V. and Yanik, G. W. (2006). Azedaralide: total synthesis, relative and absolute stereochemical assignment. Tetrahedron, 62 (31), 7355-7360. doi: 10.1016/j.tet.2006.05.030

Cobalt complexes of tripodal hexadentate ligands: Electrochemically driven rearrangements

Bernhardt, P. V., Kim, Y. and Sujandi (2006). Cobalt complexes of tripodal hexadentate ligands: Electrochemically driven rearrangements. Australian Journal of Chemistry, 59 (11), 783-790. doi: 10.1071/CH06257

Complexes of cytotoxic chelators from the dipyridyl ketone isonicotinoyl hydrazone (HPKIH) analogues

Bernhardt, P. V., Mattsson, J. and Richardson, D. R. (2006). Complexes of cytotoxic chelators from the dipyridyl ketone isonicotinoyl hydrazone (HPKIH) analogues. Inorganic Chemistry, 45 (2), 752-760. doi: 10.1021/ic051573l

Determination of the anomeric configurations of 2,3,4,6-tetra-O-acetyl-D-mannopyranosyl azide

Cosgrove, K. L., Bernhardt, P. V., Ross, B. P. and McGeary, R. P. (2006). Determination of the anomeric configurations of 2,3,4,6-tetra-O-acetyl-D-mannopyranosyl azide. Australian Journal of Chemistry, 59 (2), 473-476. doi: 10.1071/CH06157

Dimeric allylpalladium(II) complexes with pyrazolate bridges: Synthesis, characterization, structure and thermal behaviour

Singhal, A., Mishra, R., Kulshreshtha, S. K., Bernhardt, P. V. and Tiekink, E. R. T. (2006). Dimeric allylpalladium(II) complexes with pyrazolate bridges: Synthesis, characterization, structure and thermal behaviour. Journal of Organometallic Chemistry, 691 (7), 1402-1410. doi: 10.1016/j.jorganchem.2005.12.037

Dinuclear cyano-bridged Co-III-Fe-II complexes as precursors for molecular mixed-valence complexes of higher nuclearity

Bernhardt, P. V., Bozoglian, F., Gonzalez, G., Martinez, M., Macpherson, B. P. and Sienra, B. (2006). Dinuclear cyano-bridged Co-III-Fe-II complexes as precursors for molecular mixed-valence complexes of higher nuclearity. Inorganic Chemistry, 45 (1), 74-82. doi: 10.1021/ic0511423

Dipyridyl thiosemicarbazone chelators with potent and selective antitumor activity form iron complexes with redox activity

Richardson, D. R., Sharpe, P. C., Lovejoy, D. B., Senaratne, D., Kalinowski, D. S., Islam, M. and Bernhardt, P. V. (2006). Dipyridyl thiosemicarbazone chelators with potent and selective antitumor activity form iron complexes with redox activity. Journal of Medicinal Chemistry, 49 (22), 6510-6521. doi: 10.1021/jm0606342

Direct electrochemically driven catalysis of bovine milk xanthine oxidase

Bernhardt, P. V., Honeychurch, M. J. and McEwan, A. G. (2006). Direct electrochemically driven catalysis of bovine milk xanthine oxidase. Electrochemistry Communications, 8 (2), 257-261. doi: 10.1016/j.elecom.2005.08.009

Electronic energy-transfer rate constants for geometrical isomers of a bichromophoric macrocyclic complex

Moore, E. G., Bernhardt, P. V., Riley, M. J. and Smith, T. A. (2006). Electronic energy-transfer rate constants for geometrical isomers of a bichromophoric macrocyclic complex. Inorganic Chemistry, 45 (1), 51-58. doi: 10.1021/ic050396l

Enzyme Electrochemistry - Biocatalysis on an electrode

Bernhardt, P. V. (2006). Enzyme Electrochemistry - Biocatalysis on an electrode. Australian Journal of Chemistry, 59 (4), 233-256. doi: 10.1071/CH05340

Isomeric distribution and catalyzed isomerization of cobalt(III) complexes with pentadentate macrocyclic ligands. Importance of hydrogen bonding

Aullon, Gabriel, Bernhardt, Paul V., Bozoglian, Fernando, Font-Bardia, Merce, Macpherson, Brendan P., Martinez, Manuel, Rodriguez, Carlos and Solans, Xavier (2006). Isomeric distribution and catalyzed isomerization of cobalt(III) complexes with pentadentate macrocyclic ligands. Importance of hydrogen bonding. Inorganic Chemistry, 45 (21), 8551-8562. doi: 10.1021/ic060720s

Kinetic and structural evidence for the importance of Tyr236 for the integrity of the Mo active site in a bacterial sulfite dehydrogenase

Kappler, U., Bailey, S., Feng, C., Honeychurch, M. J., Hanson, G. R., Bernhardt, P. V., Tollin, G. and Enemark, J. H. (2006). Kinetic and structural evidence for the importance of Tyr236 for the integrity of the Mo active site in a bacterial sulfite dehydrogenase. Biochemistry, 45 (32), 9696-9705. doi: 10.1021/bi060058b

PCTH: A novel orally active chelator for the treatment of iron overload disease

Lovejoy, D. B., Kalinowski, D., Bernhardt, P. V. and Richardson, D. R. (2006). PCTH: A novel orally active chelator for the treatment of iron overload disease. Hemoglobin, 30 (1), 93-104. doi: 10.1080/03630260500455367

Polyamines from polyols - Pathways to azamacrocycles with hydroxymethyl pendent groups

Bernhardt, P. V., Cho, J. H., Harrowfield, J. M., Kim, J. Y., Kim, Y., Sujandi, Thuery, P. and Yoon, D. C. (2006). Polyamines from polyols - Pathways to azamacrocycles with hydroxymethyl pendent groups. Polyhedron, 25 (8), 1811-1822. doi: 10.1016/j.poly.2005.11.024

Protein film voltammetry of arsenite oxidase from the chemolithoautotrophic arsenite-oxidizing bacterium NT-26

Bernhardt, P. V. and Santini, J. M. (2006). Protein film voltammetry of arsenite oxidase from the chemolithoautotrophic arsenite-oxidizing bacterium NT-26. Biochemistry, 45 (9), 2804-2809. doi: 10.1021/bi0522448

Synthesis and characterization of Pd(II) and Pt(II) complexes with triazolopyrimidine derivatives: The crystal structure of [Pd2L2Cl4] where L=5,7-dimethyl-1,2,4-triazolo[1,5-a]pyrimidine

Lekkas, Nikos, Hadjiliadis, Nick, Garoufis, Achilleas, Kobe, Joseph, Bernhardt, Paul V. and Tiekink, Edward R.T. (2006). Synthesis and characterization of Pd(II) and Pt(II) complexes with triazolopyrimidine derivatives: The crystal structure of [Pd2L2Cl4] where L=5,7-dimethyl-1,2,4-triazolo[1,5-a]pyrimidine. Inorganica Chimica Acta, 359 (13), 4297-4303. doi: 10.1016/j.ica.2006.06.016

Towards the total synthesis of vibsanin E, 15-O-methylcyclovibsanin B, 3-hydroxyvibsanin E, furanovibsanin A, and 3-O-methylfuranovibsanin A

Schwartz, B. D., Tilly, D. P., Heim, R., Wiedemann, S., Williams, C. M. and Bernhardt, P. V. (2006). Towards the total synthesis of vibsanin E, 15-O-methylcyclovibsanin B, 3-hydroxyvibsanin E, furanovibsanin A, and 3-O-methylfuranovibsanin A. European Journal of Organic Chemistry, 2006 (14), 3181-3192. doi: 10.1002/ejoc.200600246

Transition metal complexes as mediator-titrants in protein redox potentiometry

Bernhardt, P. V., Chen, K. I. and Sharpe, P. C. (2006). Transition metal complexes as mediator-titrants in protein redox potentiometry. Journal of Biological Inorganic Chemistry, 11 (7), 930-936. doi: 10.1007/s00775-006-0148-z

Synthesis, characterization and X-ray crystal structures of dinuclear nickel(II) complexes of a novel potentially hexadentate but functionally tetradentate binucleating ligand

Akbar Ali, Mohammad, Mirza, A. H., Nazimuddin, Mohamed, Karim, Feroza and Bernhardt, Paul V. (2005). Synthesis, characterization and X-ray crystal structures of dinuclear nickel(II) complexes of a novel potentially hexadentate but functionally tetradentate binucleating ligand. Inorganica Chimica Acta, 358 (15), 4548-4554. doi: 10.1016/j.ica.2005.08.022

Novel diaroylhydrazine ligands as iron chelators: coordination chemistry and biological activity

Bernhardt, Paul V., Chin, Piao, Sharpe, Philip C., Wang, Jing-Yan C. and Richardson, Des R. (2005). Novel diaroylhydrazine ligands as iron chelators: coordination chemistry and biological activity. Journal of Biological Inorganic Chemistry, 10 (7), 761-777. doi: 10.1007/s00775-005-0018-0

Cyanocobalt(III) complexes of penta- and tetradentate-coordinated macrocyclic hexaamines

Bernhardt, Paul V. and Kilah, Nathan L. (2005). Cyanocobalt(III) complexes of penta- and tetradentate-coordinated macrocyclic hexaamines. Acta Crystallographica Section C-crystal Structure Communications, 61 (5), M245-M249. doi: 10.1107/S0108270105009261

Pressure and temperature effects on metal-to-metal charge transfer in cyano-bridged Co-III-Fe-II complexes

Macpherson, Brendan P., Alzoubi, Basam M., Bernhardt, Paul V., Martinez, Manuel, Tregloan, Peter A. and van Eldik, Rudi (2005). Pressure and temperature effects on metal-to-metal charge transfer in cyano-bridged Co-III-Fe-II complexes. Dalton Transactions (8), 1459-1467. doi: 10.1039/b418054b

Direct electrochemistry of enzymes from the cytochrome P4502C family

Shukla, Alka, Gillam, Elizabeth M., Mitchell, Deanne J. and Bernhardt, Paul V. (2005). Direct electrochemistry of enzymes from the cytochrome P4502C family. Electrochemistry Communications, 7 (4), 437-442. doi: 10.1016/j.elecom.2005.02.021

Macrocycles and medicine - facile synthesis of a bis(macrocycle) with pendent functionality

Bernhardt, Paul V., Kim, Jee Young, Kim, Yang, Lee, Young Hoon and Chow, Sujandi (2005). Macrocycles and medicine - facile synthesis of a bis(macrocycle) with pendent functionality. Comptes Rendus Chimie, 8 (2), 211-214. doi: 10.1016/j.crci.2004.10.024

Construction of the cyclovibsanin core via a biogenetically modeled approach

Tilly, David P., Williams, Craig M. and Bernhardt, Paul V. (2005). Construction of the cyclovibsanin core via a biogenetically modeled approach. Organic Letters, 7 (23), 5155-5157. doi: 10.1021/ol051897d

Diphenyltin(IV) complexes of the 2-quinolinecarboxaldehyde Schiff bases of S-methyl- and S-benzyldithiocarbazate (Hqaldsme and Hqaldsbz): X-ray crystal structures of Hqaldsme and two conformers of its diphenyltin(IV) complex

Ali, M. A., Mirza, A. H., Hamid, M. H. S. A. and Bernhardt, P. V. (2005). Diphenyltin(IV) complexes of the 2-quinolinecarboxaldehyde Schiff bases of S-methyl- and S-benzyldithiocarbazate (Hqaldsme and Hqaldsbz): X-ray crystal structures of Hqaldsme and two conformers of its diphenyltin(IV) complex. Polyhedron, 24 (3), 383-390. doi: 10.1016/j.poly.2004.11.023

Expedient construction of the vibsanin E core without the use of protecting groups

Heim, Ralf, Wiedemann, Stefan, Williams, Craig M. and Bernhardt, Paul V. (2005). Expedient construction of the vibsanin E core without the use of protecting groups. Organic Letters, 7 (7), 1327-1329. doi: 10.1021/ol0501222

Immobilisation of electroactive macrocyclic complexes within titania films

Bernhardt, P. V., Kilah, N. L., Meacham, A., Meredith, P. and Vogel, R. (2005). Immobilisation of electroactive macrocyclic complexes within titania films. Dalton Transactions (15), 2508-2515. doi: 10.1039/b505917h

Intra- vs intermolecular photoinduced electron transfer reactions of a macrocyclic donor-acceptor dyad

Moore, E. G., Bernhardt, P. V., Furstenberg, A., Riley, M. J. and Vauthey, E. (2005). Intra- vs intermolecular photoinduced electron transfer reactions of a macrocyclic donor-acceptor dyad. Journal of Physical Chemistry A, 109 (51), 11715-11723. doi: 10.1021/jp0547414

Investigating direct routes to an advanced intermediate for the synthesis of C-20 diterpene alkaloids

Williams, C. M., Mander, L. N., Bernhardt, P. V. and Willis, A. C. (2005). Investigating direct routes to an advanced intermediate for the synthesis of C-20 diterpene alkaloids. Tetrahedron, 61 (15), 3759-3769. doi: 10.1016/j.tet.2005.02.014

Mesoionic 1,3-oxazinium olates. Rearrangement to acylketenes and 3-azabicyclo[3.1.1]heptanetriones

Sheibani, H., Bernhardt, P. V. and Wentrup, C. (2005). Mesoionic 1,3-oxazinium olates. Rearrangement to acylketenes and 3-azabicyclo[3.1.1]heptanetriones. Journal of Organic Chemistry, 70 (15), 5859-5861. doi: 10.1021/jo050428m

Molecular mixed-valence cyanide bridged Co-III-Fe-II complexes

Bernhardt, P. V., Bozoglian, F., Macpherson, B. P. and Martinez, M. (2005). Molecular mixed-valence cyanide bridged Co-III-Fe-II complexes. Coordination Chemistry Reviews, 249 (17-18), 1902-1916. doi: 10.1016/j.ccr.2004.11.014

Nitrogen is a requirement for the photochemical induced 3-azabicyclo[3.3.1]nonane skeletal rearrangement!

Williams, C. M., Heim, R. and Bernhardt, P. V. (2005). Nitrogen is a requirement for the photochemical induced 3-azabicyclo[3.3.1]nonane skeletal rearrangement!. Tetrahedron, 61 (15), 3771-3779. doi: 10.1016/j.tet.2005.02.013

On the steady-state assumption and its application to the rotating disk voltammetry of adsorbed enzymes

Honeychurch, M. J. and Bernhardt, P. V. (2005). On the steady-state assumption and its application to the rotating disk voltammetry of adsorbed enzymes. Journal of Physical Chemistry B, 109 (12), 5766-5773. doi: 10.1021/jp0454570

Synthesis, characterization and X-ray crystal structures of dinuclear nickel(II) complexes of a novel potentially hexadentate but functionally tetradentate binucleating ligand

Ali, M. A., Mirza, A. H., Nazimuddin, M., Karim, F. and Bernhardt, P. V. (2005). Synthesis, characterization and X-ray crystal structures of dinuclear nickel(II) complexes of a novel potentially hexadentate but functionally tetradentate binucleating ligand. Inorganica Chimica Acta, 358 (15), 4548-4554. doi: 10.1016/j.jca.2005.08.022

The 1,3-diaxial dibromo interaction

Bernhardt, P. V., Carman, R. M. and Le, T. T. (2005). The 1,3-diaxial dibromo interaction. Australian Journal of Chemistry, 58 (7), 535-538. doi: 10.1071/CH05043

Time-resolved spectroscopy of the metal-to-metal charge transfer excited state in dinuclear cyano-bridged mixed-valence complexes

Macpherson, B. P., Bernhardt, P. V., Hauser, A., Pages, S. and Vauthey, E. (2005). Time-resolved spectroscopy of the metal-to-metal charge transfer excited state in dinuclear cyano-bridged mixed-valence complexes. Inorganic Chemistry, 44 (15), 5530-5536. doi: 10.1021/ic0506512

Tuning the photophysical behavior of luminescent cyclam derivatives by cation binding and excited state redox potential

Moore, E. G., Bernhardt, P. V., Furstenberg, A., Riley, M. J., Smith, T. and Vauthey, E. (2005). Tuning the photophysical behavior of luminescent cyclam derivatives by cation binding and excited state redox potential. Journal of Physical Chemistry A, 109 (17), 3788-3796. doi: 10.1021/jp044221t

Electrochemical anion recognition with ferrocene functionalised macrocycles

Bernhardt, Paul V. and Creevey, Nicole L. (2004). Electrochemical anion recognition with ferrocene functionalised macrocycles. Journal of the Chemical Society. Dalton Transactions, 4 (6), 914-920. doi: 10.1039/b400538d

Novel one-dimensional structures and solution behaviour of copper(II) bromide and chloride complexes of a new pentapyridyldiamine ligand

Lonnon, David G., Craig, Donald C., Colbran, Stephen B. and Bernhardt, Paul V. (2004) Novel one-dimensional structures and solution behaviour of copper(II) bromide and chloride complexes of a new pentapyridyldiamine ligand. Dalton Transactions, 4 5: 778-787. doi:10.1039/b315202b

1H-1,3-Diazepines, 5H-1,3-diazepines, 1,3-diazepinones, and 2,4-diazabicyclo[3.2.0]heptenes

Reisinger, A., Koch, R., Bernhardt, P. V. and Wentrup, C. (2004). 1H-1,3-Diazepines, 5H-1,3-diazepines, 1,3-diazepinones, and 2,4-diazabicyclo[3.2.0]heptenes. Organic & Biomolecular Chemistry, 2 (8), 1227-1238. doi: 10.1039/b317099c

A numerical approach to modeling the catalytic voltammetry of surface-confined redox enzymes

Honeychurch, M. J. and Bernhardt, P. V. (2004). A numerical approach to modeling the catalytic voltammetry of surface-confined redox enzymes. Journal of Physical Chemistry B, 108 (40), 15900-15909. doi: 10.1021/jp047808g

Concerning the proposed structure of (+)-laurobtusol: Spectral discrepancies with synthetic, racemic Stereoisomers

Blanchfield, Joanne T., Chow, Sharon, Bernhardt, Paul V., Kennard, Colin H. L. and Kitching, William (2004). Concerning the proposed structure of (+)-laurobtusol: Spectral discrepancies with synthetic, racemic Stereoisomers. Australian Journal of Chemistry, 57 (7), 673-676. doi: 10.1071/CH04047

Cytochrome c(551) from Starkeya novella - Characterization, spectroscopic properties, and phylogeny of a diheme protein of the SoxAX family

Kappler, U., Aguey-Zinsou, K. F., Hanson, G. R., Bernhardt, P. V. and McEwan, A. G. (2004). Cytochrome c(551) from Starkeya novella - Characterization, spectroscopic properties, and phylogeny of a diheme protein of the SoxAX family. The Journal of Biological Chemistry, 279 (8), 6252-6260. doi: 10.1074/jbc.M310644200

Direct electrochemistry of porcine purple acid phosphatase (uteroferrin)

Bernhardt, P. V., Schenk, G. and Wilson, G. J. (2004). Direct electrochemistry of porcine purple acid phosphatase (uteroferrin). Biochemistry, 43 (32), 10387-10392. doi: 10.1021/bi0490338

Electrochemical anion recognition with ferrocene functionalised macrocycles

Bernhardt, Paul V. and Creevey, Nicole L. (2004). Electrochemical anion recognition with ferrocene functionalised macrocycles. Dalton Transactions, 6 (6), 914-920. doi: 10.1039/b400538d

Functionalized macrocycles from functionalized tetra-amines: Pendent-arm macrocycles derived from dichloropivalic acid

Bernhardt, P. V., Harrowfield, J. M., Kim, Y., Koutsantonis, G. A., Lee, Y. H. and Thuery, P. (2004). Functionalized macrocycles from functionalized tetra-amines: Pendent-arm macrocycles derived from dichloropivalic acid. Inorganic Chemistry, 43 (5), 1681-1688. doi: 10.1021/ic034913g

Imidoylketene dimerization and rearrangement

George, L., Bernhardt, P. V., Netsch, K. P. and Wentrup, C. (2004). Imidoylketene dimerization and rearrangement. Organic & Biomolecular Chemistry, 2 (23), 3518-3523. doi: 10.1039/b412530d

Iron catalysed assembly of an asymmetric mixed-ligand triple helicate

Bernhardt, Paul V., Chin, Piao and Richardson, Des R. (2004). Iron catalysed assembly of an asymmetric mixed-ligand triple helicate. Dalton Transactions, 2004 (20), 3342-3346. doi: 10.1039/b408781j

Novel one-dimensional structures and solution behaviour of copper(II) bromide and chloride complexes of a new pentapyridyldiamine ligand

Lonnon, David G., Craig, Donald C., Colbran, Stephen B. and Bernhardt, Paul V. (2004). Novel one-dimensional structures and solution behaviour of copper(II) bromide and chloride complexes of a new pentapyridyldiamine ligand. Dalton Transactions, 2004 (5), 778-787. doi: 10.1039/b315202b

Oxidation of mixed-valence CoIII/FeII complexes reversed at high pH: A kinetico-mechanistic study of water oxidation

Bernhardt, P. V., Bozoglian, F., Macpherson, B. P., Martinez, M., Merbach, A. E., Gonzalez, G. and Sienra, B. (2004). Oxidation of mixed-valence CoIII/FeII complexes reversed at high pH: A kinetico-mechanistic study of water oxidation. Inorganic Chemistry, 43 (22), 7187-7195. doi: 10.1021/ic0493191

Self-assembly of a charge-neutral molecular square

Ali, M. A., Bernhardt, P. V., Kiem, C. L. and Mirza, A. H. (2004). Self-assembly of a charge-neutral molecular square. Australian Journal of Chemistry, 57 (5), 409-413. doi: 10.1071/CH03319

Stereocontrol in complexes of cyclam-like macrocycles - influences of chirality

Bernhardt, P. V., Dyahningtyas, T. E., Han, S. C., Harrowfield, J. M., Kim, I. C., Kim, Y., Koutsantonis, G. A., Rukmini, E. and Thuery, P. (2004). Stereocontrol in complexes of cyclam-like macrocycles - influences of chirality. Polyhedron, 23 (5), 869-877. doi: 10.1016/j.poly.2003.12.014

Synthesis of 1,3-diazepines and ring contraction to cyanopyrroles

Reisinger, Ales, Bernhardt, Paul V. and Wentrup, Curt (2004). Synthesis of 1,3-diazepines and ring contraction to cyanopyrroles. Organic & Biomolecular Chemistry, 2 (2), 246-256. doi: 10.1039/b311247k

Synthetic, spectroscopic and X-ray crystallographic structural study of the monomeric [Cu(pysme)(sac)(MeOH)] and dimeric [Cu(6mptsc)(sac)](2) complexes [pysme = anion of the pyridine-2-carboxaldehyde Schiff base of S-methyldithiocarbazate, 6mptsc=the anio

Ali, M. A., Mirza, A. H., Ravoof, T. B. S. A. and Bernhardt, P. V. (2004). Synthetic, spectroscopic and X-ray crystallographic structural study of the monomeric [Cu(pysme)(sac)(MeOH)] and dimeric [Cu(6mptsc)(sac)](2) complexes [pysme = anion of the pyridine-2-carboxaldehyde Schiff base of S-methyldithiocarbazate, 6mptsc=the anio. Polyhedron, 23 (11), 2031-2036. doi: 10.1016/j.poly.2004.05.007

The critical role of tryptophan-116 in the catalytic cycle of dimethylsulfoxide reductase from Rhodobacter capsulatus

Ridge, J. P., Aguey-Zinsou, K. F., Bernhardt, P. V., Hanson, G. R. and McEwan, A. G. (2004). The critical role of tryptophan-116 in the catalytic cycle of dimethylsulfoxide reductase from Rhodobacter capsulatus. FEBS Letters, 563 (1-3), 197-202. doi: 10.1016/S0014-5793(04)00301-1

The preparation and characterization of seven-coordinate tin(IV) complexes of the 2,6-diacetylpyridine Schiff bases of S-alkyl/aryl-dithiocarbazates and the X-ray crystal structure of the [Sn(dapsme)I-2] complex (dapsme=doubly deprotonated form of the 2,6

Ali, M. A., Mirza, A. H., Tan, A. L., Wei, L. K. and Bernhardt, P. V. (2004). The preparation and characterization of seven-coordinate tin(IV) complexes of the 2,6-diacetylpyridine Schiff bases of S-alkyl/aryl-dithiocarbazates and the X-ray crystal structure of the [Sn(dapsme)I-2] complex (dapsme=doubly deprotonated form of the 2,6. Polyhedron, 23 (11), 2037-2043. doi: 10.1016/j.poly.2004.05.010

The preparation and characterization of tin(IV) complexes of 2-quinolinecarboxaldehyde Schiff bases of S-methyl- and S-benzyldithiocarbazates and the X-ray crystal and molecular structures of the 2-quinolinecarboxaldehyde Schiff base of S-benzyldithi

Ali, M. A., Mirza, A., Hamid, M. H. S. A., Bujang, F. and Bernhardt, P. V. (2004). The preparation and characterization of tin(IV) complexes of 2-quinolinecarboxaldehyde Schiff bases of S-methyl- and S-benzyldithiocarbazates and the X-ray crystal and molecular structures of the 2-quinolinecarboxaldehyde Schiff base of S-benzyldithi. Polyhedron, 23 (15), 2405-2412. doi: 10.1016/j.poly.2004.07.015

The reaction of 8-amino-p-menthene derivatives with electrophiles

Bernhardt, P. V., Carman, R. M. and Derbyshire, R. P. C. (2004). The reaction of 8-amino-p-menthene derivatives with electrophiles. Australian Journal of Chemistry, 57 (6), 583-591. doi: 10.1071/CH03158

Tuning the metal-to-metal charge transfer energy of cyano-bridged dinuclear complexes

Bernhardt, Paul V., Bozoglian, Fernando, Macpherson, Brendan P. and Martinez, Manuel (2004). Tuning the metal-to-metal charge transfer energy of cyano-bridged dinuclear complexes. Dalton Transactions (16), 2582-2587. doi: 10.1039/b407185a

Unprecedented photochemical induced cascading rearrangement of the 3-azabicyclo[3.3.1] nonane skeleton

Williams, Craig M., Heim, Ralf, Brecknell, Douglas J. and Bernhardt, Paul V. (2004). Unprecedented photochemical induced cascading rearrangement of the 3-azabicyclo[3.3.1] nonane skeleton. Organic and Biomolecular Chemistry, 2 (6), 806-807. doi: 10.1039/b402200a

trans-Cyano(6-methyl-1,4,8,11-tetraazacyclotetradecan-6-amine)cobalt(III) bis(perchlorate) hydrate and trans-hydroxo(6-methyl-1,4,8,11-tetraazacyclotetradecan-6-amine)cobalt(III) bis(perchlorate)

Bernhardt, Paul V. and Macpherson, Brendan P. (2003). trans-Cyano(6-methyl-1,4,8,11-tetraazacyclotetradecan-6-amine)cobalt(III) bis(perchlorate) hydrate and trans-hydroxo(6-methyl-1,4,8,11-tetraazacyclotetradecan-6-amine)cobalt(III) bis(perchlorate). Acta Crystallographica Section C-crystal Structure Communications, 59 (12), M533-M536. doi: 10.1107/S0108270103023370

The preparation of zinc(II) and cadmium(II) complexes of the pentadentate N3S2 ligand formed from 2,6-diacetylpyridine and S-benzyldithiocarbazate (H2SNNNS) and the X-ray crystal structure of the novel dimeric [Zn2(SNNNS)2] complex

Ali, M. A., Mirza, A. H., Voo, C. W., Tan, A. L. and Bernhardt, P. V. (2003). The preparation of zinc(II) and cadmium(II) complexes of the pentadentate N3S2 ligand formed from 2,6-diacetylpyridine and S-benzyldithiocarbazate (H2SNNNS) and the X-ray crystal structure of the novel dimeric [Zn2(SNNNS)2] complex. Polyhedron, 22 (27), 3433-3438. doi: 10.1016/j.poly.2003.08.004

The synthesis and X-ray crystal structure of 9-carboxyhexahydro-7-methoxy-4a,7-ethano-benzopyran-5-en-1-one

Williams, C. M., Bernhardt, P. V., Wiedemann, S. and Barden, M. C. (2003). The synthesis and X-ray crystal structure of 9-carboxyhexahydro-7-methoxy-4a,7-ethano-benzopyran-5-en-1-one. Journal of Chemical Research (S), 12 (12), 784-785. doi: 10.3184/030823403322840387

Cytotoxic iron chelators: Characterization of the structure, solution chemistry and redox activity of ligands and iron complexes of the di-2-pyridyl ketone isonicotinoyl hydrazone (HPKIH) analogues

Bernhardt, P. V., Caldwell, L. M., Chaston, T. B., Chin, P. and Richardson, D. R. (2003). Cytotoxic iron chelators: Characterization of the structure, solution chemistry and redox activity of ligands and iron complexes of the di-2-pyridyl ketone isonicotinoyl hydrazone (HPKIH) analogues. Journal of Biological Inorganic Chemistry, 8 (8), 866-880. doi: 10.1007/s00775-003-0486-z

Four cytotoxic N4-substituted thiosemicarbazones derived from 2-hydroxynaphthalene-1-carboxaldehyde

Bernhardt, P. V., Caldwell, L., Lovejoy, D. and Richardson, D. R. (2003). Four cytotoxic N4-substituted thiosemicarbazones derived from 2-hydroxynaphthalene-1-carboxaldehyde. Acta Crystallographica Section C: Crystal Structure Communications, 59 (11), o629-o633. doi: 10.1107/S0108270103021401

Geometric isomers of chloro(6-methyl-1,4,8,11-tetraazacyclotetradecane-6-amine)cobalt(III) tetrachlorozincate(II)

Bernhardt, P. V. and Macpherson, B. P. (2003). Geometric isomers of chloro(6-methyl-1,4,8,11-tetraazacyclotetradecane-6-amine)cobalt(III) tetrachlorozincate(II). Acta crystallographica. Section C, Crystal structure communications, 59 (Part 11), m467-m470. doi: 10.1107/S0108270103021711

Synthesis and characterization of mono- and bis-ligand zinc(II) and cadmium(II) complexes of the di-2-pyridylketone Schiff base of S-benzyl dithiocarbazate (Hdpksbz) and the X-ray crystal structures of the [Zn(dpksbz)2] and [Cd(dpksbz)NCS]2 complexes

Ali, M. A., Mirza, A. H., Nazimuddin, M., Ahmed, R., Gahan, L. R. and Bernhardt, P. V. (2003). Synthesis and characterization of mono- and bis-ligand zinc(II) and cadmium(II) complexes of the di-2-pyridylketone Schiff base of S-benzyl dithiocarbazate (Hdpksbz) and the X-ray crystal structures of the [Zn(dpksbz)2] and [Cd(dpksbz)NCS]2 complexes. Polyhedron, 22 (11), 1471-1479. doi: 10.1016/S0277-5387(03)00125-6

1-Ethynyl-2-isopropoxy-3-methoxybenzene

Williams, Craig M., Mander, Lewis N. and Bernhardt, Paul V. (2003). 1-Ethynyl-2-isopropoxy-3-methoxybenzene. Acta Crystallographica Section E, 59 (4), 0561-0563. doi: 10.1107/S1600536803006585

Structural variations and formation constants of first-row transition metal complexes of biologically active aroylhydrazones

Armstrong, C. M., Bernhardt, P. V., Chin, P. and Richardson, D. R. (2003). Structural variations and formation constants of first-row transition metal complexes of biologically active aroylhydrazones. European Journal of Inorganic Chemistry, 2003 (6), 1145-1156. doi: 10.1002/ejic.200390146

Redox active macrocyclic receptors for neutral guests

Bernhardt, Paul V. and Hayes, Elizabeth J. (2003). Redox active macrocyclic receptors for neutral guests. Inorganic Chemistry, 42 (4), 1371-1377. doi: 10.1021/ic026000c

Bioelectricity: electrocatalysis and beyond

Bernhardt, P. V. (2003). Bioelectricity: electrocatalysis and beyond. Chemistry in Australia, 70 (4), 13-16.

Chiral resolution of hexaamine cobalt(III) cages: Substituent effects on chiral discrimination

Bernhardt, P. V., Dyahningtyas, T. E., Harrowfield, J. M., Kim, J. Y., Kim, Y. and Rukmini, E. (2003). Chiral resolution of hexaamine cobalt(III) cages: Substituent effects on chiral discrimination. Australian Journal of Chemistry, 56 (12), 1187-1191. doi: 10.1071/CH03160

Direct electrochemistry of a bacterial sulfite dehydrogenase

Aguey-Zinsou, Kondo-Francois, Bernhardt, Paul. V., Kappler, Ulrike and McEwan, Alastair G. (2003). Direct electrochemistry of a bacterial sulfite dehydrogenase. Journal of The American Chemical Society, 125 (2), 530-535. doi: 10.1021/ja028293e

Discrete cyanide-bridged mixed-valence Co/Fe complexes: Outer-sphere redox behaviour

Bernhardt, P. V., Bozoglian, F., Macpherson, B. P., Martinez, M., Gonzalez, G. and Sienra, B. (2003). Discrete cyanide-bridged mixed-valence Co/Fe complexes: Outer-sphere redox behaviour. European Journal of Inorganic Chemistry, 2003 (13), 2512-2518. doi: 10.1002/ejic.200200626

Electrochemistry of P450cin: new insights into P450 electron transfer

Aguey-Zinsou, Kondo-François, Bernhardt, Paul V., De Voss, James J. and Slessor, Kate E. (2003). Electrochemistry of P450cin: new insights into P450 electron transfer. Chemical Communications, 3 (3), 418-419. doi: 10.1039/b211567k

Functionalized macrocyclic compounds: potential sensors of small molecules and ions

Bernhardt, P. V. and Moore, E. G. (2003). Functionalized macrocyclic compounds: potential sensors of small molecules and ions. Australian Journal of Chemistry, 56 (4), 239-258. doi: 10.1071/CH02225

Isomers of 1,4,8,11-tetraazacyclotetradecane-6,13-dicarboxylate characterized as cobalt(III) complexes

Bernhardt, P. V., Hambley, T. W., Lawrance, G. A., Maeder, M. and Wilkes, E. N. (2003). Isomers of 1,4,8,11-tetraazacyclotetradecane-6,13-dicarboxylate characterized as cobalt(III) complexes. Australian Journal of Chemistry, 56 (7), 679-684. doi: 10.1071/CH02246

N-aminopyrroledione-hydrazonoketene-pyrazolium oxide-pyrazolone rearrangements and pyrazolone tautomerism

Ebner, S., Wallfisch, B., Andraos, J., Aitbaev, I., Kiselewsky, M., Bernhardt, P. V., Kollenz, G. and Wentrup, C. (2003). N-aminopyrroledione-hydrazonoketene-pyrazolium oxide-pyrazolone rearrangements and pyrazolone tautomerism. Organic & Biomolecular Chemistry, 1 (14), 2550-2555. doi: 10.1039/b304070d

Protein film voltammetry of Rhodobacter capsulatus xanthine dehydrogenase

Aguey-Zinsou, Kondo François, Bernhardt, Paul V. and Leimkuhler, Silke (2003). Protein film voltammetry of Rhodobacter capsulatus xanthine dehydrogenase. Journal of The American Chemical Society, 125 (50), 15352-15358. doi: 10.1021/ja037940e

Rates of electronic energy transfer in conformationally flexible bichromophoric macrocyclic complexes: a combined experimental and molecular modeling study

Moore, E. G., Bernhardt, P. V., Pigliucci, A., Riley, M. J. and Vauthey, E. (2003). Rates of electronic energy transfer in conformationally flexible bichromophoric macrocyclic complexes: a combined experimental and molecular modeling study. Journal of Physical Chemistry A, 107 (41), 8396-8403. doi: 10.1021/jp035781f

Structural definition of the low-temperature phase transition of tris(ethane-1,2-diamine)zinc(II) dinitrate

Bernhardt, P. V. and Riley, M. J. (2003). Structural definition of the low-temperature phase transition of tris(ethane-1,2-diamine)zinc(II) dinitrate. Australian Journal of Chemistry, 56 (4), 287-291. doi: 10.1071/CH03023

The synthesis and X-ray crystal structure of 6-bromo-2,4,4-trimethyl-cyclohex-2-enone

Williams, C. M. and Bernhardt, P. V. (2003). The synthesis and X-ray crystal structure of 6-bromo-2,4,4-trimethyl-cyclohex-2-enone. Journal of Chemical Research-s, 2003 (7), 410-411. doi: 10.3184/030823403103174326

The first non-turnover voltammetric response from a molybdenum enzyme: direct electroscopy of dimethylsulfoxide reductase from Rhodobacter capsulatus

Aguey, F. K., Bernhardt, P. V., McEwan, A. G. and Ridge, J. P. (2002). The first non-turnover voltammetric response from a molybdenum enzyme: direct electroscopy of dimethylsulfoxide reductase from Rhodobacter capsulatus. Journal of Biological Inorganic Chemistry, 7 (7-8), 879-883. doi: 10.1007/s00775-002-0374-y

An XPS study of an isomorphous trivalent lanthanoid series

Bernhardt, P. V., Flanagan, B. M., Riley, M. J. and Wood, B. J. (2002). An XPS study of an isomorphous trivalent lanthanoid series. Journal of Electron Spectroscopy And Related Phenomena, 124 (1), 73-77. doi: 10.1016/S0368-2048(02)00011-7

Bis(diethylenetriamine)mercury(II) bis(thiocyanate)

Tran, M. Linh, Bernhardt, Paul V. and Gentle, Ian R. (2002). Bis(diethylenetriamine)mercury(II) bis(thiocyanate). Acta Crystallographica Section E, E58 (4), M150-M151. doi: 10.1107/S1600536802004701

1-(Phenylethynyl)adamantane

Raine, A. L., Williams, C. M. and Bernhardt, P. V. (2002). 1-(Phenylethynyl)adamantane. Acta Crystallographica Section E - Structure Reports, E58 (12), 1439-1440. doi: 10.1107/S1600536802021542

A ligand-field analysis of the trensal (H3trensal = 2,2',2' '-tris(salicylideneimino)triethylamine) Ligand. An application of the angular overlap model to lanthanides

Flanagan, Bernadine M., Bernhardt, Paul V., Krause, Elmars R., Lüthi, Stefan R. and Riley, Mark J. (2002). A ligand-field analysis of the trensal (H3trensal = 2,2',2' '-tris(salicylideneimino)triethylamine) Ligand. An application of the angular overlap model to lanthanides. Inorganic Chemistry, 41 (20), 5024-5033. doi: 10.1021/ic011276q

Chemistry of stable iminopropadienones, RN=C=C=C=O

Bibas, H., Moloney, D. W. J., Neumann, R., Shtaiwi, M., Bernhardt, P. V. and Wentrup, C. (2002). Chemistry of stable iminopropadienones, RN=C=C=C=O. Journal of Organic Chemistry, 67 (8), 2619-2631. doi: 10.1021/jo0110552

Crown ether appended cyclam receptors for cationic guests

Bernhardt, P. V. and Hayes, E. J. (2002). Crown ether appended cyclam receptors for cationic guests. Inorganic Chemistry, 41 (11), 2892-2902. doi: 10.1021/ic011232h

Intramolecular electronic energy transfer in bichromophoric macrocyclic complexes

Bernhardt, P. V., Moore, E. G. and Riley, M. J. (2002). Intramolecular electronic energy transfer in bichromophoric macrocyclic complexes. Inorganic Chemistry, 41 (11), 3025-3031. doi: 10.1021/ic0255306

Site-Directed Mutagenesis of Dimethyl Sulfoxide Reductase from Rhodobacter capsulatus: Characterization of a Y114 → F Mutant

Ridge, Justin P., Aguey, Kondo-Francois, Bernhardt, Paul V., Brereton, Ian M., Hanson, Graeme R. and McEwan, Alastair G. (2002). Site-Directed Mutagenesis of Dimethyl Sulfoxide Reductase from Rhodobacter capsulatus: Characterization of a Y114 → F Mutant. Biochemistry, 41 (52), 15762-15769. doi: 10.1021/bi0266582

Substitution reactions on cyclometalated Pt(IV) complexes. Associative tuning by fluoro Ligands and fluorinated substituents

Bernhardt, P. V., Gallego, C., Martinez, M. and Parella, T. (2002). Substitution reactions on cyclometalated Pt(IV) complexes. Associative tuning by fluoro Ligands and fluorinated substituents. Inorganic Chemistry, 41 (7), 1747-1754. doi: 10.1021/ic0108179

Synthesis and structural properties of patellamide a derivatives and their copper(II) compounds

Bernhardt, P. V., Comba, P., Fairlie, D. P., Gahan, L. R., Hanson, G. R. and Lotzbeyer, L. (2002). Synthesis and structural properties of patellamide a derivatives and their copper(II) compounds. Chemistry-a European Journal, 8 (7), 1527-1536. doi: 10.1002/1521-3765(20020402)8:7<1527::AID-CHEM1527>3.3.CO;2-6

The influence of cis/trans isomerism on the physical properties of a cyano-bridged dinuclear mixed valence complex

Bernhardt, Paul V., Macpherson, Brendan P. and Martinez, Manuel (2002). The influence of cis/trans isomerism on the physical properties of a cyano-bridged dinuclear mixed valence complex. Journal of the Chemical Society - Dalton Transactions, 7 (7), 1435-1441. doi: 10.1039/b110461f

Twisting and planarization in push-pull ethylenes

Bernhardt, Paul V., Koch, Rainer, Moloney, Daniel W. J., Shtaiwi, Majed H. and Wentrup, Curt (2002). Twisting and planarization in push-pull ethylenes. Journal of the Chemical Society- Perkin Transactions 2, 3 (3), 515-523. doi: 10.1039/b109624a

Photoinduced electron transfer and electronic energy transfer in naphthyl-appended cyclams

Bernhardt, Paul V., Moore, Evan G. and Riley, Mark J. (2001). Photoinduced electron transfer and electronic energy transfer in naphthyl-appended cyclams. Inorganic Chemistry, 40 (23), 5799-5805. doi: 10.1021/ic0102586

A ferrocene functionalised macrocyclic receptor for cations and anions

Beer, P. D. and Bernhardt, P. V. (2001). A ferrocene functionalised macrocyclic receptor for cations and anions. Journal Chemical Society, Dalton Transactions (9), 1428-1431. doi: 10.1039/b100439p

Completion of the isomorphous Ln(trensal) series

Bernhardt, P. V., Flanagan, B. M. and Riley, M. J. (2001). Completion of the isomorphous Ln(trensal) series. Australian Journal of Chemistry, 54 (4), 229-232. doi: 10.1071/CH01076

Diverse solid-state and solution structures within a series of hexaamine dicopper(II) complexes

Bernhardt, P. V. (2001). Diverse solid-state and solution structures within a series of hexaamine dicopper(II) complexes. Inorganic Chemistry, 40 (6), 1086-1092. doi: 10.1021/ic000928s

Ligand-field analysis of an Er(III) complex with a heptadentate tripodal N4O3 ligand

Flanagan, B. M., Bernhardt, P. V., Krausz, E. R., Luthi, S. R. and Riley, M. J. (2001). Ligand-field analysis of an Er(III) complex with a heptadentate tripodal N4O3 ligand. Inorganic Chemistry, 40 (21), 5401-5407. doi: 10.1021/ic0103244

Unprecedented oxidation of a biologically active aroylhydrazone chelator catalysed by iron(III): serendipitous identification of diacylhydrazine ligands with high iron chelation efficacy

Bernhardt, P. V., Chin, P. and Richardson, D. R. (2001). Unprecedented oxidation of a biologically active aroylhydrazone chelator catalysed by iron(III): serendipitous identification of diacylhydrazine ligands with high iron chelation efficacy. Journal of Biological Inorganic Chemistry, 6 (8), 801-809. doi: 10.1007/s007750100258

Halogenated terpenoids. XXXII: Pentabromides from limonene - Two 1,2,8,9,9-pentabromo-p-menthanes

Bernhardt, Paul V., Carman, Raymond M. and Ross, Benjamin P. (2000). Halogenated terpenoids. XXXII: Pentabromides from limonene - Two 1,2,8,9,9-pentabromo-p-menthanes. Australian Journal of Chemistry, 53 (7), 611-614.

2-hydroxy-1-naphthaldehyde 2-methylthiosemicarbazone

Lovejoy, D. B., Richardson, D. R. and Bernhardt, P. V. (2000). 2-hydroxy-1-naphthaldehyde 2-methylthiosemicarbazone. Acta Crystallographica, Section C: Crystal Structure Communications, 56

'Tetol': a stereo-rigid four-strand motif for alkali and alkaline earth metal ion coordination

Bernhardt, P. V., Lawrance, G., Luther, S. M., Maeder, M., Robertson, M. J. and Sutrisno, N. G. (2000). 'Tetol': a stereo-rigid four-strand motif for alkali and alkaline earth metal ion coordination. Inorganic Chemistry Communications, 3 (8), 410-414. doi: 10.1016/S1387-7003(00)00107-6

2-hydroxy-1-naphthaldehyde 2-methylthiosemicarbazone

Lovejoy, DB, Richardson, DR and Bernhardt, PV (2000). 2-hydroxy-1-naphthaldehyde 2-methylthiosemicarbazone. ACTA Crystallographica Section C-Crystal Structure Communications, 56 (Pt3), 341-342. doi: 10.1107/S0108270199015140

C-substituted macrocycles as candidates for radioimmunotherapy

Bernhardt, PV and Sharpe, PC (2000). C-substituted macrocycles as candidates for radioimmunotherapy. Inorganic Chemistry, 39 (18), 4123-4129. doi: 10.1021/ic000315f

Discrete dinuclear cyano-bridged complexes

Bernhardt, PV, Macpherson, BP and Martinez, M (2000). Discrete dinuclear cyano-bridged complexes. Inorganic Chemistry, 39 (23), 5203-5208. doi: 10.1021/ic000379q

Halogenated terpenoids. XXXII - Pentabromides from limonene two 1,2,8,9,9-pentabromo-p-menthanes

Bernhardt, PV, Carman, RM and Ross, BP (2000). Halogenated terpenoids. XXXII - Pentabromides from limonene two 1,2,8,9,9-pentabromo-p-menthanes. Australian Journal of Chemistry, 53 (7), 611-614. doi: 10.1071/CH00022

Isomorphous Ianthanide complexes of a Tripodal N4O3 Ligand

Bernhardt, P. V., Flanagan, B. and Riley, M. J. (2000). Isomorphous Ianthanide complexes of a Tripodal N4O3 Ligand. Australian Journal of Chemistry, 53 (3), 229-231. doi: 10.1071/CH99175

Mechanisms of substitution reactions on cyclometallated platinum(IV) complexes: "Quasi-labile" systems

Bernhardt, P. V., Gallego, C. and Martinez, M. (2000). Mechanisms of substitution reactions on cyclometallated platinum(IV) complexes: "Quasi-labile" systems. Organometallics, 19 (23), 4862-4869. doi: 10.1021/om000505y

Mesoionic pyridopyrimidinylium and pyridooxazinylium olates and non-mesoionic pyridopyrimidinones. Structures in the solid state, solution, and matrices

Plug, C., Wallfisch, B., Andersen, H. G., Bernhardt, P. V., Baker, L. J., Clark, G. R., Wong, M. W. and Wentrup, C. (2000). Mesoionic pyridopyrimidinylium and pyridooxazinylium olates and non-mesoionic pyridopyrimidinones. Structures in the solid state, solution, and matrices. Journal of The Chemical Society-perkin Transactions 2 (10), 2096-2108. doi: 10.1039/b003933k

Mesoionic pyridopyrimidinylium and pyrisooxazinylium olates and non-mesoionic pyridopyrimidinones. Structures in the solid state, solution and matrices

Plug, C., Wallfisch, B., Andersen, H. G., Bernhardt, P. V., Baker, L., Clark, G. R., Wong, M. W. and Wentrup, C. (2000). Mesoionic pyridopyrimidinylium and pyrisooxazinylium olates and non-mesoionic pyridopyrimidinones. Structures in the solid state, solution and matrices. Perkin Transactions II (2), 2096-2108.

Metal-directed synthesis routes to a 16-membered tetraazamacrocycle with two pendant primary amine groups

Bernhardt, P. V., Lawrance, G. A., Luther, S., Maeder, M. and Rossignoli, M. (2000). Metal-directed synthesis routes to a 16-membered tetraazamacrocycle with two pendant primary amine groups. Inorganica Chimica Acta, 306 (1), 1-5. doi: 10.1016/S0020-1693(00)00133-X

Ni-II and Zn-II complexes of the hexadentate macrocyclic ligand cis-6,13-dimethyl-1,4,8,11-tetraazacyclotetra- decane-6,13-diamine

Bernhardt, PV (2000). Ni-II and Zn-II complexes of the hexadentate macrocyclic ligand cis-6,13-dimethyl-1,4,8,11-tetraazacyclotetra- decane-6,13-diamine. Acta Crystallographica Section C-crystal Structure Communications, 56 (7), 744-746. doi: 10.1107/S0108270100003930

Self-assembly of a noncovalently bonded Dicopper(II) complex in the solid state and in solution

Bernhardt, PV and Sharpe, PC (2000). Self-assembly of a noncovalently bonded Dicopper(II) complex in the solid state and in solution. Inorganic Chemistry, 39 (22), 4994-4995. doi: 10.1021/ic000587i

Structurally reinforced tetraazamacrocyclic complexes

Bernhardt, PV and Sharpe, PC (2000). Structurally reinforced tetraazamacrocyclic complexes. Inorganic Chemistry, 39 (10), 2020-2025. doi: 10.1021/ic9906353

Synthesis and complexes of the sexidentate macrocycle 15-methyl-1,4,7,10,13-pentaazacyclohexadecan-15-amine

Bernhardt, PV, Lawrance, GA, Napitupulu, M and Wei, G (2000). Synthesis and complexes of the sexidentate macrocycle 15-methyl-1,4,7,10,13-pentaazacyclohexadecan-15-amine. Inorganica Chimica Acta, 300, 604-612. doi: 10.1016/S0020-1693(00)00022-0

The Ni-II, Hg-II and Cu-II complexes of 12-membered-ring mixed-donor macrocycles

Marcus, Sebastian T., Gahan, Lawrence R. and Bernhardt, Paul V. (2000). The Ni-II, Hg-II and Cu-II complexes of 12-membered-ring mixed-donor macrocycles. Acta Crystallographica Section C-crystal Structure Communications, 56 (6), 655-658. doi: 10.1107/S0108270100003942

The biologically active iron chelators 2-pyridylcarboxaldehyde isonicotinoylhydrazone, 2-pyridylcarboxaldehyde benzoylhydrazone monohydrate and 2-furaldehyde isonicotinoylhydrazone

Richardson, D. R., Becker, E. and Bernhardt, P. V. (1999). The biologically active iron chelators 2-pyridylcarboxaldehyde isonicotinoylhydrazone, 2-pyridylcarboxaldehyde benzoylhydrazone monohydrate and 2-furaldehyde isonicotinoylhydrazone. Acta Crystallographica, Section C: Crystal Structure Communications, 55

Complexes of 1-thia-4,7,10-triazacyclododecane ([12]aneN3S): Synthesis, structure and stability constants

Marcus S.T., Bernhardt P.V., Grondahl L. and Gahan L.R. (1999). Complexes of 1-thia-4,7,10-triazacyclododecane ([12]aneN3S): Synthesis, structure and stability constants. Polyhedron, 18 (26), 3451-3460.

The first structurally characterized discrete dinuclear mu-cyano hexacyanoferrate complex

Bernhardt, Paul V. and Martinez, Manuel (1999). The first structurally characterized discrete dinuclear mu-cyano hexacyanoferrate complex. Inorganic Chemistry, 38 (3), 424-425. doi: 10.1021/ic981019u

A supramolecular synthon for H-bonded transition metal arrays

Bernhardt, PV (1999). A supramolecular synthon for H-bonded transition metal arrays. Inorganic Chemistry, 38 (15), 3481-3483. doi: 10.1021/ic990074f

Complexes of 1-thia-4,7,10-triazacyclododecane ([12]aneN(3)S) - Synthesis, structure and stability constants

Marcus, S., Bernhardt, P. V., Grondahl, L. and Gahan, L. R. (1999). Complexes of 1-thia-4,7,10-triazacyclododecane ([12]aneN(3)S) - Synthesis, structure and stability constants. Polyhedron, 18 (26), 3451-3460. doi: 10.1016/S0277-5387(99)00254-5

Crystal and molecular structure of 2-hydroxy-1-naphthaldehyde isonicotinoyl hydrazone (NIH) and its iron(III) complex: an iron chelator with anti-tumour activity

Richardson, D. R. and Bernhardt, P. V. (1999). Crystal and molecular structure of 2-hydroxy-1-naphthaldehyde isonicotinoyl hydrazone (NIH) and its iron(III) complex: an iron chelator with anti-tumour activity. Journal of Biological Inorganic Chemistry, 4 (3), 266-273. doi: 10.1007/s007750050312

Electrochemistry of macrocyclic cobalt(III/II) hexaamines: Electrocatalytic hydrogen evolution in aqueous solution

Bernhardt, P. V. and Jones, L. A. (1999). Electrochemistry of macrocyclic cobalt(III/II) hexaamines: Electrocatalytic hydrogen evolution in aqueous solution. Inorganic Chemistry, 38 (22), 5086-5090. doi: 10.1021/ic981425d

Metal-centred versus ligand-centred luminescence quenching of a macrocyclic copper(II) complex

Bernhardt, P. V., Flanagan, B. M. and Riley, M. J. (1999). Metal-centred versus ligand-centred luminescence quenching of a macrocyclic copper(II) complex. Journal of The Chemical Society- Dalton Transactions (20), 3579-3584. doi: 10.1039/a902881a

Nickel complexes with tris(2-aminoethyl)amine (tren): [Ni-3(tren)(4)(H2O)(2)][Cr(ox)(3)](2)center dot 6H(2)O (ox = oxalate), {[Ni-2(tren)(3)][ClO4](4)center dot H2O}(n), and [Ni-2(tren)(2)(aepd)][ClO4](4)center dot 2H(2)O (aepd = N-(2-aminoethyl)pyrrolidi

Masters, V. M., Bernhardt, P. V., Gahan, L. R., Moubaraki, B., Murray, K. S. and Berry, K. J. (1999). Nickel complexes with tris(2-aminoethyl)amine (tren): [Ni-3(tren)(4)(H2O)(2)][Cr(ox)(3)](2)center dot 6H(2)O (ox = oxalate), {[Ni-2(tren)(3)][ClO4](4)center dot H2O}(n), and [Ni-2(tren)(2)(aepd)][ClO4](4)center dot 2H(2)O (aepd = N-(2-aminoethyl)pyrrolidi. Journal Chemical Society, Dalton Transactions (14), 2323-2328. doi: 10.1039/a901659g

The biologically active iron chelators 2-pyridylcarboxaldehyde isonicotinoylhydrazone, 2-pyridylcarboxaldehyde benzoylhydrazone monohydrate and 2-furaldehyde isonicotinoylhydrazone

Richardson, D. R., Becker, E. and Bernhardt, P. V. (1999). The biologically active iron chelators 2-pyridylcarboxaldehyde isonicotinoylhydrazone, 2-pyridylcarboxaldehyde benzoylhydrazone monohydrate and 2-furaldehyde isonicotinoylhydrazone. Acta Crystallographica Section C-crystal Structure Communications, 55 (12), 2102-2105. doi: 10.1107/S0108270199011531

The biologically active iron chelators 2-pyridylcarboxaldehyde isonicotinoylhydrozone, 2-pyridylcarboxaldehyde benzoylhydrazone monohydrate and 2-furaldehyde isonicotinoylhydrazone

Richardson, D. R., Becker, E. and Bernhardt, P. V. (1999). The biologically active iron chelators 2-pyridylcarboxaldehyde isonicotinoylhydrozone, 2-pyridylcarboxaldehyde benzoylhydrazone monohydrate and 2-furaldehyde isonicotinoylhydrazone. Acta Crystallographica Section C - Crystal Structure Communications, 15 (55 (Pt12)), 2102-2105. doi: 10.1111/rp10.1107-S0108270199010094

Variable temperature and pressure study of the aquation reactions of cobalt(III) and chromium(III) penta- and tetra-amines

Benzo, F, Bernhardt, PV, Gonzalez, G, Martinez, M and Sienra, B (1999). Variable temperature and pressure study of the aquation reactions of cobalt(III) and chromium(III) penta- and tetra-amines. Journal of The Chemical Society-dalton Transactions (22), 3973-3979. doi: 10.1039/a907895i

A novel tricopper(II) complex of a polyamine alcohol

Bernhardt, PV and Sharpe, PC (1998). A novel tricopper(II) complex of a polyamine alcohol. Journal of The Chemical Society-dalton Transactions (7), 1087-1088. doi: 10.1039/a800297e

Aminotriazines as locking fragments in macrocyclic synthesis

Bernhardt, PV and Hayes, EJ (1998). Aminotriazines as locking fragments in macrocyclic synthesis. Inorganic Chemistry, 37 (17), 4214-4219. doi: 10.1021/ic980243g

Copper(II) complexes of mono- and di-nucleating hexaamines

Bernhardt, PV and Hayes, EJ (1998). Copper(II) complexes of mono- and di-nucleating hexaamines. Journal of The Chemical Society-dalton Transactions (6), 1037-1042. doi: 10.1039/a707209k

Derivatives of 1,3,5-triamino-1,3,5-trideoxy-cis-inositas versatile pentadentate ligands for protein labeling with Re-186/188. Prelabeling, biodistribution, and X-ray structural studies

Kramer, A, Alberto, R, Egli, A, Novak-Hofer, I, Hegetschweiler, K, Abram, U, Bernhardt, PV and Schubiger, PA (1998). Derivatives of 1,3,5-triamino-1,3,5-trideoxy-cis-inositas versatile pentadentate ligands for protein labeling with Re-186/188. Prelabeling, biodistribution, and X-ray structural studies. Bioconjugate Chemistry, 9 (6), 691-702. doi: 10.1021/bc980014i

N-mesityl-C-acylketenimines: 1,5-sigmatropic shifts and electrocyclization to quinolines

Rao, VV. R., Fulloon, B. E., Bernhardt, P. V., Koch, R. and Wentrup, C. (1998). N-mesityl-C-acylketenimines: 1,5-sigmatropic shifts and electrocyclization to quinolines. Journal of Organic Chemistry, 63 (17), 5779-5786. doi: 10.1021/jo9722562

N-methylation of macrocyclic hexaaminecobalt(III) complexes

Bernhardt, PV and Jones, LA (1998). N-methylation of macrocyclic hexaaminecobalt(III) complexes. Journal of The Chemical Society-dalton Transactions (11), 1757-1761. doi: 10.1039/a800051d

New stereoselective routes to macrocyclic ligands

Bernhardt, PV and Sharpe, PC (1998). New stereoselective routes to macrocyclic ligands. Inorganic Chemistry, 37 (7), 1629-1636. doi: 10.1021/ic971020d

Synthesis, structure and magnetism of the oxalato-bridged chromium(III) complex [NBu4n](4)[Cr-2(ox)(5)]center dot 2CHCl(3)

Masters, VM, Sharrad, CA, Bernhardt, PV, Gahan, LR, Moubaraki, B and Murray, KS (1998). Synthesis, structure and magnetism of the oxalato-bridged chromium(III) complex [NBu4n](4)[Cr-2(ox)(5)]center dot 2CHCl(3). Journal of The Chemical Society-dalton Transactions (3), 413-416. doi: 10.1039/a705265k

The metal directed assembly of a trinuclear macrocyclic copper(II) complex

Bernhardt, PV and Hayes, EJ (1998). The metal directed assembly of a trinuclear macrocyclic copper(II) complex. Journal of The Chemical Society-dalton Transactions (21), 3539-3541. doi: 10.1039/a806586a

Thermochromism and structure of piperazinium tetrachlorocuprate(II) complexes

Riley, MJ, Neill, D, Bernhardt, PV, Byriel, KA and Kennard, CHL (1998). Thermochromism and structure of piperazinium tetrachlorocuprate(II) complexes. Inorganic Chemistry, 37 (14), 3635-3639. doi: 10.1021/ic971612w

Macrocycle formation through carbon acid-formaldehyde condensation reactions of bis(propane-1,2-diamine)-and bis(2-methylpropane-1,2-diamine)-copper(II) ions

Rossignoli, Monica, Bernhardt, Paul V., Lawrance, Geoffrey A. and Maeder, Marcel (1997). Macrocycle formation through carbon acid-formaldehyde condensation reactions of bis(propane-1,2-diamine)-and bis(2-methylpropane-1,2-diamine)-copper(II) ions. Australian Journal of Chemistry, 50 (6), 527-534.

Gold(III) template synthesis of a pendant-arm macrocycle

Rossignoli, M, Bernhardt, PV, Lawrance, GA and Maeder, M (1997). Gold(III) template synthesis of a pendant-arm macrocycle. Journal of The Chemical Society-dalton Transactions (3), 323-327. doi: 10.1039/a606678j

Macrocycle formation through carbon acid-formaldehyde condensation reactions of bis(propane-1,2-diamine)- and bis (2-methylpropane-1,2-diamine)-copper(II) ions

Rossignoli, M, Bernhardt, PV, Lawrance, GA and Maeder, M (1997). Macrocycle formation through carbon acid-formaldehyde condensation reactions of bis(propane-1,2-diamine)- and bis (2-methylpropane-1,2-diamine)-copper(II) ions. Australian Journal of Chemistry, 50 (6), 529-534. doi: 10.1071/C96219

Molybdenum carbonyl complexes of pendant-arm polyazamacrocycles

Rossignoli, M, Bernhardt, PV and Lawrance, GA (1997). Molybdenum carbonyl complexes of pendant-arm polyazamacrocycles. Journal of The Chemical Society-dalton Transactions (22), 4247-4250. doi: 10.1039/a704343k

Nitrogen- and carbon-based isomerism in the copper(II) complexes of 6,13-dimethyl-1,4,8,11-tetraazacyclotetradecane-6,13-diamine

Bernhardt, PV, Jones, LA and Sharpe, PC (1997). Nitrogen- and carbon-based isomerism in the copper(II) complexes of 6,13-dimethyl-1,4,8,11-tetraazacyclotetradecane-6,13-diamine. Journal of The Chemical Society-dalton Transactions (7), 1169-1175. doi: 10.1039/a606476k

On the structure, electrochemistry, and spectroscopy of the (N,N'-bis(2'-(dimethylamino)ethyl)-N,N'-dimethylpropane-1,3-diamine)copper(II) ion

Bernhardt, PV (1997). On the structure, electrochemistry, and spectroscopy of the (N,N'-bis(2'-(dimethylamino)ethyl)-N,N'-dimethylpropane-1,3-diamine)copper(II) ion. Journal of The American Chemical Society, 119 (4), 771-774. doi: 10.1021/ja961764a

Self-assembly of a tetranuclear macrocyclic copper(II) complex

Bernhardt, PV and Jones, LA (1997). Self-assembly of a tetranuclear macrocyclic copper(II) complex. Chemical Communications (7), 655-656. doi: 10.1039/a700213k

Structural and electron self-exchange rate variations in isomeric (hexaamine)cobalt(III/II) complexes

Bernhardt, PV, Jones, LA and Sharpe, PC (1997). Structural and electron self-exchange rate variations in isomeric (hexaamine)cobalt(III/II) complexes. Inorganic Chemistry, 36 (11), 2420-2425. doi: 10.1021/ic961345e

The potentially hexadentate isomeric macrocycles trans- and cis-6,13-diethyl-1,4,8,11-tetraazacyclotetradecane-6,13-diamine and their cobalt(III) complexes: Unexpected conformational behavior

Bernhardt, P.V., Byriel, K.A., Kennard, C.H.L. and Sharpe, P.C. (1996). The potentially hexadentate isomeric macrocycles trans- and cis-6,13-diethyl-1,4,8,11-tetraazacyclotetradecane-6,13-diamine and their cobalt(III) complexes: Unexpected conformational behavior. Inorganic Chemistry, 35 (7), 2045-2052. doi: 10.1021/ic951260y

Stereoselective assembly of a new pendant-arm macrocycle

Bernhardt, Paul V., Byriel, Karl A., Kennard, Colin H. L. and Sharpe, Philip C. (1996). Stereoselective assembly of a new pendant-arm macrocycle. Journal of the Chemical Society - Dalton Transactions (1), 145-146. doi: 10.1039/dt9960000145

N-methylation of diamino-substituted macrocyclic complexes: Intermolecular reactions

Bernhardt, PV (1996). N-methylation of diamino-substituted macrocyclic complexes: Intermolecular reactions. Journal of The Chemical Society-dalton Transactions (23), 4319-4324. doi: 10.1039/dt9960004319

N-methylation of diamino-substituted macrocyclic complexes: Intramolecular cyclisation

Bernhardt, PV, Hetherington, JC and Jones, LA (1996). N-methylation of diamino-substituted macrocyclic complexes: Intramolecular cyclisation. Journal of The Chemical Society-dalton Transactions (23), 4325-4330. doi: 10.1039/dt9960004325

Unexpected rearrangement of a novel pendent-arm tetraazamacrocyclic complex

Bernhardt P.V. and Sharpe P.C. (1996). Unexpected rearrangement of a novel pendent-arm tetraazamacrocyclic complex. Chemical Communications (11), 1267-1268. doi: 10.1039/cc9960001267

COPPER(II) COMPLEXES OF SUBSTITUTED MACROBICYCLIC HEXAAMINES - COMBINED TRIGONAL AND TETRAGONAL DISTORTIONS

BERNHARDT, PV, BRAMLEY, R, ENGELHARDT, LM, HARROWFIELD, JM, HOCKLESS, DCR, KORYBUTDASZKIEWICZ, BR, KRAUSZ, ER, MORGAN, T, SARGESON, AM, SKELTON, BW and WHITE, AH (1995). COPPER(II) COMPLEXES OF SUBSTITUTED MACROBICYCLIC HEXAAMINES - COMBINED TRIGONAL AND TETRAGONAL DISTORTIONS. Inorganic Chemistry, 34 (14), 3589-3599. doi: 10.1021/ic00118a005

N-METHYLATED MACROBICYCLIC HEXAAMINES OF COPPER(II) AND NICKEL(II) - LARGE STERIC EFFECTS

BERNHARDT, PV, HARROWFIELD, JM, HOCKLESS, DCR and SARGESON, AM (1994). N-METHYLATED MACROBICYCLIC HEXAAMINES OF COPPER(II) AND NICKEL(II) - LARGE STERIC EFFECTS. Inorganic Chemistry, 33 (25), 5659-5670. doi: 10.1021/ic00103a011

STABILIZATION OF COBALT CAGE CONFORMERS IN THE SOLID-STATE AND SOLUTION

BERNHARDT, PV, BYGOTT, AMT, GEUE, RJ, HENDRY, AJ, KORYBUTDASZKIEWICZ, BR, LAY, PA, PLADZIEWICZ, , SARGESON, AM and WILLIS, AC (1994). STABILIZATION OF COBALT CAGE CONFORMERS IN THE SOLID-STATE AND SOLUTION. Inorganic Chemistry, 33 (20), 4553-4561. doi: 10.1021/ic00098a023

METAL-DIRECTED SYNTHESIS OF MACROCYCLIC TETRAAMINES WITH PENDANT NITRO OR AMINE GROUPS, BASED ON TRANS-CYCLOHEXANE-1,2-DIAMINE

BERNHARDT, PV, COMBA, P, ELLIOTT, BL, LAWRANCE, GA, MAEDER, M, OLEARY, MA, WEI, G and WILKES, EN (1994). METAL-DIRECTED SYNTHESIS OF MACROCYCLIC TETRAAMINES WITH PENDANT NITRO OR AMINE GROUPS, BASED ON TRANS-CYCLOHEXANE-1,2-DIAMINE. Australian Journal of Chemistry, 47 (6), 1171-1178. doi: 10.1071/CH9941171

QUINQUEDENTATE COORDINATION OF 3-[(2'-AMINO-ETHYL)AMINO]-2-[(2''-AMINOETHYL)AMINOMETHYL]PROPIONIC ACID (LH) - CRYSTAL-STRUCTURE OF TRANS-[CO(L)CL][CLO4].H2O AND MOLECULAR MECHANICS EXAMINATION OF ISOMERS

BERNHARDT, PV, HAMBLEY, TW, LAWRANCE, GA and MOLLOY, KJ (1994). QUINQUEDENTATE COORDINATION OF 3-[(2'-AMINO-ETHYL)AMINO]-2-[(2''-AMINOETHYL)AMINOMETHYL]PROPIONIC ACID (LH) - CRYSTAL-STRUCTURE OF TRANS-[CO(L)CL][CLO4].H2O AND MOLECULAR MECHANICS EXAMINATION OF ISOMERS. Australian Journal of Chemistry, 47 (5), 817-827. doi: 10.1071/CH9940817

RESOLUTION OF RACEMIC AMINO-ACIDS VIA STEREOSELECTIVE LIGAND-EXCHANGE REACTIONS ON AN OPTICALLY PURE NICKEL(II) COMPLEX

BERNHARDT, PV, COMBA, P, HAMBLEY, TW, SOVAGO, and VARNAGY, K (1993). RESOLUTION OF RACEMIC AMINO-ACIDS VIA STEREOSELECTIVE LIGAND-EXCHANGE REACTIONS ON AN OPTICALLY PURE NICKEL(II) COMPLEX. Journal of the Chemical Society-Dalton Transactions (13), 2023-2026. doi: 10.1039/dt9930002023

COMPLEXATION OF CIS-6,13-DIMETHYL-1,4,8,11-TETRAAZACYCLOTETRADECANE-6,13-DIAMINE WITH THE 1ST ROW TRANSITION-METAL IONS COBALT(III), CHROMIUM(III), AND NICKEL(II)

BERNHARDT, PV, COMBA, P and HAMBLEY, TW (1993). COMPLEXATION OF CIS-6,13-DIMETHYL-1,4,8,11-TETRAAZACYCLOTETRADECANE-6,13-DIAMINE WITH THE 1ST ROW TRANSITION-METAL IONS COBALT(III), CHROMIUM(III), AND NICKEL(II). Inorganic Chemistry, 32 (13), 2804-2809. doi: 10.1021/ic00065a004

PREDICTION AND INTERPRETATION OF ELECTRONIC-SPECTRA OF TRANSITION-METAL COMPLEXES VIA THE COMBINATION OF MOLECULAR MECHANICS AND ANGULAR OVERLAP MODEL-CALCULATIONS

BERNHARDT, PV and COMBA, P (1993). PREDICTION AND INTERPRETATION OF ELECTRONIC-SPECTRA OF TRANSITION-METAL COMPLEXES VIA THE COMBINATION OF MOLECULAR MECHANICS AND ANGULAR OVERLAP MODEL-CALCULATIONS. Inorganic Chemistry, 32 (13), 2798-2803. doi: 10.1021/ic00065a003

CHIRAL QUADRIDENTATE LIGANDS BASED ON AMINO-ACIDS - TEMPLATE SYNTHESES AND PROPERTIES OF THE FREE LIGANDS AND THEIR TRANSITION-METAL COMPLEXES

BALLA, J, BERNHARDT, PV, BUGLYO, P, COMBA, P, HAMBLEY, TW, SCHMIDLIN, R, STEBLER, S and VARNAGY, K (1993). CHIRAL QUADRIDENTATE LIGANDS BASED ON AMINO-ACIDS - TEMPLATE SYNTHESES AND PROPERTIES OF THE FREE LIGANDS AND THEIR TRANSITION-METAL COMPLEXES. Journal of the Chemical Society-Dalton Transactions (7), 1143-1149. doi: 10.1039/dt9930001143

FORMATION OF EXOCYCLIC OLEFINIC GROUPS VIA STEREOSELECTIVE NITROSATIONS - A NEW ROUTE TOWARDS PENDANT ARM MACROCYCLIC LIGANDS

BERNHARDT, PV and COMBA, P (1993). FORMATION OF EXOCYCLIC OLEFINIC GROUPS VIA STEREOSELECTIVE NITROSATIONS - A NEW ROUTE TOWARDS PENDANT ARM MACROCYCLIC LIGANDS. Journal of the Chemical Society-Chemical Communications (2), 113-114. doi: 10.1039/c39930000113

TRANSITION-METAL COMPLEXES OF THE NOVEL TRIDENTATE DI-2-PYRIDYLMETHANAMINE (DIPA)

BERNHARDT, PV, COMBA, P, MAHURICKENBACH, A, STEBLER, S, STEINER, S, VARNAGY, K and ZEHNDER, M (1992). TRANSITION-METAL COMPLEXES OF THE NOVEL TRIDENTATE DI-2-PYRIDYLMETHANAMINE (DIPA). Inorganic Chemistry, 31 (20), 4194-4200. doi: 10.1021/ic00046a038

DETERMINATION OF SOLUTION STRUCTURES OF BINUCLEAR COPPER(II) COMPLEXES

BERNHARDT, PV, COMBA, P, HAMBLEY, TW, MASSOUD, SS and STEBLER, S (1992). DETERMINATION OF SOLUTION STRUCTURES OF BINUCLEAR COPPER(II) COMPLEXES. Inorganic Chemistry, 31 (12), 2644-2651. doi: 10.1021/ic00038a061

MOLECULAR MECHANICS CALCULATIONS OF TRANSITION-METAL COMPLEXES

BERNHARDT, PV and COMBA, P (1992). MOLECULAR MECHANICS CALCULATIONS OF TRANSITION-METAL COMPLEXES. Inorganic Chemistry, 31 (12), 2638-2644. doi: 10.1021/ic00038a060

PREDICTIONS AND METHODS OF SEPARATION OF RACEMIC BIDENTATE LIGANDS VIA STEREOSELECTIVE LIGAND-EXCHANGE REACTIONS

BERNHARDT, PV, COMBA, P, GYR, T and VARNAGY, K (1992). PREDICTIONS AND METHODS OF SEPARATION OF RACEMIC BIDENTATE LIGANDS VIA STEREOSELECTIVE LIGAND-EXCHANGE REACTIONS. Inorganic Chemistry, 31 (7), 1220-1223. doi: 10.1021/ic00033a018

PLATINUM(IV) COMPLEXES OF A TETRAAZA MACROCYCLE WITH PENDENT DICHLOROAMINE OR AMMONIUM GROUPS

BERNHARDT, PV, LAWRANCE, GA and HAMBLEY, TW (1992). PLATINUM(IV) COMPLEXES OF A TETRAAZA MACROCYCLE WITH PENDENT DICHLOROAMINE OR AMMONIUM GROUPS. Inorganic Chemistry, 31 (4), 631-634. doi: 10.1021/ic00030a020

ISOLATION AND COMPLEXATION OF THE CIS ISOMER OF THE PENDANT ARM MACROCYCLE 6,13-DIMETHYL-1,4,8,11-TETRAAZACYCLOTETRADECANE-6,13-DIAMINE

BERNHARDT, PV, COMBA, P, HAMBLEY, TW, LAWRANCE, GA and VARNAGY, K (1992). ISOLATION AND COMPLEXATION OF THE CIS ISOMER OF THE PENDANT ARM MACROCYCLE 6,13-DIMETHYL-1,4,8,11-TETRAAZACYCLOTETRADECANE-6,13-DIAMINE. Journal of the Chemical Society-Dalton Transactions (3), 355-359. doi: 10.1039/dt9920000355

CHIRAL TETRAAMINES BASED ON (S)-2-(AMINOMETHYL)PYRROLIDINE - TEMPLATE SYNTHESIS AND PROPERTIES OF COPPER(II) COMPLEXES

BERNHARDT, PV, COMBA, P, HAMBLEY, TW, MARTIN, LL, VARNAGY, K and ZIPPER, L (1992). CHIRAL TETRAAMINES BASED ON (S)-2-(AMINOMETHYL)PYRROLIDINE - TEMPLATE SYNTHESIS AND PROPERTIES OF COPPER(II) COMPLEXES. Helvetica Chimica Acta, 75 (1), 145-152. doi: 10.1002/hlca.19920750111

CORRECTION

BERNHARDT, PV (1992). CORRECTION. Helvetica Chimica Acta, 75 (2), 645-645.

Epr-Spectrum and Metal-Ligand Bonding Parameters of a Low-Spin (hexaamine)iron(iii) Complex

Stratemeier, H, Hitchman, MA, Comba, P, Bernhardt, PV and Riley, MJ (1991). Epr-Spectrum and Metal-Ligand Bonding Parameters of a Low-Spin (hexaamine)iron(iii) Complex. Inorganic Chemistry, 30 (21), 4088-4093. doi: 10.1021/ic00021a023

SEXIDENTATE COORDINATION OF THE PENDANT-ARM MACROCYCLE 6,13-DIMETHYL-1,4,8,11-TETRAAZACYCLOTETRADECANE-6,13-DIAMINE (L1) TO ZINC(II) - CRYSTAL-STRUCTURE OF [ZNL1][CLO4]2.H2O

BERNHARDT, PV, LAWRANCE, GA, MAEDER, M, ROSSIGNOLI, M and HAMBLEY, TW (1991). SEXIDENTATE COORDINATION OF THE PENDANT-ARM MACROCYCLE 6,13-DIMETHYL-1,4,8,11-TETRAAZACYCLOTETRADECANE-6,13-DIAMINE (L1) TO ZINC(II) - CRYSTAL-STRUCTURE OF [ZNL1][CLO4]2.H2O. Journal of the Chemical Society-Dalton Transactions (5), 1167-1182. doi: 10.1039/dt9910001167

COORDINATION OF THE SEXIDENTATE MACROCYCLE 6,13-DIMETHYL-1,4,8,11-TETRAAZACYCLOTETRADECANE-6,13-DIAMINE TO IRON(III)

BERNHARDT, PV, COMBA, P, HAMBLEY, TW and LAWRANCE, GA (1991). COORDINATION OF THE SEXIDENTATE MACROCYCLE 6,13-DIMETHYL-1,4,8,11-TETRAAZACYCLOTETRADECANE-6,13-DIAMINE TO IRON(III). Inorganic Chemistry, 30 (5), 942-946. doi: 10.1021/ic00005a013

A MOLECULAR-MECHANICS ANALYSIS OF COMPLEXES OF THE SEXIDENTATE MACROCYCLES CIS-6,13-DIMETHYL-1,4,8,11-TETRAAZACYCLOTETRADECANE-6,13-DIAMINE AND TRANS-6,13-DIMETHYL-1,4,8,11-TETRAAZACYCLOTETRADECANE-6,13-DIAMINE

BERNHARDT, PV and COMBA, P (1991). A MOLECULAR-MECHANICS ANALYSIS OF COMPLEXES OF THE SEXIDENTATE MACROCYCLES CIS-6,13-DIMETHYL-1,4,8,11-TETRAAZACYCLOTETRADECANE-6,13-DIAMINE AND TRANS-6,13-DIMETHYL-1,4,8,11-TETRAAZACYCLOTETRADECANE-6,13-DIAMINE. Helvetica Chimica Acta, 74 (8), 1834-1842. doi: 10.1002/hlca.19910740826

PULSE-RADIOLYSIS OF MONONUCLEAR AND BINUCLEAR COPPER(II) MACROCYCLIC COMPLEXES

BERNHARDT, PV, LAWRANCE, GA and SANGSTER, DF (1991). PULSE-RADIOLYSIS OF MONONUCLEAR AND BINUCLEAR COPPER(II) MACROCYCLIC COMPLEXES. Polyhedron, 10 (12), 1373-1377. doi: 10.1016/S0277-5387(00)81271-1

COORDINATION OF 6,13-DIMETHYL-1,4,8,11-TETRA-AZACYCLOTETRADECANE-6,13-DIAMINE TO PLATINUM(II) AND PALLADIUM(II) - SYNTHESES, CHARACTERIZATION, AND X-RAY CRYSTAL-STRUCTURES OF THE PERCHLORATE SALTS OF BOTH COMPLEXES

BERNHARDT, PV, LAWRANCE, GA, PATALINGHUG, WC, SKELTON, BW, WHITE, AH, CURTIS, NF and SIRIWARDENA, A (1990). COORDINATION OF 6,13-DIMETHYL-1,4,8,11-TETRA-AZACYCLOTETRADECANE-6,13-DIAMINE TO PLATINUM(II) AND PALLADIUM(II) - SYNTHESES, CHARACTERIZATION, AND X-RAY CRYSTAL-STRUCTURES OF THE PERCHLORATE SALTS OF BOTH COMPLEXES. Journal of the Chemical Society-Dalton Transactions (9), 2853-2858. doi: 10.1039/dt9900002853

SYNTHESIS, PHYSICAL-PROPERTIES AND X-RAY CRYSTAL-STRUCTURE OF AN OXOVANADIUM(IV) COMPLEX OF THE PENDANT-ARM MACROCYCLE 6,13-DIMETHYL-1,4,8,11-TETRA-AZACYCLOTETRADECANE-6,13-DIAMINE

BERNHARDT, PV, LAWRANCE, GA, COMBA, P, MARTIN, LL and HAMBLEY, TW (1990). SYNTHESIS, PHYSICAL-PROPERTIES AND X-RAY CRYSTAL-STRUCTURE OF AN OXOVANADIUM(IV) COMPLEX OF THE PENDANT-ARM MACROCYCLE 6,13-DIMETHYL-1,4,8,11-TETRA-AZACYCLOTETRADECANE-6,13-DIAMINE. Journal of the Chemical Society-Dalton Transactions (9), 2859-2862. doi: 10.1039/dt9900002859

COORDINATION OF THE PENDANT-ARM MACROCYCLE 6,13-DIAMINO-6,13-DIMETHYL-1,4,8,11-TETRAAZACYCLOTETRADECANE TO CHROMIUM(III) - CRYSTAL-STRUCTURE AND PHYSICAL-PROPERTIES OF THE HEXACOORDINATED COMPLEX ION

BERNHARDT, PV, COMBA, P, CURTIS, NF, HAMBLEY, TW, LAWRANCE, GA, MAEDER, M and SIRIWARDENA, A (1990). COORDINATION OF THE PENDANT-ARM MACROCYCLE 6,13-DIAMINO-6,13-DIMETHYL-1,4,8,11-TETRAAZACYCLOTETRADECANE TO CHROMIUM(III) - CRYSTAL-STRUCTURE AND PHYSICAL-PROPERTIES OF THE HEXACOORDINATED COMPLEX ION. Inorganic Chemistry, 29 (17), 3208-3213. doi: 10.1021/ic00342a031

COMPLEXES OF POLYAZA MACROCYCLES BEARING PENDENT COORDINATING GROUPS

BERNHARDT, PV and LAWRANCE, GA (1990). COMPLEXES OF POLYAZA MACROCYCLES BEARING PENDENT COORDINATING GROUPS. Coordination Chemistry Reviews, 104 (2), 297-343. doi: 10.1016/0010-8545(90)80045-U

RHODIUM(III) COMPLEXES OF THE AMBIDENTATE MACROCYCLE 6,13-DIAMINO-6,13-DIMETHYL-1,4,8,11-TETRA-AZACYCLOTETRADECANE - CRYSTAL-STRUCTURE OF THE SEXIDENTATE COMPLEX

BERNHARDT, PV, LAWRANCE, GA and HAMBLEY, TW (1990). RHODIUM(III) COMPLEXES OF THE AMBIDENTATE MACROCYCLE 6,13-DIAMINO-6,13-DIMETHYL-1,4,8,11-TETRA-AZACYCLOTETRADECANE - CRYSTAL-STRUCTURE OF THE SEXIDENTATE COMPLEX. Journal of the Chemical Society-Dalton Transactions (3), 983-987. doi: 10.1039/dt9900000983

COBALT(III) COMPLEXES OF 1,5,9-TRIAMINO-5-METHYL-3,7-DIAZANONANE,L1, A NEW QUINQUEDENTATE POLYAMINE LIGAND - CRYSTAL-STRUCTURES OF THE CHLOROCOBALT(III) AND MU-SUPEROXO-DICOBALT(III) COMPLEXES OF L1

BERNHARDT, PV, LAWRANCE, GA and HAMBLEY, TW (1990). COBALT(III) COMPLEXES OF 1,5,9-TRIAMINO-5-METHYL-3,7-DIAZANONANE,L1, A NEW QUINQUEDENTATE POLYAMINE LIGAND - CRYSTAL-STRUCTURES OF THE CHLOROCOBALT(III) AND MU-SUPEROXO-DICOBALT(III) COMPLEXES OF L1. Journal of the Chemical Society-Dalton Transactions (1), 235-241. doi: 10.1039/dt9900000235

CRYSTAL-STRUCTURES OF [H4L] (CLO4)4.6H2O AND [ZN(H2L)(S2O6)2].4H2O (L = 6,13-DIMETHYL-1,4,8,11-TETRAAZACYCLOTETRADECANE-6,13-DIAMINE)

BERNHARDT, PV, HAMBLEY, TW and LAWRANCE, GA (1990). CRYSTAL-STRUCTURES OF [H4L] (CLO4)4.6H2O AND [ZN(H2L)(S2O6)2].4H2O (L = 6,13-DIMETHYL-1,4,8,11-TETRAAZACYCLOTETRADECANE-6,13-DIAMINE). Australian Journal of Chemistry, 43 (4), 699-706. doi: 10.1071/CH9900699

Dicopper(II) complexes of spiro macrobicycles with aza and thia aza donor sets

Bernhardt P.V., Comba P., Gahan L.R. and Lawrance G.A. (1990). Dicopper(II) complexes of spiro macrobicycles with aza and thia aza donor sets. Australian Journal of Chemistry, 43 (12), 2035-2044. doi: 10.1071/CH9902035

FACILE METAL-DIRECTED SYNTHESIS AND CRYSTAL-STRUCTURE OF A NEW AMINO-ACID ESTER, METHYL 3-[(2-AMINOETHYL)AMINO]-2-[(2-AMINOETHYL)AMINOMETHYL]PROPIONATE, AS THE COPPER(II) COMPLEX

BERNHARDT, PV, LAWRANCE, GA, SKELTON, BW and WHITE, AH (1990). FACILE METAL-DIRECTED SYNTHESIS AND CRYSTAL-STRUCTURE OF A NEW AMINO-ACID ESTER, METHYL 3-[(2-AMINOETHYL)AMINO]-2-[(2-AMINOETHYL)AMINOMETHYL]PROPIONATE, AS THE COPPER(II) COMPLEX. Australian Journal of Chemistry, 43 (2), 399-404. doi: 10.1071/CH9900399

6,13-DIAMINO-6,13-DIMETHYL-1,4,8,11-TETRA-AZACYCLOTETRADECANE, L7, A NEW, POTENTIALLY SEXIDENTATE POLYAMINE LIGAND - VARIABLE COORDINATION TO COBALT(III) AND CRYSTAL-STRUCTURE OF THE COMPLEX [CO(L7)]CL2[CLO4]

BERNHARDT, PV, LAWRANCE, GA and HAMBLEY, TW (1989). 6,13-DIAMINO-6,13-DIMETHYL-1,4,8,11-TETRA-AZACYCLOTETRADECANE, L7, A NEW, POTENTIALLY SEXIDENTATE POLYAMINE LIGAND - VARIABLE COORDINATION TO COBALT(III) AND CRYSTAL-STRUCTURE OF THE COMPLEX [CO(L7)]CL2[CLO4]. Journal of the Chemical Society-Dalton Transactions (6), 1059-1065. doi: 10.1039/dt9890001059

COORDINATION OF 6,13-DIAMINO-6,13-DIMETHYL-1,4,8,11-TETRA-AZACYCLOTETRADECANE TO IRON(III) - THE 1ST FULLY CHARACTERIZED HEXA-AMINEIRON(III) COMPLEX

BERNHARDT, PV, HAMBLEY, T and LAWRANCE, GA (1989). COORDINATION OF 6,13-DIAMINO-6,13-DIMETHYL-1,4,8,11-TETRA-AZACYCLOTETRADECANE TO IRON(III) - THE 1ST FULLY CHARACTERIZED HEXA-AMINEIRON(III) COMPLEX. Journal of the Chemical Society-Chemical Communications (9), 553-554. doi: 10.1039/c39890000553

CONDENSATIONS OF ETHANE-1,2-DIAMINE, FORMALDEHYDE AND AMMONIA (OR NITROETHANE) DIRECTED BY NICKEL(II) OR COPPER(II) - CRYSTAL-STRUCTURE OF (8-METHYL-8-NITRO-1,3,6,10,13,15-HEXAAZATRICYCLO[13.1.1.1 13,15]OCTADECANE)NICKEL(II) PERCHLORATE

BERNHARDT, PV, CURTIS, LS, CURTIS, NF, LAWRANCE, GA, SKELTON, BW and WHITE, AH (1989). CONDENSATIONS OF ETHANE-1,2-DIAMINE, FORMALDEHYDE AND AMMONIA (OR NITROETHANE) DIRECTED BY NICKEL(II) OR COPPER(II) - CRYSTAL-STRUCTURE OF (8-METHYL-8-NITRO-1,3,6,10,13,15-HEXAAZATRICYCLO[13.1.1.1 13,15]OCTADECANE)NICKEL(II) PERCHLORATE. Australian Journal of Chemistry, 42 (6), 797-811. doi: 10.1071/CH9890797

COORDINATION OF THE HEXACYANOFERRATE(III) ANION TO A POLYAMMONIUM MACROCYCLE - CRYSTAL-STRUCTURE OF [H4L]1.5[FE(CN)6]2 (L=6,13-DIMETHYL-1,4,8,11-TETRAAZA-CYCLOTETRADECANE-6,13-DIAMINE)

BERNHARDT, PV, LAWRANCE, GA, SKELTON, BW and WHITE, AH (1989). COORDINATION OF THE HEXACYANOFERRATE(III) ANION TO A POLYAMMONIUM MACROCYCLE - CRYSTAL-STRUCTURE OF [H4L]1.5[FE(CN)6]2 (L=6,13-DIMETHYL-1,4,8,11-TETRAAZA-CYCLOTETRADECANE-6,13-DIAMINE). Australian Journal of Chemistry, 42 (7), 1035-1043. doi: 10.1071/CH9891035

NICKEL(I) AND NICKEL(III) COMPLEXES OF SUBSTITUTED TETRAAZA MACROCYCLES FORMED BY PULSE-RADIOLYSIS AND ELECTROCHEMISTRY OF NICKEL(II) PRECURSORS

BERNHARDT, PV, LAWRANCE, GA and SANGSTER, DF (1988). NICKEL(I) AND NICKEL(III) COMPLEXES OF SUBSTITUTED TETRAAZA MACROCYCLES FORMED BY PULSE-RADIOLYSIS AND ELECTROCHEMISTRY OF NICKEL(II) PRECURSORS. Inorganic Chemistry, 27 (22), 4055-4059. doi: 10.1021/ic00295a032

SYNTHESES OF (IMIDAZOLE)PENTAAMMINEMETAL(III) AND MU-IMIDAZOLATODECAAMMINEDIMETAL(III) COMPLEXES FROM TRIFLUOROMETHANESULFONATO PRECURSORS

BERNHARDT, PV and LAWRANCE, GA (1987). SYNTHESES OF (IMIDAZOLE)PENTAAMMINEMETAL(III) AND MU-IMIDAZOLATODECAAMMINEDIMETAL(III) COMPLEXES FROM TRIFLUOROMETHANESULFONATO PRECURSORS. Polyhedron, 6 (6), 1347-1350. doi: 10.1016/S0277-5387(00)80894-3

TRIFLUOROMETHANESULFONATO COMPLEXES OF (1,4,8,11-TETRAAZACYCLOTETRADECANE)COBALT(III) AND RUTHENIUM(III) WITH TRANS GEOMETRY

BERNHARDT, PV and LAWRANCE, GA (1987). TRIFLUOROMETHANESULFONATO COMPLEXES OF (1,4,8,11-TETRAAZACYCLOTETRADECANE)COBALT(III) AND RUTHENIUM(III) WITH TRANS GEOMETRY. Polyhedron, 6 (10), 1875-1878. doi: 10.1016/S0277-5387(00)81098-0

Development of novel [F-18]thiosemicarbazone metal fluoride complexes as potential neuroimaging agents

Stimson, D., Venkatachalam, T. K., Pierens, G. K., Bernhardt, P. V., Mardon, K., Reutens, D. C. and Bhalla, R. (2019). Development of novel [F-18]thiosemicarbazone metal fluoride complexes as potential neuroimaging agents. 32nd Annual Congress of the European Association of Nuclear Medicine (EANM), Barcelona, Spain, 12-16 October 2019. Heidelberg, Germany: Springer.

Cyclic penta- and hexa leucine peptides without N-methylation are orally absorbed

Kok, Woan Mei, Hill, Timothy A., Lohman, Rink-Jan, Hoang, Huy N., Nielsen, Daniel S., Scully, Conor G., Schroeder, Christina I., Colless, Barbara, Bernhardt, Paul V., Edmonds, David, Griffith, David, Rotter, Charles, Ruggeri, Roger, Price, David, Liras, Spiros, Craik, David and Fairlie, David (2015). Cyclic penta- and hexa leucine peptides without N-methylation are orally absorbed. American Chemical Society Meeting, x, 2015. Washington, DC United States: American Chemical Society.

Viridicatumtoxins: Exploring structural diversity and antibiotic properties

Shang, Z., Salim, A. A., Khalil, Z. G., Quezada, M., Bernhardt, P. V. and Capon, R. J. (2015). Viridicatumtoxins: Exploring structural diversity and antibiotic properties. Annual Meeting of the American-Society-of-Pharmacognosy, Copper Mountain, CO, United States, 25-29 July 2015. Stuttgart, Germany: Georg Thieme. doi: 10.1055/s-0035-1556338

Mediated Molybdoenzyme Electrocatalysis

Bernhardt, P. V. (2014). Mediated Molybdoenzyme Electrocatalysis. 16th International Conference on Biological Inorganic Chemistry (ICBIC), Grenoble France, 22-26 July 2013. Heidelberg, Germany: Springer.

The Impact of the Ability to Form Hydrogen Bonds on the Activity of Model Systems for Phosphoesterases

Bosch, S., Comba, P., Bernhardt, P. and Gahan, L. (2014). The Impact of the Ability to Form Hydrogen Bonds on the Activity of Model Systems for Phosphoesterases. 16th International Conference on Biological Inorganic Chemistry (ICBIC), Grenoble France, 22-26 July 2013. Heidelberg, Germany: Springer. doi: 10.1007/s00775-014-1095-8

Globin-mediated nitric oxide detoxification in the foodborne pathogenic bacterium Campylobacter jejuni proceeds via a dioxygenase or denitrosylase mechanism

Shepherd, Mark, Bernhardt, Paul V. and Poole, Robert K. (2011). Globin-mediated nitric oxide detoxification in the foodborne pathogenic bacterium Campylobacter jejuni proceeds via a dioxygenase or denitrosylase mechanism. Maryland Heights, MO, U.S.A.: Academic Press. doi: 10.1016/j.niox.2010.12.006

Structure and absolute configuration of 3-alkylpiperidine alkaloids from an Indonesian sponge of the genus Halichondria

Mudianta, I. Wayan, Katavic, Peter, Lambert, Lynette Kay, Hayes, Patricia T., Banwell, Martin G., Munro, Murray H. G., Bernhardt, Paul V. and Garson, Mary J. (2011). Structure and absolute configuration of 3-alkylpiperidine alkaloids from an Indonesian sponge of the genus Halichondria. International Symposium on the Chemistry of Natural Products (27th, ISCNP, 2011) and the 7th International Conference on Biodiversity (7th, ICOB, 2011), South Bank, QLD, Australia, 10-15 July 2011.

Metalloproteins and their role in sulfur oxidation processes

Bernhardt, P. V., Hanson, G. R., Kappler, Ulrike, Kilmartin, J. R., Low, L., Maher, M.M, Rapson, T.D. and Riley, M.J. (2010). Metalloproteins and their role in sulfur oxidation processes. Boden Research Conference 2010, Canberra, Australia, 28 November – 1 December 2010. ACT, Australia: Australian Academy of Science.

Structure and absolute configuration of tetradehydrohaliclonacyclamine A, a new alkaloid from an Indonesian sponge of the genus Halichondria

Mudianta, I. Wayan, Katavic, Peter L., Lambert, Lynette K., Hayes, Patricia T., Banwell, Martin G., Bernhardt, Paul V. and Garson, Mary J. (2010). Structure and absolute configuration of tetradehydrohaliclonacyclamine A, a new alkaloid from an Indonesian sponge of the genus Halichondria. 13th International Symposium on Marine Natural Products, Phuket, Thailand, 17-22 October 2010.

Stereochemistry and biosynthesis of 3-alkylpiperidine alkaloids

Mudianta, I. Wayan, Bernhardt, P.V. and Garson, M.J. (2009). Stereochemistry and biosynthesis of 3-alkylpiperidine alkaloids. 42nd Congress of IUPAC, Glasgow, Scotland, 2-7 August 2009.

Structure and absolute configuration of Tetradehydrohaliclonacyclamine A, a new alkaloid from an Indonesian sponge of the genus Halichondria

Mudianta, I Wayan, Lambert, L.K., Bernhardt, P.V. and Garson, M.J. (2009). Structure and absolute configuration of Tetradehydrohaliclonacyclamine A, a new alkaloid from an Indonesian sponge of the genus Halichondria. International Conference on Medicinal Chemistry, Bandung, Indonesia, 6-8 August, 2009.

PCTH: A novel orally active chelator for the treatment of iron overload disease

Lovejoy, David B., Kalinowski, Danuta, Bernhardt, Paul V. and Richardson, Des R. (2006). PCTH: A novel orally active chelator for the treatment of iron overload disease. doi: 10.1080/03630260500455367

Molecular mixed-valence cyanide bridged CoIII-FeII complexes

Bernhardt, Paul V., Bozoglián, Fernando, Macpherson, Brendan P. and Martínez, Manuel (2005). Molecular mixed-valence cyanide bridged CoIII-FeII complexes. doi: 10.1016/j.ccr.2004.11.014

Cytochrome c551 from Starkeya novella - characterization, spectroscopic properties and phylogeny of a diheme protein of the SoxAX family

Kappler, U., Aguey, F.K., Hanson, G. R., Bernhardt, P. V. and McEwan, A. G. (2004). Cytochrome c551 from Starkeya novella - characterization, spectroscopic properties and phylogeny of a diheme protein of the SoxAX family. VAAM (Germany Microbiology Society) Meeting, Braunschweig, 28-31 March, 2004.

Ion motive electron transfer pathways involving type II molybdoenzymes of the DMSO reductase family

Mcewan, A. G., Bernhardt, P. V., Creevey, N., Hanson, G. R. and McDevitt, C. A. (2004). Ion motive electron transfer pathways involving type II molybdoenzymes of the DMSO reductase family. 13th European Bioenergetics Conference (EBEC 2004), Pisa, Italy, 21-26 Aug 2004. Amsterdam, The Netherlands: Elsevier Science Bv. doi: 10.1016/j.bbabio.2004.06.002

DNA cleavage with dinuclear metal complexes of ligands with varying flexibility

De Iuliis, G. N., Lawrance, G. A. and Bernhardt, P. V. (2003). DNA cleavage with dinuclear metal complexes of ligands with varying flexibility. 11th International Conference on Biological Inorganic Chemistry, Cairns, Australia, 19-23 Jul 2003. New York, NY, USA: Elsevier Science Inc. doi: 10.1016/S0162-0134(03)80658-X

Direct electrochemistry of bacterial molybdoenzymes

Aguey-Zinsou, K. F., Bernhardt, P. V. and McEwan, A. G. (2003). Direct electrochemistry of bacterial molybdoenzymes. 11th International Conference on Biological Inorganic Chemistry, Cairns, Australia, 19-23 Jul 2003. New York, NY, USA: Elsevier Science Inc. doi: 10.1016/S0162-0134(03)80545-7

Direct electrochemistry of cytochrome P450cin : new insights into P450 mechanism

Bernhardt, Paul V., Aguey-Zinsou, Kondo-Francois, De Voss, James J. and Slessor, Kate E. (2003). Direct electrochemistry of cytochrome P450cin : new insights into P450 mechanism. 11th International Conference on Biological Inorganic Chemistry, Cairns, Qld, 19-23 July, 2003. New York: Elsevier. doi: 10.1016/S0162-0134(03)80462-2

Intramolecular PET & EET - ricepaper screens and masthead lanterns

Moore, E. G., Bernhardt, P. V., Fuerstenberg, A., Pigliucci, A., Riley, M. J., Smith, T. and Vauthey, E. (2003). Intramolecular PET & EET - ricepaper screens and masthead lanterns. 6th Brisbane Inorganic Chemistry Symposium, Brisbane, Australia, 2 Dec 2003.

Intramolecular electron and energy transfer in bichromophoric macr

Moore, E. G., Bernhardt, P. V., Riley, M. J. and Vauthey, E. (2003). Intramolecular electron and energy transfer in bichromophoric macr. Conf of Inorganic Chemistry Division, RACI, Melbourne, 2-6 Feb, 2003.

Orally active Chelators for the treatment of iron overload diseases

Chin, Alex P., Bernhardt, Paul V. and Richardson, Des R. (2003). Orally active Chelators for the treatment of iron overload diseases. 11th International Conference on Biological Inorganic Chemistry, Cairns, Australia, 19-23 July, 2003. New York: Elsevier. doi: 10.1016/S0162-0134(03)80592-5

Probing molecular properties: Direct electrochemistry of sulfite dehydrogenase from Starkeya novella

Aguey, F.K., Bernhardt, P. V., Kappler, U. and McEwan, A. G. (2003). Probing molecular properties: Direct electrochemistry of sulfite dehydrogenase from Starkeya novella. Biospektrum, Berlin, 23-26 March, 2003.

Site-directed mutagenesis of dimethylsulfoxide reductase from Rhodobacter capsulatus: The critical roles of tyrosine-114 and tryptophan-116

McEwan, Alastair G., Ridge, Justin P., Aguey-Zinsou, Kondo-Francois, Bernhardt, Paul V. and Hanson, Graeme R. (2003). Site-directed mutagenesis of dimethylsulfoxide reductase from Rhodobacter capsulatus: The critical roles of tyrosine-114 and tryptophan-116. 11th International Conference on Biological Inorganic Chemistry, Cairns, Australia, 19 - 23 July, 2003. New York: Elsevier. doi: 10.1016/S0162-0134(03)80496-8

Reactions of tetramethyldiaminomethane with platinum(II) and palladium(II): Hydrolysis of coordinated ligand, and an unusual insertion of the resultant formaldehyde into a C-N bond in a strained chelate ring

Appleton, T. G., Begum, S., Bernhardt, P. V., Bryant, G. K. and Hoang, H. (2002). Reactions of tetramethyldiaminomethane with platinum(II) and palladium(II): Hydrolysis of coordinated ligand, and an unusual insertion of the resultant formaldehyde into a C-N bond in a strained chelate ring. 8th International Conference on the Chemistry of the Platinum Group Metals, Southampton, U.K., July, 2002.

Predicting Ianthanide spectroscopy and applications to energy up-conversion

Flanagan, B., Bernhardt, P. V., Luethi, S. and Riley, M. J. (2001). Predicting Ianthanide spectroscopy and applications to energy up-conversion. Australiasian Conference on Optics, Lasers and Spectroscopy, Brisbane, 3-6 December, 2001. Brisbane: ACOLS 2001.

Interpreting disorder and solution structures with molecular mechanics

Bernhardt, P. V. (2000). Interpreting disorder and solution structures with molecular mechanics. 219th American Chemical Society National Meeting, San Francisco, USA, 26-30 March, 2000. USA: American Chemical Society.

Macrocyclic complexes as redox-active receptors

Bernhardt, P. V. and Hayes, E. (1999). Macrocyclic complexes as redox-active receptors. IC '99, Wellington, NZ, 31 January - 4 February 2000. Wellington, NZ: NZ institute of Chemistry.

Rare earth dimers as candidates for upconversion

Bernhardt, P. V., Flanagan, B. and Riley, M. J. (1999). Rare earth dimers as candidates for upconversion. IC '99, Wellington, NZ, 31 January - 4 February 1999. Wellington, NZ: NZ Institute of Chemistry.

An Efficient Numerical Method for Simulating Electrochemically Driven Enzymatic Reactions

Honeychurch, Michael and Bernhardt, Paul (2006). An Efficient Numerical Method for Simulating Electrochemically Driven Enzymatic Reactions.